Activation of Ni/A12O3 catalysts through modification of the Al2O3 support

The effect of alumina pretreatment on the performance of alumina supported nickel catalysts was demonstrated in gas phase hydrogenation of toluene to methylcyclohexane. The state of the alumina was changed from pure to pure phase through various heat treatments in air. The catalysts were prepared from vapor phase by saturating the accessible binding sites on the pretreated alumina with the nickel precursor. The highest number of active sites for hydrogenation was observed for catalysts prepared on alumina having an incomplete phase transition and a / alumina phase ratio between 0.5 and 10. Results from temperature programmed desorption (TPD) studies revealed that a maximum in weakly chemisorbed hydrogen as well as in total amount of desorbed hydrogen was found for the same catalysts. By hydrogen chemisorption studies the total hydrogen uptake was found to correlate with the observed hydrogenation maximum. It is suggested that both the chemical and physical properties of the alumina influence the activity. An optimal metal-support interaction and structural defects on the alumina due to the phase transition can explain the observed maximum in the number of active sites and in hydrogen uptake.     

决策表中基于对象的μ-约简方法研究

研究了不协调决策表中基于对象的μ-约简问题,给出了μ-约简的一些性质及等价定义,得到了μ-约简的判定定理和相应的可辨识矩阵及辨识公式,从而提供了不协调目标信息系统知识约简的新方法。并通过实例将决策表中基于对象的约简与整体约简进行了对比,结果表明前者可以得到更简洁的知识。该方法也适用于协调目标信息系统。     

Interfacial adhesion reaction of polyethylene and starch blends using maleated polyethylene reactive compatibilizer

The interfacial reaction of the polyethylene (PE)/starch blend system containing the reactive compatibilizer maleated polyethylene (m‐PE) was directly characterized by Fourier transform infrared (FTIR) spectroscopy. A significant amount of anhydride groups on m‐PE existed as hydrolyzed forms, resulting in a large amount of carboxyl groups. Using a vacuum‐heating‐cell designed in the laboratory, the carboxyl groups were successfully transformed into the dehydrolyzed state (i.e., anhydride group). This result enabled the direct spectroscopic observation of chemical reaction occurring at the interface. For the PE/starch blend system containing m‐PE, the chemical reaction at the interface was verified by the evolution of ester and carboxyl groups in the FTIR spectra. The effect of the reactive compatibilizer on the interfacial morphology was also examined by scanning electron micrography (SEM). Enhanced interfacial adhesion was clearly observed for the blend system containing reactive compatibilizer. Tensile strengths of blend systems containing m‐PE also increased noticeably compared with the corresponding system without compatibilizer. A similar observation was made for the breaking elongation data. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 83: 767–776, 2002     

2500m^3高炉基础自动化系统构成

介绍新钢2×2500m^3高炉基础自动化系统各个子系统的构成,以及环形网络的构成及配置方法。     

CM3上μC/OS-Ⅱ任务切换和通信机制的应用

针对μC/OS-II系统任务调度处理的局限性,以对Cortex-M3上μC/OS-II源代码的分析为基础,提出了任务切换和任务间通信不可分割的观点,给出了利用任务间通信机制协调多任务运行以解决任务管理局限性的方法,分析了系统各种通信类型的特点,给出了其应用原则和使用方法。由此说明任务间通信在实现多任务协调运行中的重要性,并论证了通信机制的正确使用可以解决大多数系统任务调度局限性带来的问题。     

Oxidation behavior of 2.25Cr-1Mo steel with prior tempering at different temperatures

The oxidation behavior of a normalized 2.25Cr-1Mo steel tempered previously for 10 hr at different temperatures between 873 and 1023 K has been studied up to a maximum duration of 1000 hr in air at 773–973 K. The oxidation resistance of the steel was found to decrease significantly with the temperature of tempering. Tempering of this steel is reported to cause microstructural changes involving precipitation of Cr as carbides and a decrease in the effective (free) Cr contents, that could influence the oxidation resistance of the Cr-containing alloys. Relative compositions across the thickness of the oxide scales, as analyzed by SEM/EDX and SIMS, suggest that a less Cr-rich (and less protective) and thicker scale on the steel formed because previous tempering caused extensive depletion of free Cr.     

土坝在设计和运行中防治白蚁危害的研究

以往在水库大坝发生白蚁危害病情后,方采取工程措施进行除险加固。为把白蚁控制在危害之前,本文结合工程典型实例,根据气候、土壤、植被等建坝外部环境条件和白蚁生存需具备的土、水、食料基本因素,考虑白蚁具有喜温好湿、畏光避风、蔓延等生物特性,通过填筑坝料土质分析,研究了水库蓄水坝体浸润性、坝土级配及湿度与白蚁生存之间的关系,并提出相应对策以达到防患于未然。结果表明,坝体结构设计时,通过截断白蚁吸水水源,增加坝体干燥区,缩限白蚁生存空间;通过调整坝料级配,防止白蚁筑巢;合理采用护坡,切断白蚁食源。同时,结合水库运行管理,采取"预防为主,综合防治"的措施,使坝体周边一定范围内成为无蚁区,防止白蚁蔓延至坝,维护水库大坝的安全。     

基于STM32的逐阳帆控制系统设计

针对传统太阳能跟踪系统现场调试复杂、可靠性不够高的问题,提出一种基于STM32的太阳能跟踪系统设计。该系统为单轴跟踪系统,通过获取太阳能板的地理位置和当前时间信息用一定算法算出太阳的方位角,驱动电机,实现对太阳的跟踪;采用基于Zig Bee技术的无线通讯系统,具有群簇控制能力,简化现场调试过程;通过Mod Bus协议实现控制系统信息上报,便于后台管理;提供多种工作模式,提高系统的抗风、抗雪性能;通过在控制芯片片内Flash写入备份程序,保证系统主程序出现问题后,系统跳转至备份程序继续运行,提高系统的可靠性。在实际现场应用中,该系统具有系统运行稳定、升级维护方便、使用寿命长的特点。     

广告屏受冲击时的现场实时抓拍系统设计

针对广告屏受冲击时现场情况无法获悉的缺点,设计了一种广告屏受冲击时现场的实时抓拍系统.系统由加速度传感器、摄像头OV2640、SD卡、以太网控制器、以太网接口、路由器和STM32F103ZET6微控制器构成.可根据冲击强度实时抓拍现场情况,将照片信息存入SD卡中,并通过以太网实时上传给监控中心.该系统具有成本低、实时性强、稳定可靠等优点.     

μC/OS-Ⅱ事件标志组系统漏洞及其修复

μC/OS-Ⅱ的事件标志组在任务间的同步和通信中有着不可忽视的作用。在应用过程中,发现事件标志组存在系统缺陷,通过对其进行深入分析,提出了解决问题的方案,本文详细地描述了解决方案的具体方式及步骤。该解决方案没有改变系统函数接口,对系统实时性影响也较小,有很强的兼容性及可行性。