压水堆核电厂一回路首次钝化工艺研究

压水堆核电厂热态功能试验中的一回路首次钝化对核电厂一回路材料腐蚀控制和减少腐蚀产物等方面具有重要作用。本文结合理论研究与工程实际情况，提出了在热态功能试验过程中钝化膜的生成包含电化学反应和化学反应的观点，阐述了双层膜的生长机理，解释了用电化学测试方法分析钝化工艺过程的合理性，推导出钝化温度与钝化膜反应速率的函数关系式，钝化温度升高，反应速率升高，钝化时间缩短；明确了钝化工艺温度的理论限值应不低于260℃。      

Improved Corrosion Resistance of Selective Laser Melted Ti–5Cu Alloy Using Atomized Ti–5Cu Powder

The different types of metal powder used for selective laser melting(SLM) process would cause distinct corrosion behavior due to the uniformity of the obtained microstructure.The SLM-produced Ti–5Cu alloy using atomized Ti–5Cu metal powder(SLMed Ti–5Cu) in this work reveals a relatively uniform microstructure with overwhelming acicular α/α′ phase and shows great advantages on corrosion resistance compared with the SLM-produced Ti–5Cu alloy using the mixture powder(SLMedM Ti–5Cu).The effect of the micro-galvanic cells decreases due to the undetectable Ti_2Cu phase in the microstructure of the SLMed Ti–5Cu.An apparent passivation behavior was observed for SLMed Ti–5Cu instead of severe pitting phenomenon for the SLMed-M Ti–5Cu.The charge transfer resistance of SLMed Ti–5Cu in this work is 10.09 ± 2.63 MΩ cm~2, which is significantly higher than that of SLMed-M Ti–5Cu(4.76 MΩ cm~2).The above result indicates the atomized Ti–5Cu powder plays an important role in the formation of the uniform microstructure of SLMed product, thereby enhancing its corrosion resistance in Hank's solution at 37 ℃.     

CZ-2C火箭常规二级推进剂钝化过程分析

CZ-2C火箭发射SSO轨道卫星在星箭分离后其二级箭体轨道寿命很长,成为空间垃圾。为适应空间碎片减缓工作的需求,应该对二级箭体内剩余推进剂进行排放处理。针对优选排放方案,分析排放过程的工作情况和参数,并参照遥测数据对分析结果进行验证。     

高耐蚀性Zn—Co合金镀层钝化工艺的研究

研究了电镀Zn-Co合金镀层的钝化液的组成及工艺条件，溶液各成分及工艺条件对钝化膜质量的影响，通过几种腐蚀试验方法，测量了钝化膜的耐蚀性，结果表明，研究的钝化工艺可以得到耐蚀性良好的钝化膜。     

预硫化加氢催化剂钝化技术研究进展

钝化是预硫化加氢催化剂的关键处理过程。预硫化催化剂经过钝化处理后,有效抑制了自热性质和硫的脱离,便于催化剂的存储和运输,并保持催化剂的活性,有利于器外预硫化催化剂的大规模生产。介绍了气相、液相和固相3种钝化方式、钝化机理及其应用和研究进展。     

Passivation and pitting corrosion of nanostructured Sn-Ni alloy in NaCl solutions

The passivation and pitting corrosion of tin-nickel alloy (34% Ni-66% Sn) in NaCl solution was studied using potentiodynamic, cyclic voltammetry and electrochemical impedance spectroscopy (EIS) techniques complemented by X-ray diffraction (XRD) and scanning electron microscopy (SEM). The effect of concentration of the chloride ion, the switching potential, scans rate and pH on the electrochemical behavior of Sn-Ni alloy is discussed. The data indicate that the corrosion rate and the pitting corrosion of Sn-Ni alloy increases by the increasing of chloride ion concentration. The observed corrosion resistance of electrodeposited Sn-Ni alloy is due to the formation of a thin passive film from tin and nickel oxides.     

氨合成催化剂钝化的研究

探索了氨合成催化剂还原后的温度对钝化操作与产品质量的影响,确定了最佳的钝化温度。     

铜及其合金的表面钝化-涂装抗蚀性能的电化学测试

表面钝化与涂装工艺相结合可显著提高铜及其合金的防腐性能.采用电化学工作站对涂层腐蚀电流进行定量测量,其结果显示,常规的涂装试样,在3% NaCl盐水溶液中浸泡1天,测得腐蚀电阻(Rc)为3.56×105Ω.钝化处理后再涂装的试样测试结果为无穷大.盐水浸泡5天后,前者95%表面受到不同程度的腐蚀,后者仍然正常.后者浸泡15天的腐蚀电阻为2.31×106Ω,仍高于前者浸泡1天的数据.钝化涂装工艺可用于室外及抗腐蚀性能要求较高的铜及其合金制品的表面防护装饰.     

电磁振动雾化-速凝镁粉钝化表征研究

用电磁振动雾化-速凝法制备了粒度为0.2～1.0 mm的镁粉,研究了这种速凝镁粉在1 000 ℃的阻燃时间.结果表明,速凝镁粉阻燃时间为17～21 s,而铣削-钝化镁粉阻燃时间为11～14 s.扫描电镜和能谱仪观察和分析发现,速凝镁粉存在表面碳富集,迅速凝固产生的致密表面,增强了粉粒表面的化学稳定性,产生了钝化效果.     

The effect of partial substitution of Ti with Zr, Cr or V in the Mg35Ti10Ni55 electrode alloy on its electrochemical performance

In this paper, Zr, Cr and V were selected as the partial substitution elements for Ti to form Mg₃₅Ti₅M₅Ni₅₅ quaternary alloys prepared by means of mechanical alloying on the basis of the ternary Mg₃₅Ti₁₀Ni₅₅ electrode alloy previously studied by the authors. It is found that all the three quaternary alloys possess an amorphous main phase and exhibit improved cycling stability than the original ternary Mg₃₅Ti₁₀Ni₅₅. The Zr-substituted alloy has also a higher discharge capacity. X-ray photoelectron spectroscopy (XPS) surface analysis reveals that on the surface of each alloy a multi-component oxide composite film is formed, which is more compact and corrosion resistant than the Mg(OH)₂ film and the (TiO₂)_x(NiO)_y(Mg(OH)₂)_z composite films reported previously. Auger electron spectroscopy (AES) analysis shows that the substituting elements tend to reduce the thickness of the passivation films. The thickness of composite oxide film on the alloys is in the following order: Mg₃₅Ti₁₀Ni₅₅>Mg₃₅Ti₅V₅Ni₅₅>Mg₃₅Ti₅Zr₅Ni₅₅>Mg₃₅Ti₅Cr₅Ni₅₅. The result agrees well with that of the polarization resistances (R_P) values obtained from the electrochemical impedance spectroscopy (EIS) Nyquist diagrams. It demonstrates that the thicker the passivation film is, the higher the R_P is and the more difficultly the charge transfer reaction proceeds. Anodic polarization curves indicate that the addition of Cr and Zr decreases effectively the corrosion current. However, the corrosion of the electrode alloys in the electrolyte is still high and proceeds constantly as the corrosion current remains almost constant during further cycles.