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1.
《Ceramics International》2022,48(22):32973-32985
Multilayer structure design is one of the most promising methods for improving the comprehensive performance of AlCrN-based hard coatings applied to cutting tools. In this study, four types of AlCrSiN/AlCrVN/AlCrNbN multilayer coatings, with different modulated thicknesses, were deposited to investigate their microstructure, mechanical, tribological, and oxidizing properties. All multilayer coatings exhibited grain growth along the crystallographic plane of (200) with a NaCl-type face-centered cubic (FCC) structure. The results show that, as the modulation thickness decreases from ~35 nm to ~10 nm, (1) the grain refinement effect is increasingly evident; (2) all multilayer coatings show a hardness of >30 GPa and an elastic modulus of >300 GPa. Both the ability to resist elastic strain to failure and the plastic deformation of multilayer coatings increase. In addition, their resistance to cracking reduces; (3) the wear rates of these multilayer coatings reduce successively from 1.78 × 10?16 m3 N?1 m?1 to 7.7 × 10?17 m3 N?1 m?1. This is attributed to an increase in self-lubricating VOx and a decrease in adhesives from the counterparts; (4) the best high-temperature oxidation resistance was obtained for the multilayer coating with a modulated thickness of ~15 nm. 相似文献
2.
针对颗粒滚动摩擦作用对筒仓中玉米颗粒的力链空间分布进行研究,通过EDEM离散元软件建立筒仓模型与仿真玉米颗粒模型进行卸粮仿真模拟,并与筒仓卸料实验作流态对比,验证模型与仿真结果的准确性。通过对模拟仓进行切片观察和数据处理,对比分析了不同摩擦情况下力链的细观参数随时间演化规律。模拟结果表明:颗粒间摩擦系数越大,卸粮完成的最终时间越长;颗粒间滚动摩擦系数越小,颗粒由整体流转变为管状流的时间越早。对于有漏斗的筒仓来说,减小颗粒间摩擦会改变整体流和管状流之间的极限,从而增加产生管状流的面积。标准滚动摩擦系数下玉米颗粒在卸料过程中会出现起拱-塌陷效应;减小滚动摩擦,玉米颗粒卸料较稳定,未出现起拱的应力突增、以及拱塌陷的应力衰减;增大颗粒间滚动摩擦不但会增加拱效应,且出现成拱高度距离漏斗口更高。 相似文献
3.
Oxide-based near infrared (IR)-shielding coatings consisting of quarter‐wave stacks of oxygen-deficient tantalum oxide (Ta2O5?x) and silicon oxide (SiO2) multilayers and tin-doped indium oxide (In2O3) (ITO) films with the thicknesses of 200–600 nm can block the passage of IR-A (wavelength: 760–1400 nm) and IR-B (wavelength: 1400–3000 nm) radiation, respectively. In this study, the optical properties and microstructure of these oxide-based IR-shielding coatings were investigated. Transmission electron microscopy images indicated that amorphous Ta2O5?x/amorphous SiO2 multilayers were uniform and dense. ITO films were found to be highly crystalline and show carrier concentrations of up to 7.1 × 1020 cm?3, resulting in the strong IR-B optical absorption due to the plasma excitation of the free carriers. Oxide-based IR-shielding coatings with an ITO thickness of 420 nm were found to have near-IR shielding rates of >90% and an average visible light transmittance of >70%. The effects of IR on human keratinocytes were studied to evaluate the IR-induced photoaging in human skin. It was found that the downregulation of cellular proliferation and the enhancement of senescence-associated β-galactosidase activity induced by IR irradiation were significantly inhibited by oxide-based IR-shielding coatings. Thus, this study provides a facile method for the development of coatings for smart windows with high IR-shielding ability and high visible light transmittance. 相似文献
4.
5.
Virginija Sacevičienė Milda Jucienė Vaida Dobilaitė Valentina Krylova Skirma Žalenkienė Nijolė Dukštienė Raimondas Bliūdžius 《应用聚合物科学杂志》2019,136(21):47523
The aim of this work was to investigate the physical and mechanical performance of architectural polyester (PES)–poly(vinyl chloride) (PVC) membranes exposed to different artificial aging conditions. Two commercially available architectural membranes were chosen as research objects. The durability of the PES/PVC fabrics was evaluated by the loss in mechanical performance, scanning electron microscopy, and X-ray diffraction analysis in order to understand the effect of the degradation agents on the surface of the membranes. The mechanical performance of the PES/PVC membranes was unchanged. Scanning electron microscopy images of the tested materials showed initial cracks after aging. The X-ray fluorescence analysis showed that at the time of aging, the amount of Cl and Si decreased slightly, while Ti decreased by half, and Ca by volume increased twice. © 2019 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2019 , 136, 47523. 相似文献
6.
以FeS和CuSn8Ni1粉末为原料,利用机械合金化技术和粉末冶金技术制备了FeS/Cu复合材料,探讨了不同载荷情况下所制备的FeS/Cu复合材料的摩擦学性能及润滑膜与转移膜特征。结果表明:机械合金化提高了FeS与铜合金基体界面结合性能,进而提高了材料减摩耐磨性能;当载荷较小时,摩擦副表面接触不稳定,复合转移膜不连续,摩擦因数波动大;载荷较大时,复合转移膜易破损,材料的减摩耐磨性能变差;当载荷为150 N时,载荷适宜,材料表面软化,复合转移膜更加完整,摩擦因数较小。 相似文献
7.
Because of heat amount is different from peripheral to central of friction welding interface, which is leaded to vary the characterizations along that interface. Current study, respectively, focused on the effect of different friction pressure on micro-structural and mechanical properties of that friction welding joint interface. Presently, these friction pressures are 110, 130, 150 and 170 MPa while kept all other conditions constant. The effects of different friction pressure on welding interface characterization were investigated by EDX, SEM, tensile, compression, impact and hardness tests. The tensile tests carried out on the standardized test piece with diameter 6 mm and 8 mm, thus, compression tests were extracted from the positions of 0°, 45° 90° with test specimen of 4 mm diameter and 6.5 mm length at weld center. Whereas, the impact test pieces were picked up in two positions, the first one is symmetrical, which it obtained to the respect of the rotation axis and the interface, on the other hand, the second one is non-symmetrical with the axis of rotation and symmetrical to the interface, for making the notch head coincide with the center of the welded joint, The obtained results showed that with reducing of friction pressure will present lack of bonding increasing from peripheral toward the welding center, which will responsible on reducing of the mechanical properties such as tensile, compression and impact strength. 相似文献
8.
针对南方客户在使用我司客车一段时间后,车身涂层不同程度出现了起泡的质量问题,进行了现场查看,发现起泡位置在车身左右侧蒙皮,且发生在涂层最底层。初步分析原因是热镀锌板+阴极电泳漆 +原子灰三者之间配套存在问题,通过热镀锌板 +阴极电泳漆 +原子灰三者之间的耐高温 80 ℃配套试验,以及室外曝晒试验,得出镀锌板表面是否钝化、电泳漆膜致密程度和原子灰苯乙烯含量是造成涂层底层起泡的主要原因。为了控制涂层起泡问题,重新修订了我司原子灰、镀锌板、电泳漆的技术标准以及部分工艺文件。 相似文献
9.
《Journal of the European Ceramic Society》2020,40(8):2731-2745
Thermal barrier coatings (TBCs) play a pivotal role in protecting the hot structures of modern turbine engines in aerospace as well as utility applications. To meet the increasing efficiency of gas turbine technology, worldwide research is focused on designing new architecture of TBCs. These TBCs are mainly fabricated by atmospheric plasma spraying (APS) as it is more economical over the electron beam physical vapor deposition (EB-PVD) technology. Notably, bi-layered, multi-layered and functionally graded TBC structures are recognized as favorable designs to obtain adequate coating performance and durability. In this regard, an attempt has been made in this article to highlight the structure, characteristics, limitations and future prospects of bi-layered, multi-layered and functionally graded TBC systems fabricated using plasma spraying and its allied techniques like suspension plasma spray (SPS), solution precursor plasma spray (SPPS) and plasma spray –physical vapor deposition (PS-PVD). 相似文献
10.
《Journal of the European Ceramic Society》2020,40(7):2667-2673
Yb2SiO5 (ytterbium monosilicate) top coatings and Si bond coat layer were deposited by air plasma spray method as a protection layer on SiC substrates for environmental barrier coatings (EBCs) application. The Yb2SiO5-coated specimens were subjected to isothermal heat treatment at 1400 °C on air for 0, 1, 10, and 50 h. The Yb2SiO5 phase of the top coat layer reacted with Si from the bonding layer and O2 from atmosphere formed to the Yb2Si2O7 phase upon heat treatment at 1400 °C. The oxygen penetrated into the cracks to form SiO2 phase of thermally grown oxide (TGO) in the bond coat and the interface of specimens during heat treatment. Horizontal cracks were also observed, due to a mismatch of the coefficient of thermal expansion (CTE) between the top coat and bond coat. The isothermal heat treatment improves the hardness and elastic modulus of Yb2SiO5 coatings; however, these properties in the Si bond coat were a little bit decreased. 相似文献