Effect of phosphogypsum on saline-alkalinity and aggregate stability of bauxite residue

A column experiment was conducted to investigate the effect of phosphogypsum (PG) on the saline- alkalinity, and aggregate stability of bauxite residue. Results showed that: with increasing leaching time, the concentrations of saline-alkali ions decreased while the concentration increased in bauxite residue leachate; compared with CK (control group) treatment, pH, electric conductivity (EC), exchangeable sodium percentage (ESP), sodium absorption ratio (SAR), and exchangeable Na⁺ content of bauxite residue were reduced following PG treatment; average particle sizes in aggregates following CK and PG treatments were determined to be 155 and 193 nm, respectively. SR-μCT test results also confirmed that bauxite residue following PG treatment acquired larger aggregates and larger pore diameter. These results indicate that the PG treatment could significantly modulate the saline-alkalinity, and simultaneously enhance aggregate stability of bauxite residue, which provides a facile approach to reclaim bauxite residue disposal areas.     

聚酯类增塑剂的合成与应用研究进展

综述了国内外聚酯增塑剂的合成及应用的最新研究进展，重点介绍了超支化、生物基、石油基聚酯增塑剂的合成与制备方法以及不同类型聚酯增塑剂在聚氯乙烯(PVC)、淀粉、聚乳酸、聚氨酯弹性体与橡胶制品中的最新应用研究进展；并对聚酯增塑剂未来发展方向做了展望。     

废菌渣活性炭的制备及对废水中硝基苯的吸附

以废菌渣为原料制备活性炭，采用能量-色散光谱（EDS）和傅里叶变换红外光谱仪（FTIR）进行表征，结果表明：活性炭表面具有多种官能团，有利于提高对硝基苯的吸附。并研究了活性炭吸附硝基苯的影响因素（pH、初始浓度、吸附时间、投加量）、吸附等温线及热力学。结果表明：在常温中性pH条件下，初始浓度为50mg/L，活性炭用量为0.15g时硝基苯去除率可达98%，出水水质满足《污水综合排放标准》（GB 8978－1996）中对硝基苯浓度低于2.0mg/L的要求。活性炭对硝基苯的吸附具有较快的吸附速率，即1min接近平衡。该吸附行为是自发放热反应，可以用Freundlich模型很好地拟合。废菌渣活性炭对硝基苯的吸附主要是疏水作用和氧化钼活化共同作用的结果。因此，以农业废弃物-废菌渣制备得到的废菌渣活性炭具有良好的经济实用性，可用于废水处理中，实现以废治废的目的。     

渣油催化临氢热转化钼铁双金属催化剂的研究

Replacement of precious single metal catalysts with cost-effective, highly-dispersed composite catalysts for catalytic hydrothermal conversion of residue holds tremendous promise for the residue upgrading technologies. Organic metals were added to the feed as the oil-soluble precursors, and transformed into the catalytic active phases in this work. Physical properties and structures of the composite catalysts had been investigated by X-ray fluorescence spectroscopy, X-ray photoelectron spectroscopy, X-ray diffraction, scanning electron microscope and transmission electron microscopy. The composite catalysts were found to be highly efficient in the catalytic hydrothermal conversion of both model compound and residue. Increased metal dispersion and synergistic effects of two metals played indispensable roles in such catalytic system. Results showed that under the test conditions in the article, the catalyst had the best catalytic performance when the mass ratio of molybdenum to iron was 1.5.     

净水水处理剂中有害杂质在水中残留物分析与风险评估

与欧盟和美国标准相比,我国硫酸铝和硫酸铵标准缺少对水处理剂中有害杂质镍、锑、硒、银、吡啶、氰化物、六价铬的检测;次氯酸钠缺少对水处理剂中有害杂质汞、铬、镉、铁、镍、锑、硒、银、六价铬的检测。结合某市2019年上半年13个水厂出厂水和原水的检测数据,剔除了5项始终低于检出限的有害杂质指标,以及2项出厂水浓度低于原水浓度的有害杂质指标。建议该市硫酸铝和硫酸铵的检测项目可以在原有国标基础上增加锑、硒;次氯酸钠可以增加汞、锑、硒。     

超临界流体萃取技术生产重交通道路沥青的研究

研究了采用超临界流体萃取技术(SFEF),以减压渣油和催化裂化油浆为原料,制备重交通道路沥青产品的可行性.结果表明:当原料中油浆掺入量为10%～30%时,可以生产出牌号为AH70,AH90,AH110的重交通道路沥青产品.工业试验表明,生产牌号为AH70,AH90的重交通道路沥青,采用此技术方案是可行的.     

Effect of surface waxes on the persistence of chlorpyrifos-methyl in apples, strawberries and grapefruits

The effects of the cuticle and epicuticular waxes of grapefruit, strawberry and apple on the photodegradation and penetration of chlorpyrifos-methyl were studied. Photodegradation experiments were conducted by exposing the insecticide to the light of a xenon lamp in the presence of a film of wax extracted from the fruit surface. The half-life of chlorpyrifos-methyl irradiated in absence of waxes was 9.6 min. The half-lives of pesticide irradiated in the presence of wax extracts of apple, grapefruit and strawberry were 83, 34 and 26 min, respectively. In penetration studies, fruit with and without wax layers were treated with an aqueous suspension of pesticide. The penetration of the pesticide from the cuticle to the pulp was measured after 24 h. Samples without wax contained a higher total amount of insecticide than those with wax. No pesticide was detected in samples of apple and grapefruit pulp. Residues were detected in all fractions of strawberry. The waxes and cuticle appear to have some effect on the photodegradation and penetration of chlorpyrifos-methyl in fruit samples.     

对重油催化裂化反应历程的若干再认识——"新型多区协控重油催化裂化技术MZCC"的提出

基于对重油催化裂化反应历程的若干再认识,以高油剂混合能量短接触时间催化裂化为工艺基础,提出了进料强返混、反应平流推进、产物超快分离及化学汽提的分区协同控制新理念和实现分区协同控制反应的新技术.并且为实现高油剂混合能量短接触时间催化裂化提出了新型反应器结构;同时对汽提段的功能进行了拓展与强化,提出了"化学汽提器"的概念.分区协同控制反应的技术以进一步提高轻质油收率和实现装置长周期运行为目标,有着重要的理论和实际意义.     

Evaluation of Atmospheric and Vacuum Residues Using Molecular Distillation and Optimization

The term atmospheric residue describes the material at the bottom of the atmospheric distillation tower having a lower boiling point limit of about 340°C; the term vacuum residue (heavy petroleum fractions) refers to the bottom of the vacuum distillation, which has an atmospheric equivalent boiling point (AEBP) above 540°C. In this work, the objective is to evaluate the behavior of different kinds of Brazilian atmospheric and vacuum residues using molecular distillation. The Falling Film Molecular Distillator was used. For the results obtained through this process, a significant range of temperature can be explored avoiding the thermal decomposition of the material. So these results are very important to the refinery decisions and improvements. The Experimental Factorial Design results showed that the temperature has more influence on the process than the feed flow rate, when a higher percentage of distillate is required.