Measurements and modeling of absorptive partitioning of volatile organic compounds to painted surfaces

Partitioning to surfaces is an important sink for volatile organic compounds (VOCs) indoors, but the mechanisms are not well understood or quantified. Here, a mass spectrometer was coupled to a portable surface reactor and a flow tube to measure partitioning of VOCs into paint films coated onto glass or wallboard, and their subsequent diffusion. A model was developed to extract values of the effective absorbing organic mass concentration of the film, C_w, which is a measure of absorption capacity, and VOC diffusion coefficients, D_f, from VOC time profiles measured during film passivation and depassivation. Values of C_w agreed well with the value estimated from the paint film mass and flow tube air volume, and D_f values (also measured using attenuated total reflectance-Fourier transform infrared spectroscopy) correlated well with VOC vapor saturation concentrations, C*, estimated using a group contribution method. The value of these relationships for estimating key parameters that control VOC partitioning into paint and the fate of VOCs indoors was demonstrated using a house model, which indicated that >50% of VOCs with C* ≤10⁸ μg/m³ (C* of octane, hexanone, and propanol) that contacted a paint film of typical thickness fully permeated the film regardless of emission duration.     

水性锈转化涂料的制备及性能

采用苯丙乳液与改性苯丙乳液共混作为成膜物质,以单宁酸为转锈剂,柠檬酸为配位剂,焦性没食子酸为转锈促进剂,再加入成膜助剂、有机胺类缓蚀剂、渗透剂等,制备了一种可应用于带锈钢材的水性锈转化涂料。通过正交试验和单因素试验确定了涂料的最优配方为:成膜物质65%,转锈剂5%,转锈促进剂2%,缓蚀剂0.6%,渗透剂2%,配位剂0.5%,成膜助剂1.6%,蒸馏水余量。采用塔菲尔极化曲线测量、中性盐雾试验和盐水浸泡试验考察了漆膜的耐蚀性。结果表明,所制水性锈转化涂膜可耐盐雾96 h,耐盐水浸泡168 h,且耐酸性较强,在pH为2的3.5%NaCl溶液中有保护作用。与两款市售涂料相比,该自制水性锈转化涂料具有更好的耐蚀性。     

Fully renewable limonene‐derived polycarbonate as a high‐performance alkyd resin

Limonene‐derived polycarbonate‐based alkyd resins (ARs) have been prepared by copolymerization of limonene dioxide with CO₂, catalysed by a β‐diiminate zinc–bis(trimethylsilyl)amido complex, and subsequent chemical modification with soybean oil fatty acids using triphenylethylphosphonium bromide as the catalyst. This quantitative partial modification was realized via epoxy–carboxylic acid chemistry, affording ARs with higher oil lengths, lower polydispersities and higher glass transition temperatures (T_g) in comparison to a conventional polyester AR based on phthalic acid, multifunctional polyol pentaerythritol and soybean fatty acid. The novel limonene polycarbonate AR and the conventional polyester AR were evaluated as coatings and both the physical drying (without the presence of the oxidative drying accelerator Borchi® Oxy Coat) and chemical curing (with Borchi® Oxy Coat) processes of these coatings were monitored by measuring the König hardness and complex modulus development with time. A better performance was obtained for the alkyd paint containing polycarbonates modified with fatty acids (FA‐PCs), which showed a faster chemical drying, a higher König hardness and a higher T_g in coating evaluation, demonstrating that the fully renewable FA‐PCs are promising resins for alkyd paint applications. © 2019 Society of Chemical Industry     

E?cient Video Cutout by Paint Selection

Video cutout refers to extracting moving objects from videos, which is an important step in many video editing tasks. Recent algorithms have limitations in terms of e?ciency, interaction style, and rob...     

国内功能涂料的研究进展

介绍了国内功能涂料方面的研究进展,包括水性防火阻尼双功能涂料、低发射低反射涂料、电热涂料、长大型隧道用多功能纳米涂料、电磁波屏蔽涂料、智能控温涂料、氧化石墨烯/聚氨酯复合紫外光固化涂料、调湿抗菌涂料、隔热/耐磨透明涂料、太阳热反射涂料、转移涂料、自闭性聚合物水泥防水涂料、低VOC(挥发性有机物)常温固化氟碳涂料、水性硅藻内墙净化功能涂料、多功能净味绿色涂料、带湿带锈涂料、干粉质感涂料、抗碳化涂料、发光涂料、防涂鸦抗粘贴涂料等。     

汽车水性金属闪光底色漆的研制与应用

以水性饱和聚酯树脂为基体树脂,以甲醚化氨基树脂为交联剂,以水性闪光铝银粉为效应颜料,以改性乙烯-醋酸乙烯共聚物蜡乳液为定向排列剂,在基材润湿剂、消泡剂、流平剂、中和剂、增稠剂、助溶剂、去离子水等的配合下制得水性金属闪光底色漆。涂膜于160℃×20 min条件下固化,具有VOC(挥发性有机化合物)含量低、硬度高、抗冲击、附着力强、闪光效果好、防腐性能优异、绿色环保、施工安全方便等优点。     

阴极电泳漆槽液熟化周期研究

针对槽液熟化周期长的电泳漆品种,在进行电泳漆材料性能试验时提前将电泳漆中的乳液进行深度脱溶剂处理,除掉其中大部分的低沸点溶剂,可以有效缩短电泳漆槽液的熟化周期,在短时间内满足电泳漆的相关试验需求。     

轨道车辆上金属漆缺陷处理

对金属漆在轨道车辆上的运用进行了研究,结合金属漆涂装生产过程,介绍了金属漆喷涂的一般方法和常见缺陷,同时分析其产生的原因,并介绍了相应缺陷的修补方法。     

部分地铁车辆车体涂膜修补工作浅析

根据实际情况和具体问题,介绍了杭州部分地铁车辆车体涂膜修补工作。针对现场施工环境、3种色漆品种、局部色漆遮盖力、色差、流挂等问题,逐一给出了相应的解决方案和色漆调制配比,具有一定实用价值。