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11.
《能源学会志》2020,93(6):2505-2510
Selective hydrogenation of lignocellulosic biomass-derived chemicals is of great importance for future energy and chemical supply. So far formic acid is considered as one of the most promising materials for hydrogen storage. Herein, we report a novel pathway for the hydrogenation of Levogluosenone (LGO), a biorenewable platform chemical, to dihydrolevoglucosenone (Cyrene) and levoglucosanol (Lgol) using formic acid as a hydrogen source. Testing with typical hydrogenation catalysts indicated the crucial influence of the type on reaction selectivity and identified Pd/C as the most suitable catalyst. Among solvents screened, THF in combination with Pd/C showed the best performance for LGO hydrogenation, producing Cyrene in >99% yield at a low temperature (60 °C). Nevertheless, hydrogenation of Cyrene to Lgol required a harsher condition as a result of the difficult reduction property of its C=O bond. Elevating the reaction temperature to 180 °C and increasing double Pd dosage enabled a high yield of Lgol, attaining to 94.8%. 相似文献
12.
Novel core-shell-like Ni-supported hierarchical beta zeolite catalysts on bioethanol steam reforming
《International Journal of Hydrogen Energy》2020,45(33):16409-16420
Hierarchical-Beta zeolites have been hydrothermally synthesized by adding a new gemini organic surfactant. The used gemini surfactant play the role of a “pore-forming agents” on the mesoscale, on the same time, providing alkaline environment for the system. With this hierarchical Beta zeolite as the core support, we successfully prepared a shell layer of Ni-containing (22 wt%) petal-like core-shell-like catalyst and applied it to bioethanol steam reforming. At the reaction temperature of 350 °C–550 °C, the conversion rate of ethanol and the selectivity of hydrogen were always above 85% and 70%. After reaction of 100 h on stream at 400 °C, there were not obvious inactivation could be observed on NiNPs/OH-MBeta catalyst. 相似文献
13.
《International Journal of Hydrogen Energy》2020,45(31):15578-15588
One promising approach to design of high performance supercapacitors is based on the coupling the conductive porous carbon matrixes and the electroactive components. However, the main challenge to this goal is the maintaining the long cycling life, high power and high energy densities of the related capacitors. Herein, we reported on an electroactive composite based on biomass derived 3D graphene coupled with nickel-aluminum layer double hydroxides for manufacturing a cathode material in a supercapacitor. The electrode exhibits a remarkable specific capacitance of 1390 F g−1 at 1 Ag-1, and ultrahigh rate capability of 60% from 1 to 30 Ag-1, as well as excellent cycling stability with a capacitance retention of 92% after 5000 cycles. Furthermore, the electrode was used as the positive electrode against a Vulcan XC-72R as the negative electrode to assemble an asymmetric supercapacitor. The asymmetric supercapacitor device exhibited a maximum energy density of 173 Wh kg−1 and power density of 28.8 kW kg−1 as well as excellent cycling stability of 92% after 5000 cycles. The asymmetric supercapacitor could lighted up LED lamps with different colors more than 24 min. The work showed promising performance of further application in electrochemical devices. 相似文献
14.
《International Journal of Hydrogen Energy》2020,45(60):34679-34694
As an alternative, clean and sustainable solution, a biomass-based integrated power plant is designed and studied both thermodynamically and parametrically. Due to the environmental, economic and performance related advantages, the design of multigeneration energy plants is now increasing and becoming widespread technology. Biomass, which is one of the renewable power sources, is selected for the plant to be more sustainable and environmentally friendly. The proposed system using biomass as an energy source consists of several sub-plants integrated to utilize the waste thermal energy and to generate useful products which are electricity, hydrogen, fresh and hot water, heating, and cooling. In this paper, comprehensive work is carried out for plant modeling and simulation. The thermodynamic assessment results reveal that both energetic and exergetic effectiveness of the whole plant are 56.17% and 52.83%, which are affected positively by varying the reference state conditions, combustor temperature, biomass gasifier temperature, SOFC temperature and pressure, and biomass mass flow rate. In addition, the lowest energy and exergy efficiencies occur in the ORC combined ejector refrigeration cycle with 21.87% and 18.26%, respectively. 相似文献
15.
16.
《能源学会志》2020,93(4):1261-1270
The chemical looping gasification (CLG) of rice husk was conducted in a fixed bed reactor to analyze the effects of the ratio of oxygen carrier to rice husk (O/C), temperature, residence time and preparation methods of Fe-based oxygen carriers. The yield of gas, H2/CO, lower heating value of syngas (LHV), conversion efficiency and performance parameters were analyzed to obtain CLG reaction characterization and optimal reaction conditions. Results showed that when O/C increased from 0.5 to 3.0, the gas production, H2/CO, CO2 yield and carbon conversion efficiency gradually increased, while the yield of H2, CO and CH4 and LHV gradually decreased. At the same time, a highest gasification efficiency was obtained when O/C was 1.5. As increasing temperature, the gas production, CO yield, carbon conversion efficiency and gasification efficiency gradually increased, while the yield of H2, CH4 and CO2, H2/CO and LHV gradually decreased. Sintering and agglomeration was obvious when the temperature was higher than 850 °C. When the reaction time increased from 10 min to 60 min, the gas production, CO yield, carbon conversion efficiency and gasification efficiency gradually increased, but the yield of H2, H2/CO and LHV decreased, among which 30 min was the best reaction residence time. In addition, coprecipitation was the best preparation method among several preparation methods of oxygen carrier. Finally, O/C of 1.5, 800 °C, 30 min and coprecipitation preparation method of oxygen carrier were the optimal parameters to obtain a gasification efficiency of 26.88%, H2 content of 35.64%, syngas content of 56.40%, H2/CO ratio of 1.72 and LHV of 12.25 MJ/Nm3. 相似文献
17.
《International Journal of Hydrogen Energy》2020,45(1):230-262
The Co-Current reactor gasifier is a promising technique, owing to its good performance and less residue content. Even though it can be used only for low moisture feedstock, it is needed improvement by incorporating modifications in the design of reactor, feeding system, air supply system, preheating air or feedstock, discharge system, recirculation technique, and co-gasification. Many of the researchers found that various improvement methods have been done to improve the performance of the gasifier at different operating condition. Therefore, in this paper a detailed review has been made to study about that developments of Co-Current gasifier and their effects on the performance of the gasifier. Further to improve the performance a suitable method for the gasifier is identified. A comparision with various methods reveals that design modification showed better performance, higher producer gas yield and less pollution. 相似文献
18.
19.
In this work the primary combustion zone of a modified, commercial, small-scale boiler was investigated during staged combustion of wood-chips. Experimental research on thermal conversion of biomass in fixed beds is necessary to supply reliable data for gas phase combustion model validation and optimization. Furthermore, scruting of pollutant emission formation and combustion efficiency enhancement can be conducted. Two different fuel moistures were used while the primary combustion zone of a small-scale boiler was investigated as a function of the primary air ratio. The combustible products leaving the fuel layer were analyzed under continuous operation by an extractive method. This approach is new in the field of small-scale biomass combustion research and considers the strong coupling between the products leaving the fuel bed and the heat fluxes emitted by the flame of the secondary combustion zone. Additionally, fine particulate matter emissions were quantified to study the effect of varying primary air ratio and different fuel moisture on particulate formation. Results show that the primary air ratio and the fuel moisture have a significant influence on the primary combustion products composition, on the fuel bed behavior and on fine particulate matter emissions. At low primary air ratios, tars constitute a significant part of the heating value of primary combustion products. The smallest amount of particulate emissions was found at low primary air ratio and low fuel moisture. Experimental data was validated with an elemental balance, which showed perfect accordance. 相似文献
20.
The present contribution addresses the results of a longitudinal study in a ‘bioenergy-region’ concerning the public acceptance of biomass plants and the corresponding influencing factors. Using a standardized questionnaire, 423 persons were polled between 2009 and 2011 on three points of measurement in four places in the bioenergy-region Altmark. One main result of the study is that the reported public acceptance remains constantly high over time; nevertheless it became evident that the respective influencing factors differ in their strength, whereas the perceived regional benefit shows a strong connection to the reported public acceptance of biomass plants at each point of measurement. Concluding the research results, the acceptance of biomass plants doesn't seem to be a fixed construct, but has to be seen in context of the respective experiences with plants on a local level over time.In addition to the local population, key actors of the regional biomass sector were also interviewed (N = 26). The analyses show significant differences in the perception and evaluation of the current informational level between the population and the key actors. Furthermore, the key actors estimated the utilisation of biomass even more positively and expected a greater ‘signal function’ of the bioenergy-region-project compared to the population. 相似文献