新型有机硫水解催化剂的研制

介绍了LS-04新型有机硫水解催化剂的研制、表征及活性评价。该催化剂以氧化铝为主要原料,采用转动成型法制备载体,碱金属氧化物为活性组分,利用浸渍法制备而成。相比国外同类催化剂,该催化剂具有较高的侧压强度、更优异的水解活性及良好的活性稳定性,综合性能优于国外同类催化剂。     

多面体低聚倍半硅氧烷的合成研究进展

首先介绍了多面体低聚倍半硅氧烷(POSS)的结构、分类和性质,然后综述了三官能度硅烷或四官能度硅烷在酸、碱和有机盐催化下通过水解缩合反应合成POSS的研究进展,以及以POSS为母体、通过封端关笼法、闭环法和官能团转化法合成POSS的研究进展。     

Disulfides as Sulfonylating Precursors for the Synthesis of Sulfone‐Containing Oxindoles

The first facile one‐pot synthesis of sulfone‐containing oxindoles with easily accessible disulfides as the sulfonylating precursors is described. This reaction occurs smoothly under transition metal‐free conditions and shows excellent functional group tolerance, allowing the facile and efficient green synthesis of various sulfone‐containing oxindoles in aqueous solution. Preliminary mechanistic studies reveal that both water (H₂O) and potassium persulfate (K₂S₂O₈) can be the oxygen source of the sulfone groups in the products.

     

水解酸化／两段生物接触氧化法处理锦纶6生产废水

锦纶6生产废水为可生化性良好的含氮有机废水，采用水解酸化-两段生物接触氧化工艺处理该废水，考察了硝化液回流比、水力停留时间及溶解氧浓度对处理效果的影响。结果表明，在硝化液回流比为3、水力停留时间为12．1h以及水解酸化池和1 ^#、2^#接触氧化池的溶解氧浓度分别为（0．5～1．0）、（3．0～3．5）和（1．8～2．3）mg／L的条件下，系统的处理效果最好，对COD和TN的去除率分别为95．85％和61．04％，出水水质达到了《污水综合排放标准》的一级标准。     

含油废水处理后回用于港区除尘系统的设计与运行

介绍了某含油废水回用工程的设计、运行和管理,该回用工程设计处理量为400 m3／d。采用了水解酸化预处理+生物接触氧化+生物活性炭的处理工艺,处理后的出水用于港区煤炭储存场的除尘系统。运行结果表明,本工程的处理出水水质明显优于生活杂用水水质标准的要求,出水可用于冲洗地面、洒水抑尘等用途。     

硫酸盐对抗生素废水厌氧生物处理的影响

采用水解酸化反应器与复合厌氧反应器组合工艺处理高浓度抗生素废水 ,试验结果表明 ,水解酸化反应器最大容积负荷可达 16 .84kgCOD/ (m3·d) ,有效降低了毒性物质的抑制作用 ;复合厌氧反应器最大容积负荷可达 8.5 7kgCOD/ (m3·d) ;系统进水最大SO2 - 4浓度为 132 5mg/L ,COD/SO2 - 4值最低为 3,COD与SO2 - 4的总去除率分别为 75 .5 %和 95 .2 % ,对各种抑制物质和冲击负荷表现出很好的适应性。试验证明 ,水解酸化—厌氧消化工艺可以有效消除SO2 - 4对厌氧处理的影响 ,对于处理高浓度抗生素废水是经济可行的     

水解酸化/前置反硝化上向流生物滤池工艺处理城镇污水

结合江门市丰乐污水处理厂工程,介绍和总结了水解酸化/前置反硝化上向流生物滤池工艺及其运行情况.试运行期间对COD、SS、BOD5、NH3-N、TP和TN的去除率分别达到88.9%、96.6%、95.4%、97.5%、87.2%和68.4%.该工艺具有占地面积小、处理效果好、水量适应性强、污泥产量少和运行管理方便等特点.     

ABR水解/生物接触氧化处理印染废水

采用厌氧折流板反应器（ABR）水解／生物接触氧化法处理印染废水，在ABR的HRT为12h的条件下测定了ABR各格室及生物接触氧化池出水的色度、COD。结果表明，ABR出水色度达到了纺织染整行业一级排放标准，最终出水COD达到了行业二级排放标准。     

FDN—J高效混凝土减水剂的研制

ＦＤＮ—Ｊ高效混凝土减水剂是利用新疆八一钢铁公司煤焦油提取的粗萘为原料研制而成。该剂对混凝土的工作性和物理力学性能均有显著的改变和较好的技术经济效果。     

Enzyme-assisted extraction of chicken skin protein hydrolysates and fat: Degree of hydrolysis affects the physicochemical and functional properties

Enzyme-assisted extraction (EAE) of oils/fats involves the disruption of the cell wall of source material using enzymes to facilitate the release of oil. When proteases are used as the enzyme, EAE ends in the extracted oil as well as the protein hydrolysates. Herein, the EAE (using a commercial protease, Alcalase) was exploited to obtain fat and protein hydrolysates from chicken skin. Degree of hydrolysis (DH, the percentage ratio of cleaved peptide bonds), which showed a logarithmic correlation with the reaction time, was found to affect the properties of the products. As the DH increased, the peptide chain length of protein hydrolysates decreased which was confirmed by SDS-PAGE analysis. With the increase of DH, the emulsifying activity index, foaming capacity, and oil holding capacity of the hydrolysates decreased but the solubility and emulsion stability index increased (p < 0.05). The DPPH free radical scavenging activity of the hydrolysates increased with the DH up to DH = 39.62% but decreased thereafter (p < 0.05). EAE resulted in a rise in fat yield and the fat contained a higher amount of unsaponifiables and lower free fatty acids (FFA) content, as compared to the control treatment (No enzyme, 80°C, 2 h, p < 0.05). DH affected the fat yield and the unsaponifiables content of the fat, positively (p < 0.05). However, it did not affect the fat FFA content and iodine value (p > 0.05). Results obtained here showed DH can be used as an effective measure for controlling the physicochemical and functional properties of chicken skin protein hydrolysates and fat in the EAE process.