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21.
In this work, the effect of ZrB2 (0, 5, 10 and 20?vol%) ceramic reinforcement on densification, structure, and properties of mechanically alloyed Al was investigated. The milling of Al-ZrB2 powder compositions resulted in formation of agglomerates with varied size. In particular, the size of agglomerates was reduced considerably with increased addition of ZrB2 to Al. Interestingly, the densification of hot pressed Al increased from 96.06% to 99.22% with ZrB2 addition. The reduction of agglomerates size was attributed to the enhanced densification of Al-ZrB2 composites. Pure Al showed relatively low hardness (0.94?GPa) and it was improved to 1.78?GPa with the addition of 20?vol% ZrB2. The mechanical properties have significantly been improved for Al-ZrB2 composites. Especially Al - 20?vol% ZrB2 possessed a very high yield strength (529?MPa), compressive strength (630?MPa) and compressive strain of 19.25%. Realization of such a good combination of mechanical properties is the highest ever reported for Al composites so far in the literature. The coefficient of friction (COF) of Al-ZrB2 varied narrowly between 0.33 and 0.40 after dry sliding wear against steel disc. The wear rate of Al-ZrB2 composites was within mild wear regime and varied between 98.88?×?10?6 and 34.66?×?10?6 mm3/Nm. Among all the compositions, Al - 20?vol% ZrB2 composite exhibited the lowest wear rate and high wear rate was noted for pure Al. Mild abrasion, tribo-oxidation, third body wear (wear debris) and delamination were the major material removal mechanisms for Al-ZrB2 composites. Overall the hardness, strength and wear resistance of Al - 20?vol% ZrB2 composite was improved by 84.3%, 84.3% and 64.2%, respectively when compared to pure Al. 相似文献
22.
Ting Liu Huimin Zhang Panfei Ma Aimin Chang Hui Jiang 《Journal of the American Ceramic Society》2019,102(8):4393-4398
Core–shell structures have been proposed to improve the electrical properties of negative-temperature coefficient (NTC) thermistor ceramics. In this work, Al2O3-modified Co1.5Mn1.2Ni0.3O4 NTC thermistor ceramics with adjustable electrical properties were prepared through citrate-chelation followed by conventional sintering. Co1.5Mn1.2Ni0.3O4 powder was coated with a thin Al2O3 shell layer to form a core–shell structure. Resistivity (ρ) increased rapidly with increasing thickness of the Al2O3 layer, and the thermal constant (B) varied moderately between 3706 and 3846 K. In particular, Co1.5Mn1.2Ni0.3O4@Al2O3 ceramic with 0.08 wt% Al2O3 showed the increase of ρ double, and the change in its B was less than 140 K. The Co1.5Mn1.2Ni0.3O4@Al2O3 NTC ceramics showed high stability, and their grain size was relatively uniform due to the protection offered by the shell. The aging coefficient of the ceramic was less than 0.2% after aging for 500 hours at 125°C. Taken together, the results indicate that as-prepared Co1.5Mn1.2Ni0.3O4@Al2O3 NTC ceramics with a core–shell structure may be promising candidates for application as wide-temperature NTC thermistor ceramics. 相似文献
23.
Isaac Isarn Leïla Bonnaud Lluís Massagus ngels Serra Francesc Ferrando 《Polymer International》2020,69(3):280-290
The enhancement of the thermal conductivity, keeping the electrical insulation, of epoxy thermosets through the addition of pristine and oxidized carbon nanotubes (CNTs) and microplatelets of boron nitride (BN) was studied. Two different epoxy resins were selected: a cycloaliphatic (ECC) epoxy resin and a glycidylic (DGEBA) epoxy resin. The characteristics of the composites prepared were evaluated and compared in terms of thermal, thermomechanical, rheological and electrical properties. Two different dispersion methods were used in the addition of pristine and oxidized CNTs depending on the type of epoxy resin used. Slight changes in the kinetics of the curing reaction were observed in the presence of the fillers. The addition of pristine CNTs led to a greater enhancement of the mechanical properties of the ECC composite whereas the oxidized CNTs presented a greater effect in the DGEBA matrix. The addition of CNTs alone led to a marked decrease of the electrical resistivity of the composites. Nevertheless, in the presence of BN, which is an electrically insulating material, it was possible to increase the proportion of pristine CNTs to 0.25 wt% in the formulation without deterioration of the electrical resistivity. A small but significant synergic effect was determined when both fillers were added together. Improvements of about 750% and 400% in thermal conductivity were obtained in comparison to the neat epoxy matrix for the ECC and DGEBA composites, respectively. © 2019 Society of Chemical Industry 相似文献
24.
Priyadarshi Chakraborty Yiming Tang Tomoya Yamamoto Yifei Yao Tom Guterman Shai Zilberzwige-Tal Nofar Adadi Wei Ji Tal Dvir Ayyalusamy Ramamoorthy Guanghong Wei Ehud Gazit 《Advanced materials (Deerfield Beach, Fla.)》2020,32(9):1906043
Self-assembled peptide hydrogels represent the realization of peptide nanotechnology into biomedical products. There is a continuous quest to identify the simplest building blocks and optimize their critical gelation concentration (CGC). Herein, a minimalistic, de novo dipeptide, Fmoc-Lys(Fmoc)-Asp, as an hydrogelator with the lowest CGC ever reported, almost fourfold lower as compared to that of a large hexadecapeptide previously described, is reported. The dipeptide self-assembles through an unusual and unprecedented two-step process as elucidated by solid-state NMR and molecular dynamics simulation. The hydrogel is cytocompatible and supports 2D/3D cell growth. Conductive composite gels composed of Fmoc-Lys(Fmoc)-Asp and a conductive polymer exhibit excellent DNA binding. Fmoc-Lys(Fmoc)-Asp exhibits the lowest CGC and highest mechanical properties when compared to a library of dipeptide analogues, thus validating the uniqueness of the molecular design which confers useful properties for various potential applications. 相似文献
25.
Alberto Ballesteros Ester Laguna-Gutierrez Paula Cimavilla-Roman Maria Luisa Puertas Antonio Esteban-Cubillo Julio Santaren Miguel Angel Rodriguez-Perez 《应用聚合物科学杂志》2021,138(46):51373
In the present work blends of polystyrene (PS) with sepiolites have been produced using a melt extrusion process. The dispersion degree of the sepiolites in the PS has been analyzed by dynamic shear rheology and X-ray micro-computed tomography. Sepiolites treated with quaternary ammonium salts (O-QASEP) are better dispersed in the PS matrix than natural sepiolites (N-SEP) or sepiolites organo-modified with silane groups (O-SGSEP). A percolated network is obtained when using 6.0 wt% of O-QASEP, 8.0 wt% of N-SEP and 10.0 wt% of O-SGSEP. It has been shown that multiple extrusion processes have a negative effect on the polymer architecture. They produce a reduction in the length of the polymeric chains, and they do not lead to a better dispersion of the particles in the polymer matrix. Foams have been produced using a gas dissolution foaming process, where a strong effect of the dispersion degree on the cellular structure of the different foams was found. The effects on the cellular structure obtained by using different types of sepiolites, different contents of sepiolites and different extrusion conditions have been analyzed. The foams produced with the formulations containing O-QASEP present the lowest cell size and the most homogeneous cellular structures. 相似文献
26.
《Ceramics International》2022,48(8):10506-10515
The search for materials and methods capable of reducing human impacts on the environment is of utmost importance nowadays. This study's primary purpose was to analyze the technical feasibility of ceramic composites production utilizing Fundão Dam's Iron Ore Tailings (IOT), Blast Furnace Slag (BFS) from charcoal, and Foundry Sand (FS) as partial substitutes for the traditional raw materials – sand and clay – for application in building industry materials. The composites were molded in rectangular specimens and fired at temperatures of 900, 950, 1000, 1050, and 1200 °C. The developed materials were analyzed and characterized by X-Ray Diffraction (XRD), Scanning Electron Microscopy (SEM), Energy Dispersive Spectroscopy (EDS), Thermogravimetry (TGA), and Differential Thermal Analysis (DTA). The obtained materials had flexural strength modulus of up to 12.19 MPa, water absorption ranging from 2 to 22%, linear shrinkage ranging from 0.02 to 6.50%, and apparent density ranging from 2.03 to 1.63 g/cm3. The study of the internal structure formation process revealed the formation of amorphous structures in the composites. The results demonstrated that these waste materials may be jointly used in construction materials, contributing to the reduction of natural resource extraction, besides enabling their correct disposal, minimizing environmental impacts, and improving the life quality of the surrounding communities. 相似文献
27.
针对平面并联机构无奇异位置工作空间求解困难、过程繁琐、计算量大等问题,提出了基于CAD求解平面并联机构工作空间的三维螺旋扫描方法。将[n]自由度平面并联机构分解成[n]条支链进行独立分析,得到每条支链下末端执行器的可达区域,再将所有支链可达区域取交集即为平面并联机构工作空间。应用SolidWorks软件建立平面并联机构模型,进行几何特征处理,通过自动求解器求解,将求解过程图形化,快速得到同轴布局5R机构和平面3-RPR并联机构的无奇异位置工作空间。通过同轴布局5R机构的运动学实验,验证了该求解方法的可行性。 相似文献
28.
Chen Tang Tiehu Li Yuhang Bai Junjie Gao Wenbo Yang Shasha Jiao Tingkai Zhao 《Ceramics International》2018,44(10):11812-11819
Recently, ceramic matrix composites reinforced by short carbon fibers (CFs) attracted increasing attentions. To further improve mechanical properties and oxidation resistances, CFs were subjected to oxidation and acidification followed by sol-gel dip-coating to deposit ZrO2 on their surfaces. ZrO2-Cf/SiC composites were fabricated by joint hot compression molding and sintering, compared to Cf/SiC and SiC prepared by the same method. Microstructural analyses indicated that ZrO2 coatings were successfully deposited on CF surfaces, formed strong bonding and interfaces between CF and the matrix. Meanwhile, CFs were found uniformly distributed in SiC matrix with random orientations. Flexural curves of ZrO2-Cf/SiC and Cf/SiC revealed the presence of “false plasticity” regions after sharp drops, which were quite different from brittle flexural behavior of SiC ceramic. Compression strength of the three samples showed step-up growth. ZrO2-Cf/SiC exhibited the highest value, indicating the introduction of CFs and ZrO2 coatings do have great influence on mechanical performances. After heat treatment, ZrO2-Cf/SiC exhibited better oxidation resistance than Cf/SiC, with weight loss ratios estimated to ??3.76% and ??6.43%, respectively. These improved properties indicated that ZrO2-Cf/SiC would be excellent alternatives to other existence materials under ultra-high temperature environments. 相似文献
29.
Pietro Galizia Simone Failla Luca Zoli Diletta Sciti 《Journal of the European Ceramic Society》2018,38(2):403-409
One of the biggest challenges of the materials science is the mutual exclusion of strength and toughness. This issue was minimized by mimicking the natural structural materials. To date, few efforts were done regarding materials that should be used in harsh environments. In this work we present novel continuous carbon fiber reinforced ultra-high-temperature ceramic matrix composites (UHTCMCs) for aerospace featuring optimized fiber/matrix interfaces and fibers distribution. The microstructures – produced by electrophoretic deposition of ZrB2 on unidirectional carbon fibers followed by ZrB2 infiltration and hot pressing – show a maximum flexural strength and fracture toughness of 330 MPa and 14 MPa m1/2, respectively. Fracture surfaces are investigated to understand the mechanisms that affect strength and toughness. The EPD technique allows the achievement of a peculiar salami-inspired architecture alternating strong and weak interfaces. 相似文献
30.
Shengyue Gu Shouyang Zhang Fei Liu Wei Li 《Journal of the European Ceramic Society》2018,38(15):5082-5091
Y2Hf2O7 possesses low thermal conductivity and high melting point, which make it promising for a new anti-ablation material. For evaluating the thermal stability and the potential applications of Y2Hf2O7 on anti-ablation protection of C/C composites, Y2Hf2O7 ceramic powder was synthesized by solution combustion method and Y2Hf2O7 coating was prepared on the surface of SiC coated C/C composites using SAPS. Results shown that the coating exhibits good ablation resistance under the heat flux of 2.4?MW/m2 with the linear and mass ablation rates are 0.16?μm?s?1 and ?0.028?mg?s?1, respectively, after ablation for 40?s. With the prolonging of the ablation time, the increasing thermal stress causes the increase of cracks. Moreover, the chemical erosion from SiO2 and the physical volatilization of low temperature molten products aggravate failure of the Y2Hf2O7 coating. 相似文献