喷射成形Al-Zn-Mg-Cu-Zr系合金热处理工艺研究

采用硬度、力学性能测试,金相、扫描电镜、透射电镜观察,X射线衍射分析,研究了不同固溶及时效处理条件下喷射成形A l-7.61Zn-3.57Mg-1.79Cu-0.25Zr合金的力学性能和显微组织结构。结果表明,该喷射成形合金经挤压后基体组织细小均匀,固溶温度达490℃时,合金晶粒明显长大,出现过烧现象。合金适宜的固溶时效工艺为:480℃×60 m in+120℃×28 h。在此条件下,合金的抗拉强度σb、屈服强度σ0.2、伸长率δ、布氏硬度分别为674 MPa、601 MPa、10.6%和173 HB。合金的断裂形式为微孔聚集韧性断裂。     

Devitrification behaviour of rapidly solidified Al87Ni7Cu3Nd3 amorphous alloy prepared by melt spinning method

Rapidly solidified Al87Ni7Cu3Nd3 amorphous alloy was prepared by using melt spinning. Its calorimetric behavior was characterized by using differential scanning calorimeter in a continuous or isothermal heating mode. phase transformation was investigated, with a special interest in primary crystallization, by using an in-situ examination of X-ray diffractometry （XRD） and high resolution transmission electron microscopy （HRTEM）. The results show that, the whole devitrification of rapidly solidified Al87NiyCu3Nd3 amorphous alloy involves two main processes of primary crystallization and secondary crystallization that consist mainly of two reactions. For primary crystallization, the apparent activation energies, EIso and EKis and growth activation energies Eg are about 153, 166 and 288 kJ/mol, respectively. The interdiffusion of Al atoms is a rate-controlled step of formation of the a（Al） particles, but slow diffusion of Ni and Nd atoms plays a significant role in retarding growth of the α （Al） particles. For secondary crystallization, EIso, EKis and Eg of the first reaction are about 291,208 and 290 kJ/mol, and those of the second reaction are about 367, 269 and 372 kJ/mol. The two reactions of secondary crystallization are controlled mainly in an interface-controlled three-dimensional mode, depending mainly on slow diffusion of Ni and Nd atoms.     

Devitrification process in rapidly solidified Al-Ni-Cu-Nd metallic glass

In the present study, rapidly solidified ribbons of A187 Ni7 Cu3 Nd3 metallic glass was prepared by using melt spinning. Devitrification process of the totally amorphous ribbons was investigated by high temperature X-ray diffraction analysis, combining with differential scanning calorimetry, under continuous and isothermal heating regime. The X-ray diffraction intensity and full width at the half maximum (FWHM) were analyzed to investigate the increase of crystallized amount and growth of α-Al crystal particles. The results show that under continuous heating regime, the metallic glass devitrifies via two main stages: primary crystallization, resulting in two-phase mixture of α-Al plus residual amorphous phase, and secondary crystallization, corresponding to rapid precipitation of some inter-metallic phases in the form of dispersion or eutectic mixture. Under isothermal heating regime, only Al crystal precipitates from the Al-rich amorphous matrix at low temperature, and when heating at 280 ℃ only Al     

“材料科学基础“课程双语教学的实践与研讨

阐述了开展"材料科学基础"课程双语教学的意义,探讨了制约其双语教学开展的不利现状和实施双语教学的有利奈件,在现有的教学奈件下,引进国外优秀原版教材,进行"材料科学基础"专业课多媒体双语教学实践.结果表明,合理组织教学资源,选用原版教材,发挥多媒体技术的积极作用,有选择地开展"材料科学基础"课程双语教学是可行的,而且可以获得良好的教学效果.     

锻造对喷射沉积耐热铝合金AlFeVSi组织性能的影响

对喷射沉积制坯进行锻造,制备了AlFeVSi合金实验样品,通过TEM、拉伸实验以及金相技术等手段,研究了锻造对该合金组织性能的影响.结果表明:锻造可以明显改善喷射沉积的分层现象,有效地破碎了层与层之间的氧化膜,并加强了粉未颗粒的物理冶金结合,从而提高了合金的力学性能.     

碳含量及复合变质处理对白口铸铁组织和性能的影响

通过在铸造过程中对熔体进行复合变质处理,制备了变质白口铸铁,采用金相分析、碳化物定量分析、硬度测试和冲击韧度测试等研究了碳含量(2.2%~3.2%)及复合变质处理对白口铸铁组织和性能的影响,并研究了碳含量对复合变质效果的影响。结果表明:随着碳含量的增加,白口铸铁的显微组织由珠光体+离异共晶状渗碳体向少量珠光体+大块连续的莱氏体转变;通过复合变质处理可以有效改善碳化物的形态与分布,碳化物变得孤立、分散,部分网状结构消失,但随着碳含量的提高,复合变质效果变差;经过变质处理后,白口铸铁的硬度和冲击韧度都有所提高。     

FeCuNbSiB软磁粉芯制备及磁性能研究

通过气雾化的方法,制备了Fe73.5Cu1Nb3Si13.5B9粉末,并将所得粉末与环氧树脂剂混合,在室温下采用1.6 GPa压力压制成软磁粉芯。应用X衍射(XRD)和振动样品磁强计(VSM)分别测试了不同颗粒尺寸粉末的结构与软磁性能,并利用Rietveld全谱拟合法计算了不同尺寸粉末的非晶含量与晶粒度;采用阻抗分析仪、BH/μ分析仪和直流偏压测试仪研究了粉末尺寸与粘结剂含量对粉芯软磁性能影响,应用扫描电镜研究了粘结剂含量对粉芯截面形貌的影响。结果表明,通过气雾化所制得的Fe73.5Cu1Nb3Si13.5B9粉末具有良好的软磁性能,随着粉末尺寸的减小,非晶含量增加,晶粒度减小;随着粉末尺寸的减小,粉芯的磁导率与损耗降低,矫顽力增大;随着粘结剂含量的增加,粉芯中粉末颗粒包覆得越完全,粉芯磁导率降低,矫顽力增加,直流叠加特性变得更为优良,而当粘结剂含量为2%时,损耗具有最小值。     

溶胶-凝胶法制备Al2O3·ZrO2复合陶瓷涂层研究

用溶胶-凝胶(Sol-gel)法以Al(NO3)3·9H2O,ZrOCl2·8H2O为原料,乙醇为溶剂,在不锈钢表面制备了xAl2O3·yZrO2复合陶瓷涂层.研究了基材氧化预处理、溶液纽成、添加剂等对陶瓷涂层组成、性能的影响.结果表明:基材氧化预处理能大大改善涂层与基材的结合强度:涂有xAl2O3·yZrO2陶瓷涂层的材料具有较不锈钢更优良的抗高温氧化性能.     

ZrO2@Al2O3陶瓷涂层耐蚀性能研究

用溶胶－凝胶（sol-gel)法在不锈钢表面制备xZrO2.yAl2O3陶瓷涂层,用X射线衍射（XRD）和扫描电子显微镜能谱仪分析了涂层组成与结构;用金相显微镜观测了涂层的孔隙率;用浸泡法和高温抗氧化性试验研究了涂层的耐腐蚀性能。结果表明：xZrO2.yAl2O3涂层随二组分含量的趋近,结构从晶态转变成微晶与玻璃态混合组成,直至完全的玻璃化,涂层致密度提高,耐高温和耐腐蚀性能依次增强。     

Al-Fe-V-Si耐热铝合金高温形变及流变应力研究

采用Gleebe-1500热模拟机,对Al-Fe-V-Si合金在温度350～550℃、应变速率10-4～10-2s-1、最大变形程度50%的条件下,进行高温压缩变形实验研究.在分析合金高温变形时的形变激活能和应力指数的基础上,通过非线性回归处理,得出了合金的流变应力方程,在实验范围内拟合精度较高.