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91.
Effects of high solid concentrations on the efficacy of enzymatic hydrolysis of yeast cells and the taste characteristics of the resulting hydrolysates 下载免费PDF全文
Chun Cui Yangpeng Qian Weizheng Sun Haifeng Zhao 《International Journal of Food Science & Technology》2016,51(5):1298-1304
Effects of solid concentrations on enzymatic hydrolysis of yeast cells and the taste characteristics of the resulting hydrolysates were examined. Results showed that increased solid concentrations ranging from 10% to 30% resulted in a mild increase in degree of hydrolysis (DH) of hydrolysates during the whole hydrolysis process, whereas an obvious inhibition effect on DH was found at hydrolysates with 40% of solid concentration. The levels of amino nitrogen and total nitrogen of supernatant with 40% of solid concentration were six‐fold higher than those of hydrolysates with 10% of solid concentration at all hydrolysis time. After 21 h of hydrolysis, there was no significant difference in molecular weight distributions of hydrolysates with different solid concentrations, while a significant increase in amino acid contents of hydrolysates with high solid concentrations was found. Results from sensory evaluation showed that the intensities of umami, mouthfulness and continuity in umami solution could be significantly improved by supplementing with the resulting hydrolysates with high solid concentrations. 相似文献
92.
Candida Antarctica lipase B (CALB), a specific enzyme to catalyze the hydrolysis of esters, can be a good candidate for acetylcholine (ACh) hydrolysis instead of acetylcholinesterase. The catalytic mechanism of the CALB acylation, as the first stage in the hydrolysis reaction, with ACh and methylcaprylate (MEC) has been examined by using density functional theory technique. The significant emphasis of this article is on the free energy barriers for the acylation step of hydrolysis reactions. Computed free energy barriers of the first step are 9.2 and 15.9 kcal mol−1, but for the second step are 7.9 and 11.6 kcal mol−1 for MEC and ACh respectively. Activation free energies are in the comparable and acceptable range and imply both of two reactions are theoretically possible. The stability role of the adjacent amino acids was examined by using two applied tools. It is exposed that the oxyanion hole residues decrease energy barriers by stabilizing the transition state structures. 相似文献
93.
94.
Wei Cheng Yumei Peng Yi Wang Weidong Jiang Yan Long Guangyin Fan 《International Journal of Hydrogen Energy》2021,46(2):2204-2212
Hydrogen evolution from ammonia borane (AB) hydrolysis is of great importance considering the ever-increasing demand for green and sustainable energy. However, the development of a facile and efficient strategy to construct high-performance catalysts remains a grand challenge. Herein, we report an amino-group and space-confinement assisted strategy to fabricate Rh nanoparticles (NPs) using amino-functionalized metal-organic-frameworks (UiO-66-NH2) as a NP matrix (Rh/UiO-66-NH2). Owing to the coordination effect of amino-group and space-confinement of UiO-66-NH2, small and well-distributed Rh NPs with a diameter of 3.38 nm are successfully achieved, which can be served as efficient catalysts for AB hydrolysis at room temperature. The maximum turnover frequency of 876.7 min?1 is obtained by using the Rh/UiO-66-NH2 with an optimal Rh loading of 4.38 wt% and AB concentration of 0.2 M at 25 °C, outperforming most of the previously developed Rh-based catalysts. The catalyst is also stable in repetitive cycles for five times. The high performance of this catalyst must be ascribed to the structural properties of UiO-66-NH2, which enable the formation of small and well-dispersed Rh NPs with abundant accessible active sites. This study provides a simple and efficient method to significantly enhance the catalytic performance of Rh for AB hydrolysis. 相似文献
95.
《International Journal of Hydrogen Energy》2019,44(31):16548-16556
Development of supported ligand-free ultrafine Rh nanocatalysts for efficient catalytic hydrogen evolution from ammonia borane (AB) is of importance but remains a tremendous challenge. Here, ultrafine and ligand-free Rh nanoparticles (NPs) (2.19 nm in diameter) were in-situ decorated on porous phosphorus-functionalized carbon (PPC) prepared by pyrolyzing hyper-cross-linked networks of triphenylphosphine and benzene. The resultant Rh/PPC showed excellent hydrogen production activity from AB hydrolysis (Turnover frequency: 806 min−1). Kinetic investigations indicated that AB hydrolysis using Rh/PPC exhibited first-order and zero-order reactions with Rh and AB concentrations, respectively. Activation energy (Ea) toward hydrogen generation from AB with Rh/PPC is as low as 22.7 kJ/mol. The Rh/PPC catalyst was recyclable and reusable for at least four times. The oxygen- and phosphorus-functional groups are beneficial for the affinity of Rh complex on the PPC surface, resulting in ultrafine and ligand-free Rh NPs with high dispersity and ability to supply abundant surface accessibility to catalytically active sites for AB hydrolysis. This study proposes a feasible approach for the synthesis of ultrafine and ligand-free metal NPs supported on heteroatom-doped carbon by using hyper-cross-linked networks. 相似文献
96.
Sibel Duman Bülent Kaya Fatma Caf Barış Enez Sema Aguloğlu Fincan 《International Journal of Hydrogen Energy》2021,46(29):15410-15430
For the first time in this innovative study, microorganisms such as Bacillus simplex bacteria, mostly used in biological activity studies, are used as a bio-supporter agent of iron to release hydrogen from sodium borohydride hydrolysis at 25.0 ± 0.1 °C. The goal is to investigate thoroughly sodium borohydride hydrolysis catalyzed by Fe2O3 nanoparticles impregnated on microorganism such as Bacillus simplex (BS) bacteria (Fe2O3@BS NPs) known with strong antibacterial properties, which makes innovative them a candidate for hydrolysis reaction. This study was focused on the preparation, identification, and catalytic use of biocatalyst-like Fe2O3@BS NPs for hydrogen release from the sodium borohydride hydrolysis at 25.0 ± 0.1 °C. The characterization results made after and before hydrolysis reaction using by SEM/SEM-EDX, FT-IR, XRD, UV–vis, XPS, DLS, ELS Zeta potential, ESR, and TEM techniques reveal the formation of highly active, stable, durable, and long-lived biocatalysts-like Fe2O3@BS NPs. 相似文献
97.
目的 为了探究可降解聚乳酸在单分子层次的降解性能及其降解速率,使聚乳酸材料更好地应用于生物医学领域.方法 采用原子力显微镜在纳米层次上分别研究单个聚乳酸链在水以及酸、碱性溶液中的单分子力谱.结果 通过对其单链拉伸结果进行分析,发现单个聚乳酸分子链在纯水中短时间内发生水解断链的概率较小,可以保持其原有的长链和本征弹性,而在酸、碱性环境中则会在短时间内发生酸、碱微环境导致的加速水解行为,从而使长链聚乳酸分子较短时间内水解成为短链聚乳酸分子.通过对宏观颗粒状聚乳酸材料降解质量损失的分析,也说明酸、碱微环境会加速聚乳酸水解过程.结论 从单分子层次上进一步证明了水解过程中发生微环境的改变对聚乳酸降解速度的改变起着重要作用. 相似文献
98.
以聚乙二醇单甲醚(m PEG)为亲水段,聚丙二醇单丁醚(PPG)为疏水段,用酯键(COO)和烷氧基胺(CON)将它们连接在一起制得了两亲性嵌段聚合物PEG-COO-CON-HDI-PPG。采用核磁共振氢谱对产物的结构进行了表征。通过选择性溶剂诱导法制备了嵌段聚合物胶束,研究了聚合物胶束在高强度聚焦超声(HIFU)下的响应行为。结果表明,超声可使烷氧基胺均裂和酯键水解;用该胶束包覆药物,可以实现对药物的超声控制释放。 相似文献
99.
Physicochemical and sensory characteristics of soya protein isolate hydrolysates with added substrate‐like amino acids 下载免费PDF全文
Jianan Zhang Jucai Xu Lei Liu Yang Liu Tiantian Zhao Changping Wu Dongxiao Sun‐Waterhouse Mouming Zhao Guowan Su 《International Journal of Food Science & Technology》2016,51(1):69-77
Soya protein isolate (SPI) with or without added substrate‐like amino acid was subject to enzymatic hydrolysis catalysed by commercial proteases (Alcalase 2.4 L, flavourzyme and pancreatin). Addition of a small amount of amino acids (amino acid: SPI = 1: 2500, mol g?1) during hydrolysis would cause a significantly (P < 0.05) reduced protein recovery, increased degree of hydrolysis, and altered amino acid composition and antioxidant activities of SPI hydrolysates. The SPI hydrolysates prepared with added Asp, Arg or Lys exhibited a higher antioxidant activity than the control. The bitterness of SPI hydrolysates was largely reduced upon addition of Met, Asp or Glu during hydrolysis, whilst the umami taste and mouthfeel‐liking were remarkably increased. Therefore, adding amino acid during hydrolysis is a feasible and beneficial approach to improve both the functional and sensory properties of SPI hydrolysate. 相似文献
100.
High initial viscosity in the high-solids (>15% (w/v)) enzymatic hydrolysis of lignocellulose is problematic especially in stirred tank reactor concepts. One potential way to avoid the high viscosity is the fed-batch feeding of lignocellulosic material to the reactor. In the current study the hydrolysis of filter paper with final concentration of 19.1% (w/w) was evaluated with different fed-batch procedures. Feeding was based on visual observation, stepwise feeding and the power requirement of the stirrer motor. All the fed-batch procedures resulted in similar yields within 30 h (47–49%) which were higher than with the batch process in similar reactor (38%). However, the mixing behavior was superior in the power based feeding as the instantaneous power of the stirrer motor was kept lower (<10 W) than in other fed-batch procedures (>20 W). The power controlled procedure was further evaluated with different enzyme doses, tip speeds and the power levels of substrate feed. Further study showed that the power controlled feeding is applicable also to other hydrolysis and mixing conditions if power levels of substrate feed are set correctly. Higher (15 FPU/g) enzyme dose caused shorter feeding time (3.0 ± 0.5 h) and lower energy consumption during the feeding period (14 ± 3 Wh) compared with lower (5 FPU/g) enzyme dose (7.0 ± 1.3 h and 33 ± 5 Wh, respectively). The tip speed and the power level of substrate feed had fewer effect on these factors. The performance of the hydrolysis process can thus be enhanced by the substrate feed controlled by the power of the stirrer motor. 相似文献