稳产国Ⅵ柴油并兼产喷气燃料技术方案的工业应用

介绍了浙江石油化工有限公司新建的3 Mt/a柴油加氢精制装置，其配套使用中国石化石油化工科学研究院有限公司开发的催化剂级配技术，并实施了可根据原料供应及市场产品需求情况灵活调整切换的2种生产技术方案。1 a的安稳生产运行结果表明:该装置以直馏柴油为主原料，通过分馏塔的馏分切割及其侧线抽出，实现了稳产国Ⅵ柴油并兼产喷气燃料技术方案的工业化应用；在实施以兼产喷气燃料为主的生产技术方案时，通过调整常一线柴油的掺炼量，不仅可以生产含硫量小于10.0 μg/g的精制柴油产品，同时兼产所得到的喷气燃料产品含硫量小于0.5 μg/g，赛波特颜色号值大于30；在实施主产精制柴油组分方案时，通过掺炼质量分数为20%~40%的催化柴油，并使所提炼得到的精制柴油组分含硫量小于6.0 μg/g的前提下，这些精制柴油组分产品既可直接作为满足国Ⅵ柴油产品出厂待售，也可作为柴油调和组分储存待用于产品的进一步优化。     

紫金山东南矿段成矿期次、阶段浅析

通过对紫金山东南矿段铜钼(金)矿床地质矿化特征分析,指出铜钼矿化带主要赋存于花岗闪长斑岩的内外接触带,处于似斑状花岗闪长斑岩的上部,金矿化带赋存在表生氧化带的英安玢岩、隐爆角砾岩中。经过对矿石的组构特征、矿物生成顺序等特征分析,将矿床的成矿演化过程分为斑岩热液期、高硫化浅成低温热液期、表生氧化期三个主要矿化期次,进一步将斑岩热液期分为黑云母-钾长石化阶段、石英-绢云母化阶段、碳酸盐化阶段三个阶段;高硫化浅成低温热液期分为地开石化阶段、明矾石化阶段、硅化阶段三个阶段。研究结果为进一步研究矿床成因提供了依据。     

配煤掺烧最小煤质偏差模型及煤场存放优化

定义了混煤和锅炉目标煤的煤质偏差,给出以煤质偏差作为目标函数的掺配优化模型,通过调整某个成分的期望误差,可单独调节该成分与目标煤的接近程度;通过对模型约束条件设定,可限制低灰熔点煤的掺配份额,控制炉膛结焦,或提高采购量大的单煤的掺配比例。基于最小煤质偏差模型,针对某670 MW超临界压力直流锅炉进行掺配优化模拟,提出煤场存放的优化概念和方法。结果表明:该模型能够从复杂的单煤煤源中找到最接近目标煤质的掺配方案,优化后入炉煤质稳定,且接近目标煤质。     

利用调度优化模型研究原油调合方案的可行性

针对某沿海炼油企业拟投用原油调合系统以稳定混炼原油的性质,设计方案要求将部分码头罐的操作模式由混储改为单储的情况,采用约束规划与数学规划复合建模,实现了码头至厂区大容积长输线模拟,建立了该企业的原油调度优化模型并研究了设计方案的可行性。针对240h调度周期、10种可加工原油、3艘到港油轮的复杂工况进行了优化计算。结果表明:该设计方案具备可行性,且油轮仍可实现到港即卸油,蒸馏装置混炼油种也可长时间保持稳定;模型的优化计算时间较短(小于15min),且对长输线收付及存油情况模拟准确,复合建模方法满足工业应用要求。     

石墨烯改性涤纶/蓄热调温纤维/长绒棉混纺纱的制备与性能分析

文章采用石墨烯改性涤纶、蓄热调温纤维、长绒棉设计开发了混纺比为50/30/20、30/50/20、20/70/10的3种复合功能纱线,并对纱线的强力、拉伸性能、条干均匀度以及热学性能和抗菌性能进行测试分析。结果表明:蓄热调温纤维的静电现象会影响混纺纱的条干均匀度,并且其含量的增加会使混纺纱线的断裂强力降低;石墨烯改性涤纶所占质量分数的增加会造成混纺纱的韧性下降,同时混纺纱的热学性能和抗菌性能也会受到纤维不同混纺比的影响。     

Synergistic effect for co-coking of sawdust and coal blending based on the chemical structure transformation

Biomass was used as additives in coal blending for making coke in terms of widening the alternative raw materials and reducing CO₂ emissions. To obtain the influences of biomass incorporation on the semicoke formation, the chemical structure transformation as well as the gas evolution during sawdust (SD)/coal blending (BC) co-coking were investigated using in-situ Fourier transform infrared spectroscopy coupled with mass spectrometry (In-situ FTIR-MS). Meanwhile, the role of biomass in the semicoke formation was also characterized by several analytical techniques. The transformation of the five main functional groups between SD and BC exhibited the largest difference, and the synergistic effect based on the chemical structure transformation was also proposed for the SD/BC blends co-coking. The synergistic effect based on the chemical structure transformation was divided into two stages during semicoke formation. One stage occurred at 100–280 °C that was assigned to the physical effect that inhibited the BC decomposition. Another stage happened at 280–500 °C that was mainly attributed to the hydrogen transfer that enhanced the aromatization of semi-coke. In addition, it was also noted that the thermoplastic properties decreased proportionately to the quantity of the SD, and the non-agglomeration between BC and SD was clearly observed by SEM.     

贵州省道真县大塘铝土矿矿石特征

本次对大塘铝土矿研究区进行矿石类型划分,对其矿物、化学成分等进行研究,得出矿石特征及成因。矿石矿物以铝矿物为主,隐晶、豆状、粒屑结构等,块状构造,其主要化学成分为Al2O3、SiO2、Fe2O3、TS、TiO2。铝土矿石赋存层位为大竹园组,属Ⅳ-Ⅴ级品,产于遭受长期风化剥蚀的古陆边缘,为古风化壳沉积型矿床。     

豫西吉家洼金矿床主矿脉找矿前景分析

吉家洼金矿床位于豫西熊耳山上宫金矿集区的西部。通过对矿床地质、主要矿脉地质特征研究,对F1、F2和WF1矿脉进行了矿体趋势预测和找矿前景分析。分析结果表明,WF1矿脉北中部125～119线间、中部123～107线间及南部100～114线间,深部具有较大的找矿潜力;F1、F2矿脉11～8线为找矿有利地段,具有进一步找矿空间。     

Effect of the composition and degree of crosslinking on the properties of poly(l‐lactic acid)/crosslinked polyurethane blends

Poly(l ‐lactic acid)/crosslinked polyurethane (PLLA/CPU) blends which were prepared via reactive blending of PLLA with poly(?‐caprolactone) (PCL), glycerol and 4,4′‐methylenediphenyl diisocyanate showed excellent toughness. The effects of the composition of the mixture and degree of crosslinking of CPU on the toughness of the PLLA/CPU blends (80/20 w/w) were studied in detail. Dynamic mechanical analysis and rheological measurements were used to characterize the structure of the in situ formed CPU in the PLLA matrix. A novel netlike phase structure was observed when the average molecular weight of PCL and degree of crosslinking were 1 kDa and 10%, respectively. The impact strength of the blend was enhanced from 2.2 kJ m^?2 for pure PLLA to 62.4 kJ m^?2; meanwhile, the elongation at break was increased to 489.8%. Therefore, the mechanical properties of PLLA/CPU blends can be easily tailored by tuning the composition of the mixture and the degree of crosslinking of CPU. © 2018 Society of Chemical Industry     

瑞木矿区配矿实践

通过对品位高低不同的矿石按比例进行互相搭配,尽量使之混合均匀调配成满足矿山生产矿石指标要求,降低损失率、提高回收率。