再生用碱的质量对阴离子交换树脂性能的影响

我国许多电厂在再生阴离子交换树脂时都习惯采用隔膜法生产的工业氢氧化钠，这种氢氧化钠中的杂质离子含量较高，会对阴离子交换树脂的性能产生很大的影响。就碱中杂质成分对阴离子交换树脂的影响，通过比较两种不同纯度的碱再生后的阴离子交换树脂的技术经济性，提出再生阴离子交换树脂时应优先选择纯度较高的碱。     

离子交换铒掺杂磷酸盐玻璃波导特性研究

给出有关离子交换铒掺杂磷酸盐玻璃波导的制备以及发光特性的基本结果。用Ag+ Na+ 离子交换在含有适量氧化钠的铒掺杂磷酸盐玻璃上很容易实现低损耗平面波导 ,并且离子交换过程对这种玻璃的光谱特性没有影响。     

日产NHR-90W型催化剂失活原因分析

对日产NHR -90W催化剂在抚顺石化分公司石油二厂 6万t/a石蜡加氢装置运行情况进行了研究 ,证明该催化剂活性较高 ,对原料的适应性也较强。同时 ,对造成催化剂短期内失活的原因进行了分析 ,认为原料中铁离子含量过高是造成催化剂失活的主要原因。对相关装置生产控制提出了建议     

甲基丙烯酸乙酯合成工艺研究

以大孔强酸性离子交换树脂为催化剂,甲基丙烯酸(MAA)与乙醇直接酯化合成甲基丙烯酸乙酯(EMA)。在MAA与乙醇摩尔比为1:3、反应温度89～93℃、空速0.3h~(-1)的条件下,MAA转化率不低于98％,EMA的选择性不低于99％。     

用膜电解法处理低浓度SO2吸收液的三室电解槽材料的选择

提出了用膜电解法处理低浓度SO2吸收液的方法，介绍了三室电解槽的设计原理及在电场作用下，电解槽内离子的迁移和电解反应机理，系统地讨论了电解槽组成单元材料（如阳离子交换器）的选择及在H2SO4－NaHSO3-Na2SO3体系中金属阳极的选择等，并进行了试验验证，得到了很好的结果。     

Clarification of a wheat straw‐derived medium with ion‐exchange resins for xylitol crystallization

BACKGROUND: Xylitol bioproduction from lignocellulosic residues comprises hydrolysis of the hemicellulose, detoxification of the hydrolysate, bioconversion of the xylose, and recovery of xylitol from the fermented hydrolysate. There are relatively few reports on xylitol recovery from fermented media. In the present study, ion‐exchange resins were used to clarify a fermented wheat straw hemicellulosic hydrolysate, which was then vacuum‐concentrated and submitted to cooling in the presence of ethanol for xylitol crystallization. RESULTS: Sequential adsorption into two anion‐exchange resins (A‐860S and A‐500PS) promoted considerable reductions in the content of soluble by‐products (up to 97.5%) and in medium coloration (99.5%). Vacuum concentration led to a dark‐colored viscous solution that inhibited xylitol crystallization. This inhibition could be overcome by mixing the concentrated medium with a commercial xylitol solution. Such a strategy led to xylitol crystals with up to 95.9% purity. The crystallization yield (43.5%) was close to that observed when using commercial xylitol solution (51.4%). CONCLUSION: The experimental data demonstrate the feasibility of using ion‐exchange resins followed by cooling in the presence of ethanol as a strategy to promote the fast recovery and purification of xylitol from hemicellulose‐derived fermentation media. Copyright © 2008 Society of Chemical Industry     

锂离子电池有机电解液成膜添加剂的研究现状

文章综述了锂离子电池有机电解液成膜添加剂的作用原理，具体介绍了CO2、SO2、VC化合物、卤化物、有机铜盐以及马来酐等添加剂的研究现状。