全文获取类型
收费全文 | 15329篇 |
免费 | 2036篇 |
国内免费 | 938篇 |
专业分类
电工技术 | 247篇 |
综合类 | 1214篇 |
化学工业 | 2507篇 |
金属工艺 | 3232篇 |
机械仪表 | 3189篇 |
建筑科学 | 1130篇 |
矿业工程 | 564篇 |
能源动力 | 245篇 |
轻工业 | 441篇 |
水利工程 | 223篇 |
石油天然气 | 1047篇 |
武器工业 | 180篇 |
无线电 | 492篇 |
一般工业技术 | 2663篇 |
冶金工业 | 560篇 |
原子能技术 | 103篇 |
自动化技术 | 266篇 |
出版年
2024年 | 62篇 |
2023年 | 422篇 |
2022年 | 436篇 |
2021年 | 576篇 |
2020年 | 593篇 |
2019年 | 582篇 |
2018年 | 637篇 |
2017年 | 711篇 |
2016年 | 709篇 |
2015年 | 644篇 |
2014年 | 755篇 |
2013年 | 1049篇 |
2012年 | 992篇 |
2011年 | 965篇 |
2010年 | 705篇 |
2009年 | 826篇 |
2008年 | 651篇 |
2007年 | 984篇 |
2006年 | 952篇 |
2005年 | 775篇 |
2004年 | 767篇 |
2003年 | 561篇 |
2002年 | 425篇 |
2001年 | 436篇 |
2000年 | 389篇 |
1999年 | 294篇 |
1998年 | 246篇 |
1997年 | 207篇 |
1996年 | 193篇 |
1995年 | 177篇 |
1994年 | 108篇 |
1993年 | 94篇 |
1992年 | 95篇 |
1991年 | 56篇 |
1990年 | 56篇 |
1989年 | 40篇 |
1988年 | 46篇 |
1987年 | 17篇 |
1986年 | 7篇 |
1985年 | 14篇 |
1984年 | 14篇 |
1983年 | 6篇 |
1982年 | 10篇 |
1981年 | 1篇 |
1980年 | 7篇 |
1979年 | 2篇 |
1976年 | 1篇 |
1959年 | 3篇 |
1958年 | 1篇 |
1951年 | 4篇 |
排序方式: 共有10000条查询结果,搜索用时 31 毫秒
1.
Pimchaya Luangaramvej Peeranuch Poungsripong Stephan Thierry Dubas 《Polymer International》2022,71(1):139-145
Polyelectrolyte complex (PEC) membranes prepared from poly(styrene sulfonate) (PSS) and poly(diallyldimethylammonium chloride) (PDADMAC) were modified by crossflow polymerization of aniline (ANI). The PEC membranes were used as separators in a two-compartment setup where ANI monomer and ammonium persulfate (APS) oxidant diffused through the membranes to form polyaniline (PANI). APS and ANI having different distributions throughout the membranes, the reaction led to the asymmetric polymerization of PANI on one face of each PEC membrane thus producing Janus membranes. Due to the excess PANI content, the membrane displayed distinct asymmetric electrical conductivities on each face. Interestingly, very different ANI polymerizations were obtained when nonstoichiometric PEC membranes having different molar ratio of cationic and anionic polyelectrolytes (P+:P? represents PDADMAC:PSS) were used and transport of APS was fastest through the 2:1 PEC when compared to the 1:2 PEC. In all experiments, the polymerization was most intense on the ANI side of the membranes. Also, the influence of NaCl both during PEC fabrication and during polymerization was studied and found to have some effect on the solute permeability. Results showed that a higher content of PANI was formed on PEC membranes having excess P+ and with no NaCl added during PEC fabrication. Although X-ray diffraction confirmed the presence of PANI on both sides of each membrane, scanning electron microscopy images demonstrated that both sides of each membrane had different PANI content deposited. Electrical conductivity measurements using a four-point probe setup also showed that the PEC–PANI exhibits asymmetric electrical property on different sides. © 2021 Society of Industrial Chemistry. 相似文献
2.
Cuiping Yu Shuang Sun Sihui Li Huijia Yan Henan Zou 《International Journal of Food Science & Technology》2022,57(2):1173-1185
In this study, the effect of high-intensity ultrasound (HIUS) (200 and 400 W for 0, 5, 10 and 15 min respectively) on conformational changes, physicochemical, rheological and emulsifying properties of scallop (Patinopecten yessoensis) myofibrillar protein (SMP) was investigated. HIUS-treated SMP had lower α-helix content and higher β-sheet content compared with the native SMP. HIUS treatment induced the unfolding of SMP and increased the surface hydrophobicity. The particle size of SMP decreased and the absolute zeta-potential increased after ultrasonication, which in turn increased the solubility of SMP. The conformational changes and the improvement of physicochemical properties of SMP increased the ability for SMP to lower the interfacial tension at the oil–water interface and increased the percentage of adsorbed protein. As a result, the emulsifying properties, rheological properties of SMP and storage stability of emulsions were also improved. In conclusion, HIUS treatment has future potential for improving the emulsifying properties of SMP. 相似文献
3.
4.
5.
Liting Yang Xiao Li Ke Pei Wenbin You Xianhu Liu Hui Xia Yonggang Wang Renchao Che 《Advanced functional materials》2021,31(35):2103971
Large interfacial resistance plays a dominant role in the performance of all-solid-state lithium-ion batteries. However, the mechanism of interfacial resistance has been under debate. Here, the Li+ transport at the interfacial region is investigated to reveal the origin of the high Li+ transfer impedance in a LiCoO2(LCO)/LiPON/Pt all-solid-state battery. Both an unexpected nanocrystalline layer and a structurally disordered transition layer are discovered to be inherent to the LCO/LiPON interface. Under electrochemical conditions, the nanocrystalline layer with insufficient electrochemical stability leads to the introduction of voids during electrochemical cycles, which is the origin of the high Li+ transfer impedance at solid electrolyte-electrode interfaces. In addition, at relatively low temperatures, the oxygen vacancies migration in the transition layer results in the formation of Co3O4 nanocrystalline layer with nanovoids, which contributes to the high Li+ transfer impedance. This work sheds light on the mechanism for the high interfacial resistance and promotes overcoming the interfacial issues in all-solid-state batteries. 相似文献
6.
To gain insight into the ageing behavior of ultrafine grain(UFG)structure,the precipitation phenom-ena and microstructural evolutions of Mg-6Zn-1Y-0.4Ce-0.5 Zr(wt.%)alloy processed by sliding friction treatment(SFT)were systematically studied using hardness texting,transmission electron microscopy(TEM)equipped with high-angle annular dark-field scanning(HADDF-STEM),X-ray diffraction(XRD)and XRD line broadening analysis.The microhardness of the SFT-processed(SFTed)sample initially decreases from 109.6 HV to 104.8 HV at ageing for 8 h,and then increases to the peak-ageing point of 115.4 HV at 16 h.Subsequently,it enters the over-aged period.The un-SFTed sample,as the counterpart,follows a regular ageing behavior that increases from 89.9 HV to 99.6 HV when ageing for 12 h,and then drops.A multi-mechanistic model is established to describe the strengthening due to grain refinement,disloca-tion accumulation,precipitation etc.The analysis reveals that the temperature sensitive UFG structure has an obvious grain coarsening effect,which arouses the soft phenomenon in the early ageing stage.But precipitation hardening provides an excellent hardness enhancement for overcoming the negative influ-ence and helping to reach the peak-aged point.In our microstructural observations,a lot of equilibrium ultrafine MgZn2 precipitates precipitate along dislocations because defects can provide the favorable conditions for the migration and segregation of solute atoms. 相似文献
7.
An integrated model of ultrasonic vibration enhanced friction stir welding (UVeFSW) is developed by integrating the thermal-fluid model with the ultrasonic field model and tool torque model. The tool torque and the heat generation rate at tool/workpiece contact interfaces are coupled with the interfacial temperature, strain rate and ultrasonic energy density. The model is used in quantitatively analysing the effects of ultrasonic vibration on tool torque and thermal processes in friction stir welding (FSW). The results show that ultrasonic vibration reduces the flow stress, which results in a decreasing of tool torque, interfacial heat generation rate and interfacial temperature. The complicated interaction of ultrasonic energy with the thermal processes in FSW leads to a gentle thermal gradient and an enhanced plastic material flow in UVeFSW. The model is validated by a comparison of the calculated thermal cycles and tool torque at various welding parameters with the experimentally measured ones. 相似文献
8.
Youcef Hadji Abdessabour Benamor Nabil Chiker Adel Haddad Nacer Tala-Ighil Jean-Pierre Erauw Vedi Dupont Arnaud Tricoteaux Christelle Nivot Anthony Thuault Mohamed Hadji 《International Journal of Applied Ceramic Technology》2020,17(2):695-706
In this study, wear and friction behavior of two based-composites from the Ti-Si-C system, (40 wt% TiC; 28 wt% Ti5Si3; 17 wt% Ti3SiC2) and (18 wt% TiC; 26 wt% Ti5Si3; 41 wt% Ti3SiC2) reinforced by 15 wt% of large size SiC (100-150 µm) particles were investigated. The four-phase composites exhibited approximatively the same friction coefficient (µ ~ 0.9) under high loads (10 N and 7 N). The composite with high Ti3SiC2 showed higher wear rate values by one order of magnitude. However, under 1 N, the composite with high TiC content showed a higher running-in period and a lower steady state µ value (0.37 after 1000 m sliding distance). Scanning electron microscopy, Energy Dispersive X-Ray and Raman spectroscopy analysis of the worn surfaces of the two composites revealed that oxidation was the dominant wear mechanism. The oxidation process and the removal kinetics of the oxides during sliding controlled the tribological behavior of the composites. The influence of processing variables on microstructures development and wear mechanisms of the composites is discussed. 相似文献
9.
The present study investigates the influence of the magnetic field, thermal radiation, Prandtl number, and leading‐edge accretion/ablation on Blasius and Sakiadis flow. The convective boundary condition is employed to investigate the heat transfer. The nondimensional governing boundary layer equations have been solved by the homotopy analysis method for different values of the pertinent parameters. The effects of these parameters on the dimensionless velocity, temperature, skin friction, and Nusselt number are also investigated for various values of relevant parameters affecting the flow and heat transfer phenomena. The most relevant outcomes of the present study are that enhancement in magnetic field strength undermines the flow velocity establishing thinner velocity boundary layer for both Blasius and Sakiadis flows while an increase in accretion/ablation effect at leading‐edge manifests in a deceleration in velocity for Blasius case and the opposite trend is observed for Sakiadis flow. Another important outcome is that an increase in radiation and accretion/ablation at leading‐edge upsurges the fluid temperature leading to enhancement in the thermal boundary layer. For both Blasius and Sakiadis flow, the skin friction coefficient and the heat transfer rate decline with the enhancement of the leading‐edge accretion parameter. The results are compared with the existing data and are found in good agreement. 相似文献
10.
在天然橡胶(NR)/顺丁橡胶(BR)/丁苯橡胶(SBR)为基体的自润滑喷蜡橡胶材料中加入芥酸酰胺,考察芥酸酰胺作为润滑剂时对NR/BR/SBR自润滑喷蜡橡胶材料的硫化特性、力学性能、门尼黏度、摩擦系数及耐老化性能的影响。结果表明,与未加芥酸酰胺的胶料相比,当芥酸酰胺用量为10份时,胶料转矩减小,焦烧时间和正硫化时间缩短,扯断伸长率从388%增加至523%,拉伸强度降低了21.36%,邵尔A硬度、压缩永久变形分别下降5.56%和8.74%,动、静摩擦系数分别减小23.46%和24.82%,门尼黏度降低20.89%,耐热氧老化性能下降。硫化胶拉伸100%停放5 min后,表面出现明显的白色润滑膜,胶料流动性变好,各组分分散得更均匀,断面更光滑。 相似文献