微波辐照载锰活性焦脱硝实验研究

通过在活性焦上负载Mn2O3实现微波低功率（200 W）高效脱除NO。实验发现,经硝酸氧化处理和负载Mn2O3,活性焦表面的羰基和羧基等含氧官能团含量增加,微波辐照使得活性焦比表面积和微孔体积大幅增加,为反应气体在活性焦表面吸附提供丰富的表面活性位,有利于NO的脱除。硝酸处理后的活性焦负载Mn2O3,脱硝效率能稳定达到85%以上,负载Mn2O3使得微波诱导的放电强度增强,等离子体浓度增加,更多的稳定态NO分子被转化为激发态,促进了NO还原反应的发生。     

基于区域偏差控制和荷电状态分区的电池储能参与二次调频控制策略

随着日益增多的非传统能源进入发电领域,电力系统的频率波动问题越发严峻。火电机组调频缺陷是响应时间长、爬坡速度慢;而电池储能因其响应迅速、调节灵活等优点逐渐成为电力系统调频的研究热点。本文首先介绍了储能参与电力系统二次调频的区域控制偏差和区域控制需求2种基本方式,并分析了这2种基本控制方式的特点;对区域控制偏差和储能系统电池的荷电状态（SOC）进行分区,在不同区域计及频率调节需求和储能系统出力特点提出不同的调频方式,并在区域控制偏差正常调节和SOC正常充放电状态下,采用模糊控制器平滑储能系统出力;最后利用MATLAB/Simulink仿真平台建立2区域互联仿真系统,仿真结果证明了区域偏差控制和SOC分区控制策略的可行性。     

脱硫废水低温烟气蒸发零排放系统平衡计算

2019年7月在湖北鄂州发电厂投运了一套利用低温烟气余热蒸发脱硫废水的零排放处理系统。为了优化该系统运行操作参数,在投运初期调整试验过程中采用系统水平衡、盐平衡和热量平衡等计算方法进行了平衡试验研究。结果表明:在系统稳定运行条件下,处理脱硫废水能力达到16.19 m?/h;系统烟气放热和浆液吸热基本达到平衡;排泥量（泥与废水质量比）控制在0.165可维持系统盐平衡。     

SCAL型间接空冷系统循环水中溶氧量变化规律及其对pH值间接影响

表面式换热器铝制散热器（SCAL）型间接空冷（间冷）机组已经成为解决我国北方富煤贫水地区发电的有效措施,该机组SCAL型间冷系统稳定运行过程中常出现循环水pH值异常升高的现象。由于系统内散热器采用铝材质,pH值异常升高会破坏铝管表面氧化膜,导致散热器腐蚀甚至泄漏,因此循环水pH值异常升高是该系统运行的难题。通过对SCAL型间冷系统结构的分析、水质调研,分析了系统中的动态变量,通过理论计算和工业试验验证对该问题进行了深入研究。结果表明:SCAL型间冷系统在运行期间基本处于密闭状态,外界氧气难以扩散进入,系统循环水中溶解氧的来源为系统运行前除盐水中溶解的氧气;碳钢的腐蚀反应是系统中溶解氧主要的消耗方式;溶氧量变化改变了碳钢腐蚀产物的类型,当系统中溶氧量较低时,碳钢腐蚀生成的Fe(OH)2具有较大的溶度积,能够导致循环水pH值升高。     

生物质直燃发电大气污染物超低排放技术路线分析

总结了生物质燃料与煤的元素含量的差异,分析了生物质锅炉积灰、结渣、腐蚀的机理,梳理了生物质锅炉的烟气特点,并对选择性非催化还原脱硝技术、选择性催化还原脱硝技术、湿法脱硫技术在生物质电厂应用的局限性进行了讨论和总结。结果表明:固态高分子脱硝和催化剂脱硝脱硫均需特殊催化剂或脱硝剂,属于专利产品,运行成本高;氧化脱硝技术属于氧化吸收反应,产生易溶于水的硝酸盐,部分地区禁止采用该技术;陶瓷催化滤管一体化脱除技术运行维护简单,锅炉过氧燃烧可提高燃烧效率,延长空气预热器使用寿命,而且没有脱硫废水、烟囱防腐、白色烟羽等相关问题,适用于生物质锅炉硫、尘、硝超低排放。     

PHYSICAL SIMULATION OF INTERFACIAL CONDITIONS IN HOT FORMING OF STEELS

1.~nonNUInericalmodellingbythefiniteelement(FE)methodhasbecomeaneffectiveandeconomyicmeansforsimulatingmetalfoeingprocesses.However,accuratemodellingdemandsthecorrectdefinitionandinputsofthedataforthethermalandphysicalpIDPertiesoftheworkpieceandtoolmaterials,theboUndaryconditionsattheworkpiece--toolinterfaceandinotherareas,inadditiontoappropriatemeshgenerationandnumericalsolutions.Althoughmostofthematerialdataareavailable,thedataforinterfacialheattransferandfrictionconditions,Whichhavesubst…     

Advances in the research of nitrogen containing stainless steels

The current status of nitrogen containing stainless steels at home and aboard has been introduced. The function and existing forms of nitrogen in the stainless steels, influence of nitrogen on mechanical properties and anti-corrosion properties as well as the application of nitrogen containing cast stainless steels were discussed in this paper. It is clear that nitrogen will be a potential and important alloying element in stainless steels. And Argon Oxygen Decarbonization (AOD) refining can provide an advanced manufacture process for nitrogen containing stainless steels with ultra-low- carbon and high cleanliness.     

3D Modeling of the preparation process of metal rubber material

Based on the analysis of the preparation of metal rubber (MR) and two pivotal hypotheses,the uniform distribution and the unaltered topological structure of wires in the radial direction of columns in the punch process,a 3D parametrical model was established based on four approaches:helix-making,planar roughcast-weaving,planar roughcast-rolling,and 3D roughcast punching.In the modeling process,5 lattice types of weave patterns in planar roughcast were put forward,and 10 quantificational modeling parameters ...     

Relationship between the microstructure and reaction performance of aluminosilicate

A systematic study was conducted to comprehend the mechanism of thermal activation of silica-alumina materials by using 29 Si and 27 Al magnetic angle spinning nuclear magnetic resonance (MAS NMR) spectroscopy.The reaction performance of silica-alumina-based materials with different molar ratios of Si/Al,which were thermally activated,was also investigated.With the increase in calcining temperature,the coordination of Al in metakaolin becomes four,five,and six firstly,and then transforms completely to four ...     

Decarburization rate of RH refining for ultra low carbon steel

The decarburization behaviors of ultra low carbon steel in a 210-t RH vacuum degasser were investigated under practical operating conditions.According to the apparent decarburization rate constant (KC) calculated by the carbon content in the samples taken from the hot melt in a ladle at an interval of 1-2 min,it is observed that the total decarburization reaction period in RH can be divided into the quick decarburization period and the stagnant decarburization period,which is quite different from the tradit...