激光熔覆Co+Cr3C2复合涂层的组织与性能

在低碳钢表面激光熔覆了钴基合金涂层(Co60)以及添加不同含量Cr3C2(20%,40%,60%,质量分数)的Co Cr3 C2复合涂层,比较研究了几种涂层的组织与性能.结果表明,Co60涂层主要由初生γ-Co枝晶及其间的共晶组织γ Cr23 C6组成;Co Cr3 C2涂层主要由未熔Cr3C2、杆状或块状的富Cr碳化物及其间的细小枝晶组织组成,组成相主要为γ-Co、Cr7 C3,Cr23 C6和未熔Cr3 C2.添加的Cr3 C2改变了涂层的凝固特征,并细化了组织.随着Cr3 C2加入量的提高,未熔Cr3 C2以及凝固过程中形成的富铬碳化物明显增加.三种Co Cr3 C2涂层的硬度、耐磨性、高温抗氧化性与耐蚀性比Co60涂层均有明显的提高.随Cr3 C2加入量的提高,复合涂层的高温抗氧化性与耐蚀性均提高,而Co 40%Cr3 C2涂层的耐磨性最好.     

波形控制逆变CO2焊接电源关键控制信号的获取

通过分析波形控制CO2焊接过程，介绍了焊接电源空载、燃弧、短路等工作状态的判别，电流、电压、du/dt、di/dt等关键信号的获取方法，为研制波形控制CO2逆变焊机奠定了基础。     

原位TiB2颗粒增强铝基复合材料及其力学性能

对原位反应合成TiB2／A356铝基复合材料微观组织和力学拉伸性能进行了研究。结果表明，原位反应生成的颗粒增强相在复合材料基体中分布均匀，基体与颗粒间的界面洁净。复合材料强度随着颗粒含量的增加显著提高，与基体合金相比，TiB2质量分数为8％的TiB2／A356复合材料强度和弹性模量的提高幅度约为28％，TiB2质量分数为16％的TiB2／A356复合材料强度和弹性模量的提高幅度约为35％。复合材料的断裂主要是由于基体与颗粒界面脱粘，在拉伸应力作用下由此萌生微裂纹并扩展，导致界面处的基体撕裂，从而降低复合材料塑性。     

高纯均匀A1-V4中间合金制备工艺研究

利用铝热还原法，通过过量铝粉一步还原工业V2O5得到Al－V50合金。在300kg熔铝用中频感应炉中， 温度1050－1150℃，把Al－V50分批加入Al99．85熔体，机械装置强力搅拌条件下。可以生产出优质高纯且成分均匀的Al－V4中间合金，并用于生产各种大型复杂关键的ZL205A合金铸件。     

Oxidation Mechanism of Ni—20Cr Foils and Its Relation to the Oxide-Scale Microstructure

The oxidation behavior of Ni—20Cr foils of 100- and 200-m thickness wasstudied in air between 500 and 900°C. Simultaneously, the morphology,microstructure, and composition of the oxide layers were determined byscanning and transmission electron microscopies. Depending on thetemperature, the oxide layer differed significantly. The scale formedat all temperatures was complex, with an outer NiO layer having columnargrains, and an inner layer of equiaxedNiCr₂O₄+NiO+Cr₂O₃ grains. At low temperatures (500 and 600°C),the chromium content was insufficient to form a continuousCr₂O₃ layer, while such a continuous layer formed at theinner interface at oxidation temperatures of 700 to 900°C. At 600°C,internal oxidation of chromium occurred in the substrate. The oxidationmechanism is described taking into account these morphologies and theoxidation kinetics. The observation of no significant differences betweenthe oxidation behavior of thin strips and thick materials is related to thelimited exposure times of the study.     

铝合金点焊在线监测数据库的构建

以所开发的铝合金点焊在线监测系统为基础,构建了在线监测数据库.数据库通过与基于LabVIEW开发环境的在线监测系统相连接,实现了焊点质量特征参数及焊点原始特征信息的实时记录与保存.数据库为用户提供了焊点信息及人员信息的多种查询、管理功能,实现了点焊生产的信息化管理,非常适合航空航天产品的生产管理及该厂的实际情况.数据库信息为在线监测系统提供参数优化数据源,通过均值控制图法实现对在线监测系统焊点质量判定临界阈值的优化.结果表明,数据库的参数优化功能使铝合金点焊在线监测系统达到了较高的判定精度,并已在航空航天产品的点焊生产中得到应用.     

铝电解用TiB_2阴极涂层固化、炭化的升温制度

采用DTG ,DDTA等热分析手段 ,研究了高温固化、炭化过程中 ,铝电解用TiB2 阴极涂层糊料的质量和能量的变化速率 ,制定了涂层的变速固化、炭化升温制度 ;在此基础上 ,研究了升温制度对TiB2 阴极涂层性能的影响。结果表明 :变速升温制度优于匀速升温制度 ,采用变速固化、炭化升温制度所制备的涂层形变小、无裂纹 ,其抗拉强度达 3.13MPa,电阻率为 2 3.2 μΩ·m ;而采用升温速度为 10 .3℃ /h的匀速固化、炭化升温制度制备的涂层形变大、裂纹多 ,抗拉强度小 (2 .6 9MPa) ,电阻率大 (2 8.6 μΩ·m)。     

(ZrAl3+ZrB2)/Al复合材料的制备和微观组织结构

采用混合盐反应法,以KBF4和K2ZrF6粉剂为原料在铝熔融体中制备了(ZrAl3 ZrB2)/Al复合材料.借助于X射线衍射仪、电子探针和透射电镜对复合材料的物像和增强相进行了观察,结果表明ZrB2颗粒呈等轴或等轴颗粒状,为六方结构,尺寸大部分小于1μm,ZrAl3相大部分呈长条状,两种增强相整体分布较为均匀,且与Al的界面光滑洁净,没有其它界面生成物.对复合材料的硬度做了测试,原位合成增强相的引入显著提高了复合材料的HRB硬度.     

Nanoscale Studies of the Early Stages of Oxidation of a TiAl-Base Alloy

The strategy to perform nanoscale studies of the initial stages of oxidation of TiAl involved first gaining some information on the electronic structure of pure TiO₂ surfaces and then on TiAl surfaces before and after oxidation both in low- and high-oxygen potentials. Both materials were studied in atomically-cleaned states generated by repeated sputtering and heating. It was found that the oxygen vacancies created additional defect states in the band gap of stoichiometric TiO₂. The results obtained on TiO₂ were used as fingerprints to study the oxide nucleation. The results on the initial stages of oxidation of TiAl confirm the nucleation of Ti₂O₃ islands of nanometer size and monolayer height in a low-oxygen-pressure environment, whilst a TiO₂ layer developed in an atmospheric environment. The ledges on atomically-cleaned surfaces usually acted as nucleation sites.     

Simulation on function mechanism of T1(Al_2CuLi) precipitate in localized corrosion of Al-Cu-Li alloys

1Introduction Al-Li alloys,compared with traditional Al alloys,possess more excellent properties,such as lower density,greater elastic modulus and higher specific strength.In the near future,they would be widely applied in airplane structures.However,they…