全文获取类型
收费全文 | 4857篇 |
免费 | 616篇 |
国内免费 | 258篇 |
专业分类
电工技术 | 444篇 |
综合类 | 201篇 |
化学工业 | 1099篇 |
金属工艺 | 786篇 |
机械仪表 | 51篇 |
建筑科学 | 65篇 |
矿业工程 | 678篇 |
能源动力 | 438篇 |
轻工业 | 31篇 |
水利工程 | 9篇 |
石油天然气 | 102篇 |
武器工业 | 11篇 |
无线电 | 279篇 |
一般工业技术 | 649篇 |
冶金工业 | 803篇 |
原子能技术 | 40篇 |
自动化技术 | 45篇 |
出版年
2024年 | 7篇 |
2023年 | 69篇 |
2022年 | 154篇 |
2021年 | 197篇 |
2020年 | 251篇 |
2019年 | 166篇 |
2018年 | 148篇 |
2017年 | 175篇 |
2016年 | 189篇 |
2015年 | 181篇 |
2014年 | 283篇 |
2013年 | 265篇 |
2012年 | 415篇 |
2011年 | 417篇 |
2010年 | 271篇 |
2009年 | 253篇 |
2008年 | 234篇 |
2007年 | 361篇 |
2006年 | 304篇 |
2005年 | 251篇 |
2004年 | 225篇 |
2003年 | 182篇 |
2002年 | 147篇 |
2001年 | 126篇 |
2000年 | 122篇 |
1999年 | 88篇 |
1998年 | 47篇 |
1997年 | 47篇 |
1996年 | 40篇 |
1995年 | 32篇 |
1994年 | 26篇 |
1993年 | 12篇 |
1992年 | 12篇 |
1991年 | 7篇 |
1990年 | 10篇 |
1989年 | 3篇 |
1987年 | 2篇 |
1986年 | 3篇 |
1985年 | 1篇 |
1984年 | 2篇 |
1983年 | 1篇 |
1982年 | 1篇 |
1951年 | 4篇 |
排序方式: 共有5731条查询结果,搜索用时 15 毫秒
1.
褐煤作为低级煤资源利用率不高,但褐煤中具有腐植酸成分,将褐煤中提取的腐植酸作为化肥原料,提取后剩余残渣作为碳源,与MnS纳米粒子制备了MnS@C复合材料。采用XRD、拉曼光谱、XPS、N2吸附-脱附、SEM和TEM对样品进行了表征。将该复合材料应用于锂离子电池负极材料,对其电化学性能进行了测试。结果表明,MnS@C复合材料的比表面积和孔容分别为117.19m2/g和0.044mL/g,该电极在0.1 A/g电流密度条件下循环200次后比容量高达830 mA‧h/g,且电极容量保持率为99%左右。在0.2、0.4、0.8、1.0、1.2和1.6 A/g电流密度下比容量分别为644、522、427、399、373和348mAh/g,展现出良好的倍率性能。MnS@C复合材料优异的电化学性能得益于碳基体的存在,不仅可以缓解MnS纳米粒子在嵌锂/脱锂过程中的体积膨胀,而且展示了锂离子电池高性能的巨大潜力,为褐煤的高值化利用作出巨大贡献。 相似文献
2.
《Ceramics International》2022,48(7):9083-9089
Direct-methane solid oxide fuel cells (DMSOFCs) have recently attracted substantial attention due to their simplified system, reduced cost, and the direct availability of methane fuel obtained from natural gas. Among oxygen-ion conductive materials, doped-ceria such as gadolinium-doped ceria (GDC) or samarium-doped ceria can be incorporated into Ni-based anodes to reinforce their coking resistance, enlarge their electrochemical reaction area, and improve the kinetics of the internal reforming/electrochemical oxidation of methane. To reduce the range of operating temperatures of DMSOFCs while maintaining their performance, the thin film deposition technique of magnetron sputtering was adopted in this work. An Ni-GDC thin-film anode and a Pt thin-film cathode were deposited on scandia-stabilized zirconia (ScSZ) electrolyte supports. This fuel cell was tested with directly supplied methane fuel (3% H2O) at 500 °C. The results demonstrated the effects of the GDC volume fraction in the anode—which was controlled by co-sputtering power—on open circuit voltage and electrochemical performance. The co-sputtered Ni-GDC anode was able to survive through 36-h operation, although there was some performance degradation. Field-emission scanning electron microscopy results revealed no formation of filamentous carbon on the Ni catalysts, despite the fact that both X-ray photoelectron spectroscopy and Raman spectroscopy analyses detected carbon coking. The relatively high performance and resistance to carbon coking of co-sputtered thin-film anode were attributed to its intrinsic small grain size. 相似文献
3.
不同给液方式对铜电解过程中有重要的影响,不同的循环方式会影响槽内温度分布、电解液成分及阳极泥沉降等,因此,根据铜电解生产不同情况的需要,分析对比了多种给液方式在贵冶电解车间的应用,总结了这几种给液方式的优缺点和适用条件。 相似文献
4.
5.
Rui-an Huang Yuzhong Guo Zhining Chen Xingshuai Zhang Jianhua Wang Bin Yang 《Ceramics International》2018,44(4):4282-4286
A new three-dimensional (3D) sandwich-like Si/Polyaniline/Graphene nanoarchitecture anode for lithium ion batteries (LIBs) is successfully fabricated through an easy approach. In this nanoarchitecture, the in-situ polymerized electronic conductive polyaniline (PAni) hydrogel, acting as “glue”, agglutinates tightly to both the silicon nanoparticles (SiNPs) and graphene sheets, forming efficient conductive networks with high elastic modulus and high tensile strength. This mechanically robust nanoarchitecture can endure the great volume change of silicon and retain structural stability during Li-ion insertion/extraction. The electrodes consisting of this 3D sandwich-like Si/Polyaniline/Graphene nanoarchitecture reveal excellent electrochemical performance. The progress made in this work provides an easy and scalable route for preparing Si-based anode materials with high performance for advanced LIBs. 相似文献
6.
Gerardo Valadez Huerta Johanan Álvarez Jordán Michael Dragon Keno Leites Stephan Kabelac 《International Journal of Hydrogen Energy》2018,43(34):16684-16693
Solid oxide fuel cell (SOFC) systems with anode off-gas recirculation (AGR) and diesel pre-reforming are advantageous because they can operate with the current fuel infrastructure. In the SchIBZ-project, the prototype of such a SOFC system for maritime applications has already been commissioned. In this first paper, we model the system devices to conduct an exergy analysis of this real SOFC plant and validate them with experimental values from experiments in laboratory scale. The results of our simulation agree well with the experimental values. The calculations with the validated results may be closer to the real thermodynamic behavior of such system components than previous literature. 相似文献
7.
硅负极具有高比容量的显著优势,其理论比容量(4 200 mA∙h/g)达到传统石墨负极的10倍以上,被认为是锂离子电池最有潜力的负极之一。然而,硅负极存在导电性较差、充放电过程中体积膨胀巨大等诸多问题,导致其循环性能较差,限制了大规模实际应用。本文提供了一种高性能硅负极的制备方法及应用,通过将硅负极分散在多级孔碳中,连同黏结剂聚丙烯腈涂覆在集流体上,再对极片进行热处理实现聚丙烯腈碳包覆,有效提高电极的整体导电性并能为巨大的体积变化提供空间,从而提升硅负极的大倍率性能和循环稳定性。 相似文献
8.
Ekaterina Koroleva Ilya Reshetov Ekaterina Babich Sergey Vakhrushev Dmitry Tagantsev Andrey Lipovskii 《Journal of the American Ceramic Society》2022,105(5):3418-3427
Broadband dielectric spectroscopy (BDS) was applied to study polarization phenomena in alkaline silicate glasses, in particular, properties and structure of subsurface (anodic) polarized layers forming in poling with deposited film electrodes of different structures. A model of poled glasses which does not contradict experimental data is proposed. In accordance with the model, a poled glass is presented as two resistor-capacitor circuits in a series connection, one of which is the polarized layer and another is the rest of the sample. It is found that the electric properties of the layers essentially depend on the structure of the anodic electrode used in glass poling. It is also shown that the dielectric response of poled glass samples is mainly determined by the electric properties of the submicron polarized layers and this gives an opportunity to reveal specific properties of the layers rather than ones of the glass sample bulk. Revealed temperature dependence of DC conductivity of the polarized layers obeys Arrhenius's law, and determining activation energy does not depend on the electrode. Finally, it is noted that today above-mentioned information about polarized layers can be obtained only by BDS. 相似文献
9.
10.
硅在自然界中储量丰富,其理论比容量高达4 200 mA∙h/g,已成为高能量密度锂离子电池负极材料的研究热点。但是Si作为负极材料也存在许多不足,最大的问题是电池充放电过程中,硅体积膨胀(高达300%),导致Si基负极材料粉化脱落、电池容量迅速衰减,其循环性能尚难以满足实际需求。通过研究开发硅基负极专用黏结剂材料,可以有效抑制循环过程中硅的体积变化,维持硅负极结构稳定,提升电池循环性能。本文综述了近年来硅基负极黏结剂材料的研究进展,主要从合成高分子聚合物黏结剂、天然高分子聚合物黏结剂、导电高分子聚合物黏结剂三个方面进行详细归纳总结,并介绍了本课题组在硅基负极黏结剂方面的部分研究成果,期望能为将来的硅基负极专用黏结剂的研究和应用提供一些思路。 相似文献