五氯吡啶的合成研究

以吡啶为原料，氯气为氯化剂，通过固定床催化反应合成了五氯吡啶。为此，在分析反应机理的基础上，分别以第Ⅱ、Ⅷ和IB族的金属盐类或其混合物为活性成分制备了一系列催化剂，并在493-663K、空速200—1200hr^-1、吡啶/氯气摩尔比(R)1：6—1：12范围内，对上述各催化剂性能进行考察。结果表明，Ba、Ca、La、Rh等金属的盐类混合物对本反应有较高的活性，收率高达95％，纯度96％(GC)。同时还获得了针对该催化剂适宜的工艺参数：温度590-650K，空速600-800hr^-1，R为8．5。     

Velocity Profile in Fixed Beds: A Study on the Representativeness of the Experimental Measurement of Downstream Flow Characteristics

Although considerable progress has been made in the development of experimental techniques for investigating velocity distribution inside a fixed bed, these techniques were limited to special cases. Consequently, the velocity distribution is normally measured at downstream of the fixed bed and then this measurement is considered to be representative for the flow inside the bed. To evaluate the representativeness of this technique, this work presents a study of the change in the flow characteristics, starting from the boundary of the fixed bed within the pipe to a downstream position where the experimental measurement is taken, by using simulations based on computational fluid dynamics methods.     

Albemarle渣油加氢处理催化剂研究

渣油加氢处理技术在炼油生产中占有很重要的地位.Albemarle最近开发的固定床催化剂KFR22和 KFR72具有出色的脱沥青质活性和更高的脱氮性能,最近开发的沸腾床催化剂是KF1302T 和KF1311,与以前的沸腾床催化剂相比 ,这些催化剂的组合降低了沉积物的生成,可提供更高的加氢脱硫性能.     

Autothermal two-stage gasification of low-density waste-derived fuels

In order to increase the efficiency of waste utilization in thermal conversion processes, pre-treatment is advantageous. With the Herhof Stabilat^® process, residual domestic waste is upgraded to waste-derived fuel by means of biological drying and mechanical separation of inerts and metals. The dried and homogenized waste-derived Stabilat^® fuel has a relatively high calorific value and contains high volatile matter which makes it suitable for gasification. As a result of extensive mechanical treatment, the Stabilat^® produced is of a fluffy appearance with a low density. A two-stage gasifier, based on a parallel-arranged bubbling fluidized bed and a fixed bed reactor, has been developed to convert Stabilat^® into hydrogen-rich product gas. This paper focuses on the design and construction of the configured laboratory-scale gasifier and experience with its operation. The processing of low-density fluffy waste-derived fuel using small-scale equipment demands special technical solutions for the core components as well as for the peripheral equipment. These are discussed here. The operating results of Stabilat^® gasification are also presented.     

VERIFICATION AND COMPARISON OF FORMULAS FOR BED LOAD TRANSPORT

1 .　ＩＮＴＲＯＤＵＣＴＩＯＮＴｈｅｂｅｄｌｏａｄｔｒａｎｓｐｏｒｔｈａｓｂｅｅｎｅｘｔｅｎｓｉｖｅｌｙｓｔｕｄｉｅｄｉｎｔｈｅｐａｓｔｆｅｗｄｅｃａｄｅｓａｎｄｍａｎｙｆｏｒｍｕｌａｓｆｏｒｐｒｅｄｉｃｔｉｎｇｂｅｄｌｏａｄｔｒａｎｓｐｏｒｔｒａｔｅｈａｖｅｂｅｅｎｐｒｅｓｅｎｔｅｄ(Ｅｉｎｓｔｅｉｎ 1950 ;Ｍｅｙｅｒ Ｐｅｔｅｒ 194 8;Ｂａｇｎｏｌｄ 1973;Ｅｎｇｅｌｕｎｄ 1976;Ｙａｌｉｎ 1972 ;Ｓａｍａｇａ 1986;ａｎｄＫａｒｉｍ 1998) .Ｗｈｅｎａｐｐｌｉｅｄｔｏｓｔｒｅａｍｓｗｉｔｈｐａｒｔｉａｌ…     

码头建筑物对水位影响的模型试验及计算方法

河岸码头建筑物势必导致其上游水位壅高及对码头附近水流流态产生影响。以汉江沙洋河段为对象 ,通过定床概化物理模型试验研究了码头建筑物对河道水位与流速场的影响。并基于能量平衡原理 ,采用河道恒定非均匀流水面曲线基本方程 ,结合物理模型试验资料 ,计算了码头建筑物附近的水位变化值 ,并提出了码头建筑物产生的水位壅高值的计算方法。     

DRYING OF GRANULAR PARTICLES IN A MULTISTAGE INCLINED FLUIDIZED BED WITH MECHANICAL VIBRATION

A mathematical model for the drying rate of granular particles in a multistage inclined fluidized bed(IFB) is presented from the standpoint of simultaneous heat and mass transfer, with taking the effect of mechanical vibration added vertically into consideration.

Steady-state distributions for the temperatures and concentrations of the particles and the heating gas, and for the moisture content of the particles are numerically calculated based on the present model. The calculated results show fairly good agreement with the experimental data, which were obtained from the drying experiments of brick particles in a three-stage IFB using comparatively low temperature air(40-60°C) as the heating gas.

It has been found within the range of the experimental conditions employed that, the mechanical vibration added vertically enhances the over-all drying rate of the particles and its effect can be considered equivalent to an increase in the air velocity.     

采用轴径向技术有效解决固定床反应器阻力降的快速升高

讨论了固定床反应器阻力降快速升高的原因，介绍了用轴径向技术解决这一问题的原理及优点，及其在铁铬系变换催化剂和钴钼系耐硫变换催化剂反应器中的实际应用。     

脉冲相干激光雷达对运动目标成像模拟

针对运动目标，在考虑激光雷达方程、信噪比和自动增益、成像指标、噪声、图像处理等模块的基础上，对脉冲相干成像激光雷达进行了运动目标的成像模拟。     

Valley floor landscape change following almost 100 years of flood embankment abandonment on a wandering gravel‐bed river

Critical to restoring the nature conservation value of many river corridors is an understanding of how alluvial landscapes will respond to cessation of river management and land use practices that have previously degraded the environment. This paper analyses changes in valley floor landforms and vegetation patch dynamics, in relation to fluvial disturbance, over a period of almost 100 years following flood embankment abandonment on a wandering gravel‐bed river, namely the River Tummel, Scotland. Such rivers were once typical of many draining upland areas of northern maritime Europe. Prior to abandonment the valley floor landscape was agriculturally dominated and the river for the most part was single thread confined between flood embankments. The pattern of landform change and vegetation patch development over time following a decision in 1903 not to maintain embankments was tracked by geomorphic and land cover mapping utilizing successive sets of aerial photography for the period 1946 to 1994. A historical context for these changes was also feasible because the channel planform in 1900 and earlier channel planform changes dating back to 1753 were known due to the availability of old maps and earlier geomorphic studies. The land cover mapping was validated by comparison of results produced from the interpretation work on the 1994 aerial photographs with the field‐based UK National Vegetation Classification protocol. The findings of the study illustrate that bordering the River Tummel fluvial landforms and vegetation patch mosaics, presumably resembling those that occurred before valley floor land use intensification, evolved in less than 50 years after flood embankment abandonment with a resultant increase in habitat diversity. The change relates primarily to flood‐induced channel planform change and moderate levels of fluvial disturbance. The general significance of this change to plant species diversity on the valley floor of the River Tummel and elsewhere is discussed as is possible implications of the upstream impoundment and scenarios for climatically induced changes in flood frequency and magnitude. The overall outcome is the strong possibility that simple changes in river management and land use practices could result in re‐establishment of the nature conservation value of similar river corridors in Europe over the medium term without active restoration efforts. Copyright © 2002 John Wiley & Sons, Ltd.