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1.
《International Journal of Hydrogen Energy》2022,47(42):18496-18503
Methanol crossover is one of the main challenges for direct methanol fuel cells (DMFCs). Depositing a metal barrier on Nafion can reduce the crossover but usually faces the metal cracking issues. This study presents a new composite membrane in which an anodic aluminum oxide (AAO) substrate is impregnated with a Nafion solution and then coated with a layer of Au. The AAO/Nafion/Au composite membrane shows an ideal metal crack-free surface. Higher and more stable voltage has been achieved for the cell with the membrane, indicating an effectively suppressed methanol-crossover. Results reveal that there is a tradeoff between suppressing the methanol crossover and increasing the ion transmission. By optimizing the membrane, it can not only suppress the methanol crossover but also enhance the output performance of DMFCs. The current density and power density of the cells can be enhanced by 59% and 52.85%, respectively, compared to the cell with a commercial Nafion 117. Overall, this work provides a new approach to designing crack-free membranes for DMFCs. 相似文献
2.
《International Journal of Hydrogen Energy》2022,47(65):28152-28164
The combustion characteristics of ammonia/methanol mixtures were investigated numerically in this study. Methanol has a dramatic promotive effect on the laminar burning velocity (LBV) of ammonia. Three mechanisms from literature and another four self-developed mechanisms constructed in this study were evaluated using the measured laminar burning velocities of ammonia/methanol mixtures from Wang et al. (Combust.Flame. 2021). Generally, none of the selected mechanisms can precisely predict the measured laminar burning velocities at all conditions. Aiming to develop a simplified and reliable mechanism for ammonia/methanol mixtures, the constructed mechanism utilized NUI Galway mechanism (Combust.Flame. 2016) as methanol sub-mechanism and the Otomo mechanism (Int. J. Hydrogen. Energy. 2018) as ammonia sub-mechanism was optimized and reduced. The reduced mechanism entitled ‘DNO-NH3’, can accurately reproduce the measured laminar burning velocities of ammonia/methanol mixtures under all conditions. A reaction path analysis of the ammonia/methanol mixtures based on the DNO-NH3 mechanism shows that methanol is not directly involved in ammonia oxidation, instead, the produced methyl radicals from methanol oxidization contribute to the dehydrogenation of ammonia. Besides, NOx emission analysis demonstrates that 60% methanol addition results in the highest NOx emissions. The most important reactions dominating the NOx consumption and production are identified in this study. 相似文献
3.
《International Journal of Hydrogen Energy》2022,47(6):4155-4170
This paper presents results from numerical simulations of a non-premixed hydrogen-air rotating detonation combustor with radial injection. The fuel and air mass flow rate are varied in order to hold a unity global equivalence ratio. The calculations show that multiple detonation waves co-exist when the mass flow rate is increased. Conditional statistics of the detonation structure and combustion processes suggest similarities across co-existing waves. Quantification of the injection response to the rotation of a detonation indicates that at higher flow rate the refill time is short enough to allow for a quick and well mixed composition prior to the new front passage. Details of the combustion characteristics are analyzed. The results elucidate the correlation between initial injection conditions and detonation multiplicity on the overall physics within the combustor. 相似文献
4.
《International Journal of Hydrogen Energy》2022,47(18):10409-10419
The utilization of renewable gaseous fuels in the diesel engine has gained significant interest in recent years due to its clean-burning nature and higher availability. In this study, hydrogen-rich reformed biogas was used as a gaseous fuel in a common rail diesel engine with diesel as pilot fuel. The hydrogen-rich reformed gas was synthesized through dry-oxidative reforming. The experimentations were performed in the load range from 6 to 24 N m with two different flow rates of gaseous fuel (0.5 and 1.5 kg/h) at a constant speed of 1800 RPM. The effects on engine performance parameters (brake thermal efficiency, brake specific energy consumption, and brake specific diesel consumption), combustion parameters (rate of pressure rise and maximum heat release rate) and emission parameters (Unburnt hydrocarbons, nitrogen oxides, carbon monoxide, and carbon dioxide) were assessed. The induction of gaseous fuel led to an increase in brake thermal efficiency by 10.5%, reduction in brake specific energy consumption by 13.6%, and a reduction of 26.4% in brake specific diesel consumption with a flow rate of 0.5 kg/h when compared to diesel-only mode at 24 N m load. The HC, NOX and CO2 emissions were reduced by 18.2%, 7.4% and 1.4% with a flow rate of 0.5 kg/h when compared to diesel-only mode at 24 N m load due to lower availability of carbon content in the combustible mixture. The utilization of renewable fuel like hydrogen-rich reformed biogas has great potential for overcoming the issue related to both biogas and hydrogen in diesel engines. Moreover, the higher diesel substitution also demonstrates the potential for cost-saving and fossil fuel conservation. 相似文献
5.
教传艳 《计算机测量与控制》2022,30(2):124-128
针对当前柴油机废气再循环冷却控制系统受到时滞问题影响,导致系统开度走势与设定走势不一致、废气再循环效果差的问题,提出基于自适应LS-SVM的柴油机废气再循环冷却控制系统;以AT89C51单片机40针作为电控单元核心部件,利用位置传感器向系统发送负载信号,利用温度传感器来传输信号并反馈至D/A转换器;在D/A转换器中,反馈信号以串行或并行方式进入寄存器,并在转换后输出电流电压,控制系统阀门在排气再循环时的开启;伺服泵采用冷却系统,为系统提供液压动力源;利用自适应LS-SVM原理计算柴油机废气再循环冷却控制目标边界值,在最小二乘支持向量机基础上,利用求解线性方程组进行优化,消除了控制误差;根据控制差的大小,调整控制系统的输出值;由试验结果可知,该系统开度走势与设定开度走势一致,且与设定开度误差为1开度,说明使用该系统具有良好稳态特性,有效克服了系统中时滞问题,废气再循环效果较好。 相似文献
6.
《International Journal of Hydrogen Energy》2022,47(62):26746-26757
The increased use of fossil fuels in the transportation sector has led to an exponential rise of carbon dioxide in the atmosphere. The carbon dioxide (CO2) is the major cause of global warming resulting in climate change and extreme weather conditions. This study explores the ways of reducing the CO2 emission from the exhaust of a common rail engine. The reduction in CO2 emissions were achieved by a combination of methods. It includes the use of low carbon biofuels (cedarwood oil (CWO), and wintergreen oil (WGO)), induction of zero-carbon, hydrogen in the intake manifold and a zeolite-based after-treatment system. In diesel, CWO and WGO were blended 20% by volume and experiments were conducted at different load conditions. The results shows that 20% blending of winter green oil resulted in maximum CO2 reduction of 20% as compared to diesel. The emission was further reduced with the induction of hydrogen along with the after-treatment system. It is seen that a maximum of 54% reduction in CO2 emission could be achieved with the combination for WGO in comparison to diesel without much affecting the other emissions and performance parameters. 相似文献
7.
《International Journal of Hydrogen Energy》2022,47(32):14674-14686
Reformed exhaust gas recirculation technology has attracted great attention in internal combustion engines. A platform of an exhaust gas-fuel reformer connected with the marine LNG engine was set up for generating on-board hydrogen. Based on the platform, effects of the methane to oxygen ratio (M/O) and reformed exhaust gas ratio (REG) from the reformer and excess air ratio (λ) from the engine on the components, hydrogen yield, thermal efficiency and reforming process of the reformer were experimentally investigated. Results shown that hydrogen-rich gases (reformate) can be generated by reforming the mixture of engine exhaust gas (about 400 °C) and methane supplied via the reformer with Ni/Al2O3 catalyst, and the hydrogen concentration of reformate was between 6.2% and 12.6% by volume. The methane supplied rate and λ affected the components and temperature of the reactant in the reformer, while REG changed the gas hour space velocity during the exhaust gas-fuel reforming processes, resulting in the difference in the components of the reformate and thermal efficiency. At the present experimental condition, the highest H2 concentration reformate was generated under the M/O of 2.0, λ of 1.55 and REG of 6%. 相似文献
8.
《International Journal of Hydrogen Energy》2022,47(63):27199-27222
In this present work, the effect of lanthanum oxides (La2O3) on the thermal cycle behavior of TBC coatings and mechanical properties such as adhesion strength and microhardness of 8% Yttria Stabilized Zirconia (8YSZ) TBCs were investigated. CoNiCrAlY and aluminium alloy (Al–13%Si) were used as bond coat and substrate materials. 8YSZ and different wt % of La2O3 (10, 20, and 30%) top coatings were applied using the atmospheric plasma spray (APS) method. The thermal cycling test for TBC coated samples were conducted at 800 °C in the electric furnace. The XRD pattern shows that the La2O3 doped 8YSZ material transformed to cubic pyrochloric structured La2Zr2O7 during thermal cycling. Further, the Taguchi-based grey relation analysis (GRA) method was applied to optimize the TBC coating parameters to achieve better mechanical properties such as adhesion strength and microhardness. And the optimized La2O3/8YSZ TBC coating was coated on CRDI engine combustion chamber components. The engine was tested with microalgae biodiesel and hydrogen, and the results were promising for the TBC-coated engine. The engine performance increased while using La2O3/8YSZ coated components, and the emissions from engine exhaust gas such as CO, HC, and smoke reduced considerably. It was found that there was no separation crack and spallation of the coating layer in the microstructure. Ultimately, the microstructural analysis of the optimized TBC coated piston sample after 50 h of running in the diesel engine confirmed that the developed coating had a superior thermal insulation effect and longer life. 相似文献
9.
《International Journal of Hydrogen Energy》2022,47(43):18831-18856
This study represents the results of the analysis and optimization of an integrated system for cogenerating electricity and freshwater. This setup consists of a Solid Oxide Fuel cell (SOFC) for producing electricity. Unburned fuel of the SOFC is burned in the afterburner to increase the temperature of the SOFC's outlet gasses and operate a Gas turbine (GT) to produce additional power and operate the air compressor. At the bottom of this cycle, a combined setup of a Multi-Effect Desalination (MED) and Reverse Osmosis (RO) is considered to produce freshwater from the unused heat capacity of the GT's exhaust gasses. Also, a Stirling engine is used in the fuel supply line to increase the fuel's temperature. Using LNG and the Stirling engine will replace the fuel compressor with a pump which increases the system performance and eliminates the need for the expansion valve. To study the system performance a mathematical model is developed in Engineering Equation Solver (EES) program. Then, the system's simulated data from the EES has been sent to MATLAB to promote the best operating condition based on the optimization criteria. An energetic, exergetic, economic, and environmental analysis has been performed and a Non-dominated Sorting Genetic Algorithm (NSGA-II) is used to achieve the goal. The two-objective optimization is performed to maximize the exergetic efficiency of the proposed system while minimizing the system's total cost of production. This cost is a weighted distribution of the Levelized Cost of Electricity (LCOE) and Levelized Cost of freshwater (LCOW). The results showed that the exergetic and energetic efficiencies of the system can reach 73.5% and 69.06% at the optimum point. The total electricity production of the system is 99 MW. The production cost is 11.71 Cents/kWh, of which 1.04 Cents/kWh is emission-related and environmental taxes. The freshwater production rate is 42.44 kg/s which costs 4.38 USD/m3. 相似文献
10.