Fabrication and Characterization of Highly Oriented Composite Nanofibers with Excellent Mechanical Strength and Thermal Stability

Here, highly‐oriented poly(m‐phenylene isophthalamide)/polyacrylonitrile multi‐walled carbon nanotube (PMIA/PAN‐MWCNT) composite nanofiber membranes with excellent mechanical strength and thermal stability are successfully produced using electrospinning. It is demonstrated that the cooperation of multi‐walled carbon nanotubes (MWCNT) and high‐speed rotating collection is beneficial to the acquisition of highly oriented fibers and effectively improves the mechanical strength of the membrane along the orientation direction. Specifically, the tensile stress of poly(m‐phenylene isophthalamide)/polyacrylonitrile (PMIA/PAN) membrane is enhanced significantly from 10.6 to 20.7 MPa, benefiting from the highly oriented alignment of the fibers as well as the reinforcing effect of MWCNTs on the fibers. Furthermore, the stressing process of single fiber and fiber aggregates is carefully simulated, and the influence of MWCNTs on the mechanical properties of PMIA/PAN‐MWCNT membranes is analyzed comprehensively, providing a meaningful auxiliary means for the study of mechanical properties. In addition, the composite nanofiber membrane has the advantages of both PMIA and PAN, possessing high temperature resistance, flame‐retardancy, and chemical stability, for an ideal high‐temperature material. In short, the as‐prepared PMIA/PAN‐MWCNT composite membrane with excellent comprehensive property emerges a promising application in many fields, especially in high‐tech.     

镁合金网格壁板压弯成形数值模拟及实验研究

为探索镁合金整体壁板压弯成形的可行性,以及镁合金壁板压弯成形过程中金属的流动规律,对AZ31镁合金网格壁板压弯成形进行了数值模拟和实验研究。建立了有限元数值模拟的几何模型,采用有限元计算软件对AZ31镁合金网格壁板压弯成形过程进行了数值模拟研究,分析了镁合金网格壁板压弯成形中的温度场、应变场、应力场、破坏系数等的分布规律。确定了合适的AZ31镁合金壁板压弯成形工艺参数,并对镁合金网格壁板压弯成形进行了实验研究,获得了合格的镁合金网格壁板弯曲件,并分析了镁合金网格壁板成形件尺寸精度,模拟结果与实验结果相吻合,最大相对误差为16.7%。     

直流配网型混合动力系统在车客渡船上的应用

针对车客渡船动力负荷切换频繁,传统柴油机推进油耗高、排放和噪声大的问题,提出一种基于变速发电机组和超级电容储能装置的直流配网型混合动力系统。目前系统已成功应用于“江苏路渡3011”轮,实船运行数据显示:该混合动力系统不仅能达到较好的节油效果、降低排放,更在操控性、舒适性上优于传统的柴油机推进模式。     

“电网一张图”时空信息管理系统

文章首先总结了电力企业信息管理系统的现状,提出了多源信息管理系统融合集成的邦联、子集和完全融合3种方式,分析了3种方式的优缺点,以建设企业"互联网搜索"型数字引擎为目标,提出了融合基于本体的图数据库建模,多维关联与路径因果分析,和人机共生互动可视化决策于一体的企业信息管理系统技术发展趋势;在系统分析目前正在快速发展的图数据库技术与传统关系数据库之间的本质区别基础上,总结原创的电力图计算平台技术的特点;在此基础上讨论"电网一张图"在建设能源互联网时空信息管理平台数据关联索引图中的核心作用,提出了支持能源互联网建设的"电网一张图"时空信息管理系统的技术架构与特点,最后总结"电网一张图"时空信息管理系统在提高电网安全运行水平、提升客户服务水平、增强清洁能源消纳水平、改善经营绩效水平、以及为综合能源服务和建设能源生态等提供数据服务方面的广阔应用场景。     

计及时间相关性的微能源网鲁棒规划方法

微能源网以能源的梯级利用为原则,可实现风、光等多种新能源的高比例消纳,满足区域内电、热、冷等多种能源需求。微能源网中存在新能源出力与冷、热、电负荷的多重不确定性。为增强系统规划结果的鲁棒性,常采用不确定集表述新能源出力与多种用能需求的不确定性,实现针对微能源网的鲁棒规划设计,往往使系统规划结果过于保守,降低系统经济性。为克服以上问题,规避实际运行中不可能发生的场景,降低系统规划结果的保守性,文章提出一种考虑时间相关性的微能源网鲁棒规划模型。该模型在计及多重源荷不确定性的基础上,进一步考虑新能源出力与冷、热、电负荷的时间相关性。通过算例对传统不确定集与所提出的改进不确定集进行对比分析,验证了所提模型及方法的优越性和有效性。     

基于大数据挖掘的用电行为分析

得益于智能电网的发展,电力大数据的价值与作用逐渐被挖掘。通过对电力大数据的深入挖掘与研究,可促进电网企业管理水平的进一步提升,为我国智能电网的发展提供助力。而依托于大数据挖掘的用户用电行为分析,可实现当前企业电网调控与需求侧的充分融合,为电力系统的稳定性运行提供保障。基于此,文章针对大数据挖掘的用电行为分析进行深入探析,以期为智能电网发展提供帮助。     

Effect of neodymium substitution on crystalline orientation,microstructure and electric properties of sol-gel derived PZT thin films

Pb(Nd_xZr_0.52Ti_0.48)O₃ (PNZT) (x = 0%, 1%, 2%, 3%, 4%, 5%) thin films were prepared by sol-gel process to investigate the effects of neodymium substitution on crystalline orientation, microstructure and electric properties of lead zirconate titanate (PZT) films. X-ray diffraction (XRD) and scanning electron microscope (SEM) analysis showed that PNZT films with Nd doping concentration below 3% exhibited dense perovskite structure with (100) preferred orientation. The average grain size of PNZT films decreased as the Nd substitution increased. The maximum dielectric constant, remnant polarization and minimum coercive field were obtained in 2% Nd-doped PZT films. Fatigue resistance was also improved significantly with 2% Nd dopant.     

Influence of Different Additives on the Interaction of Quinolone Antibiotic Drug with Surfactant: Conductivity and Cloud Point Measurement Study

Conductometric and cloud point (CP) measurement studies have been performed to investigate the interaction of tetradecyltrimethylammonium bromide (TTAB) and Triton® X-100 (TX-100) with ciprofloxacin hydrochloride (CFH) in different solvents over the temperature range of 295.15–315.15 K. CFH is used for the treatment of various bacterial infections. The observed critical micelle concentration (CMC) values of TTAB were found to be reduced in the presence of electrolytes (Na₂SO₄/Na₃PO₄), and this reduction proceeds with the elevation of salt concentration. The order of the CMC of TTAB follows the trend: > >. The observed CMC values of TTAB were found to increase with increasing temperature and decrease with increasing concentration of CFH in aqueous medium. The values of Gibbs free energy of micellization () for the TTAB/TTAB + CFH mixture were found to be negative, implying spontaneous micellization. The estimated CP of TX-100 decreases with increasing concentration of TX-100 in aqueous medium. The CP values first decrease with increasing concentration of CFH and then increase at higher concentration of CFH almost in all cases investigated. The values of free energy of clouding were found to be positive in all cases studied implying that phase separation of TX-100 was nonspontaneous. The other thermodynamic parameters associated with the micellization of TTAB and the phase separation of TX-100 were estimated and explained.     

电液控制系统关键传感器的故障预警方法研究

为了保证电液控制系统的正常运行,对电液控制系统核心传感器部件的故障预警是关键一环,分析了传感器在电液控制系统的工作原理,得到了传感器在系统中的故障规律,为了对井下的电液控制系统中的核心传感器的故障进行预警和诊断,结合目前比较流行的传感器故障预警方法,以液压支架的压力传感器为例,提出了一个静态分析与动态分析融合的诊断方法,其核心是通过对传感器采集的数据进行分析,能有效预测压力传感器故障,提高电液控制系统的可靠性。     

Small-Molecule Inhibitors of METTL3, the Major Human Epitranscriptomic Writer

The RNA methylase METTL3 catalyzes the transfer of a methyl group from the cofactor S-adenosyl-L-methionine (SAM) to the N⁶ atom of adenine. We have screened a library of 4000 analogues and derivatives of the adenosine moiety of SAM by high-throughput docking into METTL3. Two series of adenine derivatives were identified in silico, and the binding mode of six of the predicted inhibitors was validated by protein crystallography. Two compounds, one for each series, show good ligand efficiency. We propose a route for their further development into potent and selective inhibitors of METTL3.