复合式水力旋流器油水分离实验研究

复合式水力旋流器将动态与静态旋流分离技术有机地结合在一起 ,具有动态与静态水力旋流器的双重优点。这种旋流器由动力组件 (包括电动机、空心驱动轴、旋转栅及溢流嘴等 )、静态旋流单体、入口腔、底流腔及溢流腔等部分组成。对额定处理量为 8m3/h样机的分离特性测试表明 ,当电动机驱动轴转速低于 30 0 0r/min时 ,入口压力为 0 10～ 0 35MPa ,底流压差为0 0 5～ 0 2 0MPa ,处理量为 3～ 10m3/h ,选用单螺杆泵增压和离心泵增压两种方式 ,分离效率分别为 97%和 84 % ,均取得满意的分离效果。     

Effects of solvent and temperature on the coupling agent/epoxy resin interface

Increased wetting of the coupling agent/epoxy resin interface was observed when γ-glycidoxypropyltrimethoxysilane, polyfunctional aminosilane and γ-aminopropyltriethoxysilane were applied respectively from methyllethylketone, dimethylformamide and water on woven glass cloths which had been cleaned at 300°C. However, when factory-applied coupling agents were burnt off the woven cloths and fresh coupling agents re-applied, it was found that the nature of the factory-applied coupling agent influenced subsequent wetting. Thinner glass fibres showed a greater improvement in wetting rate than thicker fibres in those solvents identified to be good for improved wettability, irrespective of the heat-cleaning temperature.     

Intermetallic compounds formed at the interface between liquid indium and copper substrates

The interfacial reactions between liquid In and Cu substrates at temperatures ranging from 175°C to 400°C are investigated for the applications in bonding recycled sputtering targets to their backing plates. Experimental results show that a scallop-shaped Cu₁₆In₉ intermetallic compound is found at the Cu/In interface after solder reactions at temperatures above 300°C. A double-layer structure of intermetallic compounds containing scallop-shaped Cu₁₁In₉ and continuous CuIn is observed after the Cu/In interfacial reaction at temperatures below 300°C. The growth of all these intermetallic compounds follows the parabolic law, which implies that the growth is diffusion-controlled. The activation energies for the growth of Cu₁₆In₉, Cu₁₁In₉, and CuIn intermetallic compounds calculated from the Arrhenius plot of growth reaction constants are 59.5, 16.9, and 23.5 kJ/mole, respectively.     

硼酸铝晶须增强环氧树脂和双马来酰亚胺树脂体系的研究

本文以硼酸铝晶须为增强剂，以4，5-环氧环己烷-1，2-二甲酸二缩水甘油酯(TDE-85)，甲基纳狄克酸酐(MNA)、N，N’-二胺基二苯甲烷型双马来酰亚胺(BMI)/O，O′-二烯丙基双酚A(BA)体系分别作为基体制备晶须增强复合材料。研究了晶须对树脂的尺寸、表面处理方法、含量对树脂体系力学性能和热性能的影响；通过扫描电子显微镜(SEM)分析了浇注体的弯曲、冲击断口，研究晶须的增强机理。     

Structure and properties of CE/CTBN/EP blends: II. Effect of EP on the mechanical properties and thermostability of the CE/CTBN system

Carboxyl‐terminated butadiene‐acrylonitrile rubber (CTBN) has often been used to improve the toughness of cyanate ester (CE) resin while sacrificing modulus and thermostability. In this paper, the addition of the appropriate amount of epoxy resin (EP) to the CE/CTBN system is shown to not only increase the modulus and thermostability of the blend, but also improve the toughness. The values of impact strength showed a maximum for the CE/CTBN/EP 100/5/5 blend. The temperature of 10 % weight loss (T₁₀) improves from 376 °C for CE/CTBN 100/5 to 407 °C for the CE/CTBN/EP 100/5/2.5 blend. It is proposed that addition of the appropriate amount of EP can decrease the mobility and increase the stability of CTBN via the reaction between the terminal carboxyl group of CTBN and the hydroxyl group of EP. But a very high EP concentration will decrease the crosslinking density of CE, consequently reducing the mechanical properties and thermostability of the blends. Copyright © 2004 Society of Chemical Industry     

西霞院水利枢纽工程泄洪闸振冲碎石桩基础处理

通过西霞院水利枢纽工程泄洪闸振冲碎石桩基础处理施工方法论述,给出了加砂层振冲碎石桩施工造孔水压、水量、成孔速度、填料级配、填料方法以及振密电流值、留振时间等施工控制参数。     

反渗透膜仓用韧性环氧树脂基体研究

工业上广泛使用反渗透膜仓制备高纯水,为了用玻璃钢替代不锈钢,研究了一种适合湿法缠绕的反渗透膜仓用韧性环氧基体。在配方中采用液体酸酐固化剂甲基四氢邻苯二甲酸酐和高效活性增韧剂,对树脂基体和复合材料力学性能及耐水性能的研究表明该树脂基体具有许多优良性能,如拉伸强度≥86.2MPa,断裂延伸率≥5.2%,弯曲强度≥139MPa,制得膜仓爆破时纤维强度转化率高达88.7%,耐疲劳达10万次而无损伤。此外,配方体系室温下粘度为0.35～0.4Pa·s,适用期≥8h,室温下在水中浸泡180d后吸水率低于0.5%,同不锈钢相比成本降低1/2。实验结果表明,该韧性环氧基体完全适用于反渗透膜仓使用。     

明渠断面水流流速与边界剪切应力横向分布模型

天然河流的横断面多为由主槽和漫滩组成的复式断面,水流在这种断面中比在单一断面中受到更多因素影响,流态也更加复杂。通过将明渠横断面上微元体在水流方向的N-S控制方程沿水深积分,得出描述垂线平均流速和边界剪切应力横向分布的模型,并通过对实验数据的验证,确定了模型的实用性。     

聚合物-金属界面相形貌的研究

环氧树脂在 Al 合金表面生成纤维状的界面相结构,其形成、发展和特征与树脂的体系、交联反应条件以及 Al 合金的表面状态有关。环氧树脂的基础相为颗粒状的超结构组织。聚合物界面相的力学破坏表现为纤维体的拉伸、变形和断裂,而基础相在纯剪切受力时出现在45°方向的裂纹,并发展导致连接层的破坏。     

蓝湿皮酶软化的特性研究

以自行研制的一种复合酶为软化剂 ,研究了 p H值、反应温度、反应时间、酶用量以及铬含量对猪蓝湿皮软化效果的影响 ,其软化效果以软化液中羟脯氨酸的浓度增量来表征。研究结果表明 :通过蓝湿皮软化来改善成品革的质量是可行的 ,而且有明显的效果 ;以软化液中羟脯氨酸的浓度来表征软化效果是一个有效的方法 ;当用该复合酶软化猪蓝湿皮时 ,最适 p H值范围为 6 .0 - 6 .5 ;反应温度在 4 0 - 6 5℃之间时 ,软化效果随温度的升高而增大 ;在 5 5℃条件下 ,该酶有很好的热稳定性 ,能长时间保持活力不衰减 ;最适酶用量为 30 0 U/ g试样 ;蓝湿皮的铬含量对软化效果有影响 ,用该方法处理的蓝湿皮 ,其铬离子质量含量一般应≤ 2 .5 %。