汽车尾气净化催化剂的研究现状及其进展

综述了汽车尾气净化催化剂的3个组成部分－载体、活性涂层和活性组分的研究现状及其研究进展，指出了汽车尾气净化催化剂中急需解决的关键问题。     

基于TCP的网络拥塞控制机制

本文介绍了网络传输中TCP拥塞控制的基本概念、产生原因、及TCP拥塞控制机制,并初步探讨了TCP拥塞控制机制面临的一些主要问题。     

Characteristics of graphite felt electrode electrochemically oxidized for vanadium redox battery application

The graphite felt was oxidized at a positive electrode potential in sulfuric acid solution.The electrochemical performance of the treated graphite felt served as electrode for vanadium redox battery was investigated with FT-IR,SEM,XPS,BET,cyclic voltammetry and testing VRB system,respectively.The results show that the molar ratio of O to C increases from 0.085 to 0.15 due to the increase of—COOH functional groups during electrochemical oxidation treatment,and the GF surface is eroded by electrochemical oxidation,resulting in the surface area increase from 0.33 m2/g to 0.49 m 2/g.The VRB with modified GF electrode exhibits excellent performance under a current density of 30 mA/cm 2 .The average current efficiency reaches 94%and average voltage efficiency reaches 85%.The improvement of electrochemical activity for the electrode is ascribed to the increase of the number of—COOH group and the special surface of GF.     

不同锰源合成尖晶石型LixMn2O4及其性能

以自制γ—MnO2(SPDM)和电解二氧化锰(EDM)为原料，采用流变相法合成了尖晶石型锂锰氧材料。应用XRD，SEM，TG和DSC等手段研究了原材料性质和配比等因素对合成尖晶石型锂锰氧的结构、粒径、比表面积以及充、放电性能的影响。结果表明，采用流变相法在700-760℃下，反应12h即可得到均相、无杂质、锰平均氧化价态接近3．5的LixMn2O4正极材料；以SPDM为锰源较EMD为锰源在相同条件下合成的尖晶石材料的首次充、放电容量更高，比表面积更大，粒度更小；当原材料中n(Li)／n(Mn)在一定范围内变化时，合成的锂锰氧的晶格常数随材料中锂与锰摩尔比的增大而减小。     

Preparation and electrochemical performance of nanosized Co3O4 via hydrothermal method

The hydrotalcite-type cobalt compounds were prepared through oxidation of Co（OH）2 gel using NH4OH as precipitating agent and H2O2 as oxidant. These hydrotalcite-type cobalt compounds were transformed into Co3O4 through hydrothermal decomposition with nanostructural deformation. The precursor and product were characterized by Fourier-transform infrared（FT-IR） spectrum, X-ray diffractometry（XRD） and transmission electron microscopy（TEM）. The electrochemical performances of as-prepared nanosized Co3O4 as anode materials in lithium-ion batteries were tested by charge-discharge test in the voltage range of 0-3.0 V. The influence of morphology of Co3O4 particle on the capacity and cycling performance was studied. The results show that the shape and size of the final product can be controlled by altering cobalt sources. The irregular cubic Co3O4 with the average particle size of about 10 nm shows the best electrochemical performance. After 10 charge-discharge cycles, the specific charge capacity retains 555 mA.h/g.     

锰酸锂/碳纳米管复合电极的电化学特性

以多壁碳纳米管(multi-walled carbon nanombes,MWCNTs)作为正极材料导电剂制备了LiMn2O4/MWCNTs复合电极.扫描电镜照片显示:MWCNTs形成三维网状结构并且均匀的分散在LiMn2O4活性颗粒之间.以1 C倍率进行充放电测试,质量分数分别为2%,5%和8%MWCNTs的正极材料首次放电容量为分别为96.0,105.5 mAh/g和114.8mAh/g.质量比为5%的乙炔黑(acetylene black,AB)电极放电容量为98.0mAh/g,说明MWCNTs能有效提高电极材料的电子电导率以及活性物质的利用率.交流阻抗测试结果表明:电极过程中电荷传递电阻随MWCNTs含量的增加而减小,并由此计算得出相同导电剂含量的LiMn2O4/MWCNTs和LiMn2O4/AB复合电极的电荷传递活化能为27.5kJ/mol和32.3kJ/mol.     

Citrate-stabilized CdSe/CdS quantum dots as fluorescence probe for protein determination

A rapid, ultrasensitive and convenient fluorescence measurement technology based on the enhancement of the fluorescence intensity resulting from the interaction of functionalized CdSe/CdS quantum dots (QDs) with bovine serum albumin (BSA) was proposed. The citrate-stabilized CdSe/CdS (QDs) were synthesized by using Se powder and Na₂S as precursors instead of any pyrophoric organometallic precursors. The modified CdSe/CdS QDs are brighter and more stable against photobleaching in comparison with organic fluorophores. At pH 7.0, the fluorescence signal of CdSe/CdS is enhanced by increasing the concentration of BSA in the range of 0.1–10 μg/mL, and the low detection limit is 0.06 μg/mL. A linear relationship between the enhanced fluorescence peak intensity (ΔF) and BSA concentration (c) is established using equation ΔF=50.7c+16.4 (R=0.996 36). Results of determination for BSA in three synthetic samples are identical with the true values, and the recovery (98.9%–102.4%) and relative standard deviation (RSD, 1.8%–2.5%) are satisfactory.     

简易温室在葡萄生产上的应用

通过对简易温室在葡萄生产应用方面的论述,探索并总结出了利用简易温室进行高档次葡萄生产中的一些新经验、新技术.     

天荒坪抽水蓄能电站输水系统设计

天荒坪工程上游输水系统为斜井，一洞三机，输水道总长与平均发电水头的比值为２．５。６台机组有两个相同的水力单元，中心距为５９．５４ｍ，承受６８０ｍ的最大静水头，输水系统全长１４３５ｍ。尾水部分长２４５．３～２５３．８ｍ，为单机单洞，共６条尾水洞。岔管采用钢筋混凝土结构，平底两次分岔，分岔角度为６０°。高压钢管承受最大内压为８．７ＭＰａ，近厂房段钢管按明管设计，离厂房边线１８ｍ外按埋管设计并考虑钢管、衬砌和围岩三者联合作用。为保证钢衬回填质量，高压钢管均不设加劲环，在回填混凝土和回填浆液中掺适量微膨胀剂，并采用设置排水廊道和钢管外排水等措施降低外水压力。经充水试验观察，高压钢管部位缝隙值小于设计值，外水压力接近零，效果较好。