碳中和背景下配电网差异化节能降耗潜力评估分

为了提高配电网差异化节能降耗效果，解决现有潜力评估方法存在的应用性能差的问题，提出碳中和背景下配电网差异化节能降耗潜力优化评估方法。根据配电网的空间结构，构建相应的等值电路模型。在该模型下，从设备损耗和运行附加损耗2个方面计算配电网的损耗量。根据损耗量计算结果，确定配电网差异化碳中和节能降耗方式。从静态和动态2个角度设置潜力评估指标，通过指标数据处理、指标权重求解等步骤，得出配电网差异化节能降耗潜力的综合量化评估结果。将设计潜力评估方法应用到配电网的差异化节能降耗改造工作中，能够有效降低配电网的实际线损量、降低区域损耗费用，并具有较高的应用价值。     

电子雷管技术的推广应用助力爆破器材安全管理工作

电子雷管技术提高了爆破器材的本质安全。通过对电子雷管技术发展历程的介绍,对其推广应用的可行性进行了深入分析,论述了电子雷管技术的推广应用对爆破器材安全管理工作的促进作用,并提出了今后推广应用中还需加强的工作。     

Investigation of fabrication of gas diffusion substrate for proton exchange membrane fuel cells

The gas diffusion substrate (GDS) is essential in the proton exchange membrane fuel cells. Its fabrication techniques affect the performance significantly and are worthy of investigation. In this study, a manufacturing process of the GDS is proposed to understand the formation process of GDS and promote its structure and performance more pertinently. Different states during the preparation process, raw carbon paper, pre-curing, curing, carbonation, and graphitization, are characterized and measured. Experimental and numerical methods are employed to determine the relationships between microstructure, transport, and mechanical performance variation with the fabricating processes. The results show that its porosity, average pore size, and effective diffusivity decrease first and increase after curing. These parameters after graphitization are lower than that of the carbon paper (CP). The electrical resistivity increases dramatically while pre-curing and decreases gradually after curing, carbonation, and graphitization, and it is much reduced after graphitization. Moreover, mechanical measurement results show that both the picks of tensile strength and flexural modulus occur after curing. Its tensile strength shows little change after graphitization compared to the initial paper's. In contrast, the flexural modulus is improved significantly.     

Natural hydrogen emanations in Namibia: Field acquisition and vegetation indexes from multispectral satellite image analysis

Natural hydrogen exploration is now active in various places of the world. Onshore, correlation between natural H₂ generation and the presence of iron rich rocks especially from Archean and Neoproterozoic cratons have been observed. Emanations and accumulations of H₂ have already been confirmed in such geological settings in Australia, South Africa and Brazil. The geological similitude and the presence of numerous sub circular depressions that are a good proxy for hydrogen emanations suggest that hydrogen resources may also exist in Namibia. We present here the results of a data acquisition campaign which allowed us to confirm the presence of natural hydrogen in this country in the vicinity of Neoproterozoic Banded Iron Formation. The H₂ content in the soil, as in Brazil, is variable within the depressions in time and space and is particularly time sensitive across the day. Comparison of the H₂ signal versus time within these two regions shows a similar behavior of the soils with an increase of the H₂ flow at the middle of the day. In addition, these new data allow us to better constrain the morphological characteristics of such H₂-emiting depressions. By using satellite images and digital elevation model we propose a new proxy to differentiate potentially H₂-emiting features from other type of depressions such as Salt Pan. The Landsat multispectral images and their processing through NDVI and SAVI indexes, that highlight a ring of healthy vegetation around the sub circular area with scarce vegetation already observed appear able to discriminate between H₂ emitting structures and other soft depressions.     

One-step to prepare high-performance gas diffusion layer (GDL) with three different functional layers for proton exchange membrane fuel cells (PEMFCs)

Gas diffusion layer (GDL) is one of the most important components of fuel cells. In order to improve the fuel cell performance, GDL has developed from single layer to dual layers, and then to multiple layers. However, dual or multi layers in GDL are usually prepared by layer-by-layer methods, which cost too much time, energy, and resources. In this work, we successfully developed a facile one-step method to prepare a GDL with three functional layers by utilizing the different sedimentation rates and filtration rates of short carbon fiber (CF) and carbon nanotube (CNT). The treatment temperature for this GDL is much lower than that of traditional method. The thickness of the GDL can be effectively controlled from as thin as 50 μm to more than 200 μm by simply adjusting the content of CF. The GDL with high flexibility is suitable to develop high performance flexible electronics. The fuel cell with the GDL has the maximum power density 1021 mW cm^?2, which shows 19% improvement comparing to the conventional one. Therefore, this work breaks the traditional concept that GDL for fuel cells only can be prepared by very complex and high-cost procedure.     

Effects of different metal corrosion inhibitors on hydrogen suppression and film formation with Mg–Zn alloy dust in NaCl solutions

To improve the safety of wet dust removal systems for processing magnesium-based alloys, a new method is proposed for preventing hydrogen generation. In this paper, hydrogen generation by Mg–Zn alloy dust was inhibited with six common metal corrosion inhibitors. The results showed that sodium dodecylbenzene sulfonate was the best hydrogen inhibitor, while CeCl₃ enhanced hydrogen precipitation. The film-forming stability of sodium dodecylbenzene sulfonate was tested with different contents, temperatures, Cl^? concentrations and perturbation rates. The results showed that this inhibitor formed stable protective films on the surfaces of Mg–Zn alloy particles, and adsorption followed the Langmuir adsorption model.     

Heterofullerene C48B12-impregnated MOF-5 and IRMOF-10 for hydrogen storage: A combined DFT and GCMC simulations study

The H₂ storage properties of isoreticular metal-organic framework materials (IRMOFs), MOF-5 and IRMOF-10, impregnated with different numbers and types of heterogeneous C₄₈B₁₂ molecules were investigated using density functional theory and grand canonical Monte Carlo (GCMC) calculations. The excess hydrogen adsorption isotherms of IRMOFs at 77 K within 20 bar indicate that suitable number and type of C₄₈B₁₂ molecules play a crucial role in improving the H₂ storage properties of IRMOFs. Among the studied pure and nC₄₈B₁₂ (n = 1, 2, 4, 8) in Ci symmetry impregnating into MOF-5, at 77 K under 6 bar, MOF-5-4C₄₈B₁₂ with a 3.5 wt% and 29.9 g/L hydrogen storage density, and at 77 K under 12 bar, the pure MOF-5 with a 4.9 wt% and 31.0 g/L hydrogen storage density has the best hydrogen storage properties. Whereas, among the studied pure and nC₄₈B₁₂ (n = 1, 2, 4, 8) in S6 symmetry impregnating into IRMOF-10, IRMOF-10-8C₄₈B₁₂ always shows the best hydrogen storage properties among the pure and C₄₈B₁₂-impregnated IRMOF-10 at 77 K within 20 bar. IRMOF-10-8C₄₈B₁₂ has a 6.0 wt% and 34.6 g/L hydrogen storage density at 77 K under 6 bar, and has a 7.1 wt% and 41.4 g/L hydrogen storage density at 77 K under 12 bar. The confinement effect of IRMOFs on C₄₈B₁₂ molecules, and steric hindrance effect of C₄₈B₁₂ molecules on IRMOFs mainly affects the H₂ uptake capacity by comparing the absolute H₂ molecules in individual IRMOFs units, C₄₈B₁₂ molecules, and IRMOFs-nC₄₈B₁₂ compounds. The absolute hydrogen adsorption profiles show that eight C₄₈B₁₂ molecules impregnating into MOF-5 can exert obvious steric effects for H₂ adsorption. The saturated gravimetric and volumetric H₂ densities of IRMOF-10-8C₄₈B₁₂ higher than those of MOF-5-8C₄₈B₁₂ due to with larger free volume.     

Influencer-defaulter mutation-based optimization algorithms for predicting electricity prices

Efficient electricity price forecasting plays a significant role in our society. In this paper, a novel influencer-defaulter mutation (IDM) mutation operator has been proposed. The IDM operator has been combined with six well-known optimization algorithms to create mutated optimization algorithms whose performance has been tested on twenty-four standard benchmark functions. Further, the artificial neural network is integrated with mutated optimization algorithms to solve the electricity price prediction problem. The policymakers can identify appropriate variables based on the predicted prices to help future market planning. The statistical results prove the efficacy of the IDM operator on the recent optimization algorithms.     

A triptycene derived hypercrosslinked polymer for gas capture and separation applications

This work describes facile synthesis of a porous polymeric material ( T-HCP ) using readily available reagents. Specifically, T-HCP is a thermally stable and hypercrosslinked polymer (HCP) that is essentially microporous with a high BET specific surface area (940 m² g^?1). Triptycene based polymers are known to feature internal free volume. Thus, the incorporation of triptycene units and extensive crosslinking by an external cross-linker in T-HCP makes it a promising adsorbent for small gas capture applications. Experimental results show that T-HCP demonstrated good CO₂ capture capacity of 132 mg g^?1 (273 K, 1 bar). Molecular hydrogen storage capacity of T-HCP is estimated to be 17.7 mg g^?1 (77 K, 1 bar). T-HCP revealed high CO₂/N₂ selectivity (up to 63) as well as promising CO₂/CH₄ (up to 9.1) selectivity suggesting its potential applicability for CO₂ separation from flue and natural gases.