Single transition metal atom catalysts on Ti2CN2 for efficient CO2 reduction reaction

Electrochemical CO₂ reduction reaction (CO₂RR) is an efficient way in the utilization of CO₂. In this work, single transition-metal (TM) atom (TM = Sc, Ti, V, Cr, Mn, Fe, Co, Ni, Cu, Zn) anchored on two-dimensional (2D) Ti₂CN₂ are designed for CO₂RR using density-functional-theory (DFT) calculation. We show that Ti₂CN₂ serves as an excellent substrate to support single atom catalysts (SACs), compared to Ti₂CO₂ and Ti₂CF₂. We find that the Sc, Ti and V supported on Ti₂CN₂ show high catalytic activities to produce CO with a low overpotential of 0.37, 0.27, and 0.23 eV, respectively. Differently, the Mn and Fe on Ti₂CN₂ are catalytically active for the production of HCOOH with a low overpotential of 0.32 and 0.43 eV, respectively. We further show that the negatively charged TM-Ti₂CN₂ can capture and activate CO₂ more effectively, and the catalytic activity and selectivity can be significantly tuned by injecting extra electrons.     

A dynamic meta-learning rate-based model for gold market forecasting

In this paper, an improved EMD meta-learning rate-based model for gold price forecasting is proposed. First, we adopt the EMD method to divide the time series data into different subsets. Second, a back-propagation neural network model (BPNN) is used to function as the prediction model in our system. We update the online learning rate of BPNN instantly as well as the weight matrix. Finally, a rating method is used to identify the most suitable BPNN model for further prediction. The experiment results show that our system has a good forecasting performance.     

Evidence for compliance controlled oxygen vacancy and metal filament based resistive switching mechanisms in RRAM

We present electrical evidence on asymmetric metal-insulator-semiconductor (MIS) based test structures in support of the presence of two different independent switching mechanisms in a resistive random access memory (RRAM) device. The valid mechanism for switching depends on the compliance capping (I_gl) for forming/SET transition. Our results convincingly show that low compliance based switching only involves reversible oxygen ion drift to and from oxygen gettering gate electrodes, while high compliance switching involves formation and rupture of conductive metallic nanofilaments, as verified further by our physical analysis investigations. We have observed this unique dual mode switching mechanism only in NiSi-based gate electrodes, which have a moderate oxygen solubility as well as relatively low melting point.     

Carotenoids and Their Geometry Isomers in Selected Tropical Fruits

This study determined the carotenoids content in cherry tomato, pink guava, and red grapefruit pulps and juices. Cherry tomato pulp exhibited the highest β-carotene content whereas pink guava pulp had the highest lycopene content. However, β-carotene and lycopene contents in the studied fruit juices were lower than their pulps in the same sample portion. Interestingly, six to twelve cis-isomers of carotenoids were identified in the fruit pulps and juices studied. A higher number of trace amounts of cis-carotenoids was found in fruit pulps as compared to juices. Therefore, consumption of whole fruit is recommended as the studied fruit juices have lower carotenoids content.     

优化制动转矩分布以提高四轮驱动混合电动车辆的稳定性(二)

四轮驱动混合电动车辆稳定性控制逻辑建议采用后马达能量回收制动和一个电液制动器(EHB)。采用一个通常的算法,求得能量回收制动和EHB转矩之间最佳的转矩分布。根据已知输入的所要求的偏转转矩和道路摩擦系数,用该通常算法计算出最佳能量回收制动转矩和最佳的EHB转矩。基于最佳的制动转矩分布,相应驾驶员转向角和车辆速度,用模糊控制算法,车辆稳定控制逻辑建议形成所要求的偏转转矩,去补偿侧滑角和偏转率的误差。对单车道变更机动性用比较固定能量回收制动和最佳能量回收制动,判断车辆稳定性控制逻辑的性能。由仿真结果可以看到,在满足车辆稳定性的情况下,最佳能量回收制动可以比固定的能量回收制动增大能量回收。     

Production of high-purity medical radio isotope 64Cu with accelerator-based neutrons generated with 9 and 12 MeV deuterons

We conducted a feasibility study for producing a high-purity medical radioisotope ⁶⁴Cu from natural zinc with accelerator-based neutrons. ⁶⁴Cu isotopes were produced via the ⁶⁴Zn(n,p) reaction. The accelerator-based neutrons were generated via the C(d,n) reaction using low-energy deuterons of 9 and 12 MeV on a 1-mm-thick carbon target. First, the production purity was estimated using the evaluated nuclear data library JENDL-4.0 and our previously measured thick target neutron yield. We found that even when natural zinc was used as the starting material, significantly high-purity ⁶⁴Cu could be obtained. Next, irradiation experiments for producing ⁶⁴Cu using natural zinc were conducted at Kyushu University Tandem Laboratory, with the amounts of ⁶⁴Cu isotopes and other gamma-emission nuclides measured by a high-purity germanium detector. As a result, high-purity ⁶⁴Cu isotopes of 1.11(49) × 10⁰ and 3.70 (17) × 10⁰ Bq/g/μC were produced with incident deuteron energies of 9 and 12 MeV, respectively.