Effect of heating-rate on failure temperature of pre-loaded brass H62

The response and failure of brass H62 specimens subjected to different levels of pre-loaded stresses and heating rates were investigated using a Gleeble-1500 thermal-mechanical material testing system. The metallographs of the tested material were also observed and analyzed. It is found that the increase of either pre-loaded stress or heating-rate decreases the failure temperature. Metallographic analysis shows that high heating-rate may cause stronger local thermal inconsistency （LTI） and remarkably increase the microdefects in the material, which may markedly degrade the macroscopic mechanical properties of the material.     

粉末冶金制备换热管用HAl77-xTi铝黄铜合金及其性能表征

对Ti与HAl77铝黄铜建筑粉末充分混合,再对其实施放电等离子烧结及热挤压处理,分析不同固相烧结工艺下,在铝黄铜内加入Ti时引起的物相结构与组织分布状态的变化,并对试样的界面组织与力学强度进行了测试。研究结果表明:未添加Ti时,在HAl77基体内存在α与β两种组织相。加入Ti元素后在HAl77基体组织内形成了许多弥散态的第二相晶粒,当Ti含量逐渐增大后,得到的第二相颗粒也持续变多,呈现不规则的外形结构。当Ti的加入量逐渐增大后,合金试样各项力学性能参数发生了线性变化,铝黄铜获得了更优的力学性能;并且微裂纹数量降低,形成了更多韧窝并在断口部位呈均匀分布。在外力作用下,位错将会使Ti与Cu₂Ti₄O颗粒发生作用,阻碍基体变形,显著提高合金强度。     

Microstructure and properties of cutting magnesium-brass containing no lead

1 INTRODUCTIONLead-brass has excellent cutting ability , me-chanical and physical properties and is one of themost widely used copper alloys . The occupationratio of brass tube to all kinds of tubes reaches90 % in developed countries . The cutting lead-brass is a dual-phase brass and fine lead particlesdistribute dispersivelyin grains and on grain boun-ries . Theleadin wasted brass can easily beleachedand dissolvedinto soil .If the wasted lead-brass isburned in air ,the lead will become p…     

α黄铜选择性溶解的研究

采用恒电流E-t曲线与旋转盘环电极方法研究了α黄铜(Cu32Zn)在酸性Na2SO4和HNO3稀溶液中的阳极溶解行为,得到的典型E-t曲线上存在几个特征区,证明在较低电流密度条件下的初始阶段只存在Zn的选择性溶解。用恒电位法研究了Cu32Zn选择性溶解过程,得到了按抛物线衰减的暂态扩散曲线,由i-t-1/2直线关系求得了不同介质中Cu32Zn中Zn的固相扩散系数D在10-16～10-13cm2·s-1数量级,发现中性介质中测出的D值比酸性介质中要大两个数量级。     

黄铜中纳米级微裂纹的形核与钝化

黄铜薄膜试样在透射电镜中原位拉伸观察表明，在平衡条件下加载裂发出的位错纯化成无位错区，它是一个应变很高的异常弹性区。当缺口足够锐，外加载荷足够大时，这个非线弹性区中的应力有可能达到原子键合力，从而使纳米级微裂纹在无位错区中不连续形核，或从钝化的原裂纹顶端形核。这个微裂纹一昊形核，即使保持恒位移，也将钝化成空洞或缺口。     

硅黄铜铸件的渗漏缺陷分析

为了满足耐海水腐蚀、高导热率和承压能力要求,冷却器盖均采用硅黄铜制造。某厂在冷却器盖的生产过程中,铸件废品率高达60%,主要问题是铸件在水压测试中出现渗漏。分析了冷却器盖铸件的渗漏缺陷。结果表明:硅的加入量和浇注温度偏高,硅熔化不完全是导致此类铸件产生渗漏的主要原因。针对性地采取措施后,冷却器盖铸件的成品率大幅提高,达到了90%以上。     

浅析胶料与镀铜钢丝帘线粘合的影响因素

采用正交设计法和对比试验法，考察了硫黄、氧化锌、促进剂、炭黑以及某些工艺条件对胶料与镀铜钢丝帘线粘合力的影响。结果表明，硫黄品种对粘合力的影响不大；氧化锌用量增大，粘合力增大；用１．０份促进剂ＣＺ时的粘合力大于用１．３份促进剂ＤＺ；使用高结构炭黑可增大粘合力；胶料的混炼方法和硫化时间对粘合力的影响较大。     

黄铜超低浓度硝酸酸洗工艺的研究

通过对黄铜酸洗工艺的讨论,采用了超低浓度硝酸新工艺代替硫酸-双氧水体系的老工艺.结果表明:新工艺不仅大大降低了成本,而且零件表面的光洁度、均匀程度及抗变色能力都有了较为明显的提高,并且酸洗时升温较慢,可以连续生产;此外,对三废的处理也进行一定的探讨,新工艺中产生的NOx气体可以得到有效的控制,废液处理量少,同时新工艺中产生的废渣可以直接回收利用.     

低磷共聚物对黄铜的缓蚀作用

采用失重法、能量散射X-射线、电化学方法，研究了自制低磷共聚物在配制冷却水中对黄铜的缓蚀作用，分析了空白实验和加入低磷共聚物后黄铜试片的表面元素组成，探讨了低磷共聚物的缓蚀机理。结果表明，低磷共聚物在黄铜试片表面活性位置吸附抑制了阳极电化学过程。     

Electrochemical anticorrosion performance evaluation of Al2O3 coatings deposited by MOCVD on an industrial brass substrate

Alumina (Al₂O₃) coatings of different thickness were deposited on OT59 brass substrate (BS) using the metal organic chemical vapour deposition (MOCVD) technique to evaluate the corrosion performance by EIS measurements. The used precursor was dimethyl-aluminium-isopropoxide. Electrochemical characterizations of the deposited films were performed in a standard very aggressive acidic solution (aerated 1N H₂SO₄ at 25 °C up to 168 h of immersion time) by means of direct current method (Tafel curves) and electrochemical impedance spectroscopy (EIS). The Rutherford backscattering spectroscopy (RBS) indicated that the films are very pure with the correct Al₂O₃ stoichiometry, while the IR absorption spectra showed that the films did not contain any OH groups. The surface film morphology was investigated by atomic force microscopy (AFM) and displayed a globular texture. The films were very smooth, with a maximum root mean square roughness, for example, of 14 nm for a 0.96 μm thick coating. The EIS data confirmed, as expected, that a 2.40 μm Al₂O₃ layer ensures the best corrosion protection after 168 h of immersion in the very acidic environment used.