基于裂缝参数的钢筋混凝土预裂梁刚度试验研究

为研究钢筋混凝土简支梁桥跨中开裂后的刚度特性,开展不同裂缝名义损伤比下跨中预裂梁的力学试验。试件为现浇钢筋混凝土预裂梁,考虑了跨中3种不同长度a(a=8、18和26 mm)的预制裂缝。试验研究8 m标准跨径混凝土简支梁不同荷载级别下跨中预裂梁抗弯刚度折减系数k随裂缝名义损伤比λ和裂缝张开度w的演化规律。研究表明,不同试验工况下,k均随λ和w的增加而降低,且k的降低幅度在裂缝长度小于钢筋保护层时变化较小,在裂缝长度接近钢筋高度时快速降低,而在高于钢筋位置后则降幅减缓。在此基础上,提出跨中开裂钢筋混凝土简支梁桥抗弯刚度折减系数的计算公式。研究结果为该类梁桥跨中开裂后刚度性能的准确预测与评估提供了依据。     

STUDY ON THE VARIATION MECHANISM OF CARBON CONTENT OF LIQUID IRON IN MELTING GASIFIER

This paper studied the changing principles of carbon content in direct reduction iron (DRI) and liquid iron in the COREX melting gasifier. Under the normal working conditions of experimental equipment, liquid nitrogen was poured into the melting gasifier from its tuyere to cool down quickly. And then seven cross sections were made to study the carburization reaction and its characteristics of the solid iron and the liquid iron, and also the reaction of carbon between the slag and the metal. According to the results, the influences of the thickness of the semi-coke layer and the temperature on the carbon content of liquid iron in the COREX melting gasifier were confirmed.     

液相化学还原法制备不同形貌的多晶纳米镍

采用液相化学还原法,在1,2-丙二醇体系中,分别使用吐温-80（Tween-80）、聚乙二醇-6000（PEG-6000）和十二烷基硫酸钠（SDS）与聚乙二醇-6000（PEG-6000）的混合物作为修饰剂,利用1,2-丙二醇还原相同母体醋酸镍,制备形貌分别为海绵体、纤维状、雪花状的多晶纳米镍;在水体系中,使用SDS为修饰剂,利用水合肼还原相同母体醋酸镍,制备球形多晶纳米镍。通过X射线衍射（XRD）、透射电子显微镜（TEM）、选区电子衍射（SAED）对纳米镍进行表征。利用傅立叶红外（FTIR）分析初步解释不同形貌纳米镍的形成机理。     

一种基于分布约简的规则获取方法*

基于决策表分布约简定义规则的分布核与分布约简概念,提出一种基于分布约简的规则获取方法.首先确定条件类的分布核,进而采用启发式算法计算其分布约简,挖掘出最简产生式规则.该方法能适应决策表的不一致情形,且运用此方法所提取的规则集能够保持与原信息系统一致.     

N、S共掺杂碳基高效氧还原催化剂的制备

杂原子掺杂碳基氧还原（ORR）催化剂具有代替Pt基催化剂的巨大潜力。以硫掺杂g-C₃N₄（S-doped g-C₃N₄, S-g-C₃N₄）作为硫源和氮源,以三嵌段共聚物P123作为碳源,通过简单的高温热解法成功制备了N、S共掺杂碳（N, S co-doped carbon, NSC）催化剂,并考察了热解温度对制备的NSC催化剂ORR性能的影响。材料表征结果显示:温度为1 000 ℃时制备的催化剂NSC-1000具有较高的氮含量和硫含量及最大的比表面积;电化学测试结果显示:NSC-1000具有最佳的ORR性能,在0.1 mol/L KOH溶液中半波电位（half-wave potential, E1/2）高达0.888 V,且经10 000圈循环伏安扫描后E1/2仅负移12 mV,表现出极佳的活性和稳定性。此外,旋转环盘电极测试结果显示:NSC-1000催化剂主要以四电子反应路径催化ORR的发生。本实验为制备N、S共掺杂碳基高效ORR催化剂提供了新的思路。     

Cobalt nanoparticle decorated N-doped carbons derived from a cobalt covalent organic framework for oxygen electrochemistry

The low cost and highly efficient construction of electrocatalysts has attracted significant attention owing to the use of clean and sustainable energy technologies. In this work, cobalt nanoparticle decorated N-doped carbons (Co@NC) are synthesized by the pyrolysis of a cobalt covalent organic framework under an inert atmosphere. The Co@NC demonstrates improved electrocatalytic capabilities compared to N-doped carbon without the addition of Co nanoparticles, indicating the important role of cobalt. The well-dispersed active sites (Co–N_x) and the synergistic effect between the carbon matrix and Co nanoparticles greatly enhance the electrocatalytic activity for the oxygen reduction reaction. In addition, the Co content has a significant effect on the catalytic activity. The resulting Co@NC-0.86 exhibits a superb electrocatalytic activity for the oxygen reduction reaction in an alkaline electrolyte in terms of the onset potential (0.90 V), half-wave potential (0.80 V) and the limiting current density (4.84 mA·cm^–2), and a high selectivity, as well as a strong methanol tolerance and superior durability, these results are comparable to those of the Pt/C catalyst. Furthermore, the superior bifunctional activity of Co@NC-0.86 was also confirmed in a home-built Zn-air battery, signifying the possibility for application in electrode materials and in current energy conversion and storage devices.     

协同处置系统优化节能降耗的生产实践

公司协同处置项目植入热盘炉后,烧成系统运行稳定性变差,热耗上升,处置废弃物时标煤耗最高上升4kg/t.cl以上。对窑尾烟室缩口,C4下料管及窑尾分解炉燃料喷入点进行综合诊断分析,实施优化改造措施,分解炉内煤粉燃烧环境得到改善,系统通风阻力降低,标煤耗降低到103 kg/t.cl以下,与热盘炉植入前相当。     

电能变换领域中随机脉宽调制技术研究概况及展望

相较于传统的脉宽调制技术,随机脉宽调制具备有效的谐波频谱分散能力,从而实现机电负载噪声的削弱。随机脉宽调制技术包括起步的随机开关调制、后续的随机脉冲位置与随机开关频率等3个基本方法。随着电力电子技术的整体发展,随机脉宽调制已从传统的载波调制逐渐拓展到空间矢量调制之中,应用范围日趋广泛,谐波频谱分散与功率谱峰值抑制的效果不断提升。同时,新的优化方案不断被提出,对谐波频谱及功率谱的分散效果亦在不断提高。梳理了随机脉宽调制的研究历程,总结了数种典型的随机脉宽调制的基本原理,并对未来随机脉宽调制的研究方向作出展望,为随机脉宽调制技术的深入研究提供参考。     

高土壤电阻率变电站降阻措施分析及降阻目标选择

采用接地系统辅助设计软件包CDEGS,结合工程实例对局部换土、深井接地、引外接地和敷设接地极(接地模块或离子接地棒) 4种高土壤电阻率变电站常用降阻措施进行了仿真计算。基于计算结果分析了每种降阻措施的降阻特性,并提出了工程应用建议。此外,在确保人身和设备安全前提下,探讨了如何合理选择降阻目标避免过度设计。     

涂装废气焚烧炉烟气余热利用的改善

针对某汽车涂装车间使用废气焚烧炉的实际情况,制定了烟气余热利用的改进方案,从节能效益和减排效益两个方面论证了方案的可行性及优越性。