A fast approach to the synthesis of MO/CNT/Fe hybrid nanostructures built on MXene for enhanced Li-ion uptake

We report herein a fast and scalable approach to the synthesis of MO/CNT/Fe (MCI) hybrid nanostructures via microwave irradiation of MXene under ambient condition. The effect of three arcing materials, CNT, graphite (C), and carbon fiber (C_f), on the growth of carbon nanotubes on MXene-derived metal oxides were investigated. The resulted MCI nanostructures were tested as anodes in LIBs, all exhibiting better electrochemical performance than that of pristine Ti₃C₂. Remarkably, MCI-C_f delivered reversible capacities of 430?mA?h?g^?1 and 175?mA?h?g^?1 at 1?A?g^?1 and 10?A?g^?1, respectively, which is much higher than that of commercial graphite at high rates. The findings in this work open new exciting opportunities to developing hybrid electrode materials with high specific capacity for energy conversion and storage.     

Advanced visible-light photocatalytic property of biologically structured carbon/ceria hybrid multilayer membranes prepared by bamboo leaves

Biologically structured carbon/cerium dioxide materials are synthesized by biological templates. The microscopic morphology, structure and the effects of different oxidation temperatures on materials are characterized by scanning electron microscopy (SEM), transmission electron microscopy (TEM), X-ray diffraction (XRD) ultraviolet-visible light spectrum (UV–Vis) and X-ray Photoelectron Spectroscopy (XPS). Moreover, by splitting water under visible light irradiation, the hydrogen production is measured to test the photocatalytic property of these materials. The results show that materials made with bamboo biological templates which are immersed in 0.1 mol L^?1 of cerium nitrate solution, then carbonizated in nitrogen (700 °C) and oxidized in air (500–600 °C), can obtain the biological structure of bamboo leaves. The product is in the composition of hybrid multilayer membrane, which one is carbon membrane form plant cell carbonation and another is ceria membrane by nanoparticle self assembly. The best oxidation temperature is 550 °C and the band gap of carbon/cerium dioxide materials synthesized at this optimum oxidation temperature could be reduced to 2.75 eV. After exposure to visible light for 6 h, the optimal hydrogen production is about 302 μmol g^?1, which is much higher than that of pure CeO₂.     

CMC jackets for metallic pipes – A novel approach to prevent the creep deformation of thermo-mechanically loaded metals

Steel materials suffer extensive creep by the application at temperatures of about 700?°C and pressures about 350?bar in a power plant environment. The presented concept overwraps a steel pipe with a ceramic matrix composite (CMC) jacket in order to support the steel pipe and provide high temperature strength. Finite Element simulations show the influence of the wall thickness of CMC jacket and the coefficient of thermal expansion (CTE) on circumferential stresses within the hybrid metal ceramic pipe. Suitable fiber and matrix materials were studied, composites fabricated and mechanical properties determined. Finally, a prototype was designed in order to confirm the feasibility of the concept. The lifetime of a pure steel pipe was increased by more than four-fold by the additional CMC jacket.     

Hybrid electric power plant sizing strategy based on ab-initio fuel cell design for weight minimization

This work presents a methodology for the design of a hydrogen fuel cell-based hybrid electric power plant for hybrid electric vehicles (HEV), where a battery bank and ultracapacitors are also considered as components of the hybrid power plant. The methodology considers the design features of an electric vehicle and evaluates its energy and power requirements as to fulfil a driving cycle. The work starts by weight minimizing a fuel cell taking into consideration its physical and electrochemical characteristics. Batteries and ultracapacitors are then sized according to their dynamic response features and considering specifications from commercial candidate cells, to propose an electric configuration and specify the baseline for a hybrid power plant. In order to illustrate the methodology, a crossover utility electric vehicle and a WLTC class I drive cycle are used. This work shows that by reducing the power plant size, power and energy requirements can also be minimized and the overall performance can be increased promoting fuel and costs savings. For comparison and to show the impact of weight minimization on the energy on board and cost, this work presents the energy and power required by different power plant configurations. Results showed that including ultracapacitors to the power plant offers more benefits, such as less stress on batteries, at a marginal initial cost compared to a case without ultracapacitors, where batteries should attend transients with a limited capability for energy recovery from regenerative breaking. The methodology is easily implemented and does not large computational resources providing with a power plant baseline for further design stages, such as particular energy management approaches depending on particular priorities for the developer, such as range, productivity and performance, economy and others.     

Experimental investigation of power management and control of a PV/wind/fuel cell/battery hybrid energy system microgrid

This paper presents an experimental study of a standalone hybrid microgrid system. The latter is dedicated to remote area applications. The system is a compound that utilizes renewable sources that are Wind Generator (WG), Solar Array (SA), Fuel Cell (FC) and Energy Storage System (ESS) using a battery. The power electronic converters play a very important role in the system; they optimize the control and energy management techniques of the various sources. For wind and solar subsystem, the speed and Single Input Fuzzy Logic (SIFL) controllers are used respectively to harvest the maximum power point tracking (MPPT). To maintain a balance of energy in the hybrid system, an energy management strategy based on the battery state of charge (SOC) has been developed and implemented experimentally. The AC output voltage regulation was achieved using a Proportional Integral (PI) controller to supply a resistive load with constant amplitude and frequency. According to the obtained performances, it was concluded that the proposed system is very promising for potential applications in hybrid renewable energy management systems.     

Iron(II) Sulfate(VI) from Titania Production as a Raw Material for Preparation of Hydrogen Sulfide Sorbents

A hybrid sorbent material for removal of hydrogen sulfide from air was developed. The material is based on activated carbon and iron compounds obtained from waste iron(II) sulfate(VI) heptahydrate. The iron salt is deposited on the carbonaceous support and subjected to oxidation (Fe²⁺ to Fe³⁺) using atmospheric oxygen under alkaline conditions. An effect of H₂O₂ addition to the process on the composition of the resultant material was also examined. X-ray diffraction (XRD) analyses confirmed easy conversion of waste FeSO₄·7H₂O to iron oxides Fe₃O₄ and FeOOH. The activated carbon supporting iron oxides revealed a higher efficiency in H₂S elimination from air compared to the commercial activated carbon, without any modification.     

Performance analysis of hybrid power configurations: Impact on primary energy intensity,carbon dioxide emissions,and life cycle costs

Utilization of Natural gas and Hydrogen to support current and future building energy needs to offset the total electric demand while improving the grid resiliency and energy efficiency was investigated. Demand side energy management will play an important role in efficiently managing the available energy resources. Performance assessment of different power generation and energy management configurations is presented in this paper. Development of solutions in addressing grid resiliency by providing the ability to design suitable configurations for meeting individual building energy needs is discussed. Primary movers (PM) such as internal combustion engines (ICE) and fuel cells (FC) along with small scale auxiliary renewable energy source such as photovoltaics (PV) were considered. Key attributes of total carbon foot-print, life cycle costs including capital and operational expenditure, electric grid offset or peak shaving capability, thermal energy availability and its further potential to offset total electric demand, and primary energy intensity are analyzed and discussed in detail.     

Biological Water Treatment by a Hybrid Fluidized-Bed Bioreactor: Theoretical Study

A hybrid fluidized-bed bioreactor for water purification was proposed and analyzed. It is a novel type of bioreactor characterized by hitherto unknown stationary and dynamic features. Steady-state characteristics of this hybrid bioreactor with external liquid circulation are presented. A quantitative analysis of steady-state properties of the bioreactor was performed with the aid of an original mathematical model developed for a double-substrate aerobic microbiological process. A steady-state analysis of aerobic processes characterized by different oxygen demand was performed. The effect of essential parameters was evaluated, including carbonaceous substrate concentration in the feed stream to the apparatus, aeration intensity, total residence time of a liquid in the bioreactor, and height of the bed of fine carrier particles.     

Terrific effect of H2 on 3D free convection MHD flow of C2H6O2H2O hybrid base fluid to dissolve Cu nanoparticles in a porous space considering the thermal radiation and nanoparticle shapes effects

In this article, the physical aspects of natural convection magnetohydrodynamic flow of Cu/Ethylene glycol-water nanofluid past a porosity vertical stretching sheet under impact of thermal radiation, shape and slip factor and suction/injection process has been analyzed using Runge- Kutta Fehlberg fifth order (RKF 5) numerical method. The influence of variable, different parameters such as nanoparticles shape factor, named hexahedron and Lamina on temperature and velocity profiles are exemplified quantitatively through graphs. Outputs demonstrate thermal radiation impact causes to produce heat and increase the temperature profile by increasing nanofluid molecules energy. Lamina shape nanoparticle has a greater effect on increasing Nusselt number (Nu) compared to hexahedron.