汽车涂装废水处理技术的研究进展

汽车涂装中产生大量的工业废水，主要包括脱脂废水、磷化废水、电泳废水和喷漆废水等,其典型污染物为重金属离子、表面活性剂、油漆颗粒、磷酸盐等，是一类复杂及难处理的高浓度工业废水。依据废水中所含污染物的不同，对涂装各工序废水进行分质预处理可有效地去除磷酸盐、重金属离子、悬浮固体、油类物质等污染物，有利于减轻后续生物或高级处理单元的负荷，提高整个处理系统的效率。本文综述近年来汽车涂装废水处理方面的研究成果或实践，旨在总结预处理工艺及主体处理工艺的优点及存在的不足，希望为汽车涂装废水处理达标排放及循环回用提供一些借鉴。     

A novel technique for direct reuse of wastewater in combining scouring and bleaching of cotton fabric

Abstract

Wastewater generated from the conventional pretreatment process is having potential to reuse several times for pretreatment of subsequent batches without harming the fabric quality. As the major portion of water is used in textile pretreatment processes, in the present work a novel method was studied for direct reuse of wastewater in combining scouring and bleaching process. The wastewater generated by the conventional pretreatment was reused with and without mixing with freshwater. Simple technique like filtration with nylon mesh was also studied for its effects on efficiency of pretreatment. The pretreated fabrics were characterized using advanced techniques and further evaluated towards efficiency of scouring and bleaching. In order to evaluate the effect of novel pretreatment process involving reuse of wastewater on dyeability, the pretreated fabrics (using both conventional and novel methods) were further studied for dyeability using reactive dyes. The resulting wastewaters were characterized before reuse in novel method. The pretreated fabrics showed insignificant variations in strength and pretreatment efficiency. The dyeability of both fabrics towards reactive dyes was comparable. The volume of effluent generated was greatly reduced in novel method which showed a great promise to save 33% of water in pretreatment process of cotton fabric.     

海藻化工以氢氧化钙作为钙化剂的新型钙化工艺研究

研究了海藻化工中以氢氧化钙作为钙化剂的新型钙化工艺,使用氢氧化钙+氯化钙作为褐藻酸钠的钙化剂替代传统的单一氯化钙。确定的双钙钙化工艺条件：每升褐藻酸钠胶液（褐藻酸钠质量浓度为2.5 g/L）,添加氯化钙溶液29.0 mL（质量分数为5%）,添加氢氧化钙溶液13.75 mL（质量分数为5%）,复合钙化剂中氯化钙与氢氧化钙物质的量比为1.19∶1。与传统工艺相比,新型钙化工艺褐藻酸钠的产率未有明显变化,得到的褐藻酸钠粘度稍有降低,粘度由275.1 mPa·s降低至241.3 mPa·s;氯化钙使用量降低40%以上,总钙添加量减少19%。双钙钙化工艺实现了对钙化废水的再利用,废水中钙质量浓度经处理由483 mg/L降到20 mg/L左右,电导率由6.84 mS/cm降至4.28 mS/cm;经脱钙处理的钙化废水回用后对产品褐藻酸钠的产率和粘度没有显著影响。新工艺操作简单,不仅有效减少了钙化废水中离子的引入,同时可以实现低成本地脱钙,脱钙后的废水可以作为冲稀水回收利用,减少了水资源的消耗,为海藻化工行业的减排提供了一条新的工艺途径。     

铅锌多金属矿分段浓缩选别技术的研究与应用

通过多碎细磨、原矿分级溢流优先浓缩脱水,进行了高浓度选铅银、选锌,锌尾矿再浓缩脱水选硫、选锰,同时匹配合理的选矿药剂,原矿浓缩水回用于磨矿分级和选铅,锌尾浓缩水回用于选锌,尾矿浓缩水回用于选硫、选锰,剩余各种废水经适度处理回用于选铅和磨矿分级等,使一段磨矿细度-74μm从70%提高到80%,铅、锌、硫入选初始浓度分别提高到50%、40%、50%,选矿废水全部分质回用。铅锌硫银回收率分别提高了1.5、2.83、13.57、1.01个百分点,硫精矿主品位从38.9%提高到46.5%,设备减少40%、能耗降低25%,节约了选矿药剂消耗和废水处理费用,实现了铅锌多金属矿产资源的高效回收和节能环保。     

基于卷积神经网络的构件分类策略的研究

为了提高软件复用过程中构件检索的效率，分析了软件构件分类技术的优缺点以及构件特征，从构件刻面信息的角度，采用卷积神经网络技术，提出一种基于卷积神经网络的构件分类策略；利用卷积神经网络对构件刻面特征进行提取，减少人为因素，提高刻面信息提取精确性，并训练出基于卷积神经网络的构件分类模型，通过具体的实验，来论证该模型的准确性，以达到提高构件检索效率的目的。     

Technological and sensorial properties of liquid nitrogen ice cream enriched with protein from brewing waste (trub)

Debittered trub (brewing waste) is an important source of protein source (70.26%). Trub and whey protein were used for 5% protein enrichment of ice cream frozen by liquid nitrogen. Three formulations were elaborated: ice cream standard (ICS), ice cream with whey protein (ICW) and ice cream with trub (ICT). Chemical composition, rheological properties, texture, overrun, melting rate, scanning electron microscopy and a sensorial test were performed. Results showed that ICT presented a higher viscosity, obtained on the upward curve up to 6.76 Pa s⁻¹, consistency index (22.96 (Pa s⁻¹)ⁿ), hysteresis area (140.40 mPa s⁻¹) and hardness (31113.33 g) but a lower melting rate (0.38 g min⁻¹), overrun (13.92%) and sensorial acceptability than the other formulations. The addition of trub debittered for protein enrichment improved ice cream properties and demonstrated that it could be used as a food ingredient.     

基于径流污染控制目标为目的的分流制初期雨水调蓄池容积确定

鉴于初期雨水污染为地表水体的主要污染源之一,以儒乐湖初期雨水调蓄池容积确定为例,采用调蓄池工程措施进行截流,以V类水体标准为径流污染控制目标,在《室外排水设计规范》中控制径流污染的分流制初期雨水调蓄池计算公式的基础上,应用模型法模拟得出控制目标下的初期雨水径流累积深度及调蓄池容积。结果表明,截留径流累积深度为7mm,初期雨水调蓄池容积分别为9 250、5 850m^3时,研究区域内能够满足在管网重现期下排水水质达到V类水体标准。研究成果可为初期雨水截流工程实施提供建议及参考。     

玉米深加工生产废水深度处理工程实例

以某玉米深加工公司生产废水的深度处理工程为例,对现有污水处理工艺进行了改造设计,将生物曝气滤池+臭氧消毒+转盘滤布滤池+超滤工艺作为深度处理工艺串联在原有污水处理站,介绍了该深度处理工艺特点、设计参数、处理效果及运行成本。经过深度处理,出水水质由原《污水综合排放标准》二级标准提高到《生活杂用水水质标准》,新增水处理费用仅为0.128元/m3,清水回收率可达97%。     

硫铁矿制酸净化工序废酸回用的探讨

为了考察硫铁矿制酸净化工序产生的废稀酸回用于湿法磷酸萃取系统的可行性问题．将经简单沉淀和经深度处理的废稀酸分剐回用于制取磷酸。结果表明,未经深度处理的废稀酸直接回用将导致磷酸产品中砷及重金属元素铅、镉的浓度明显升高,分别升高34．13、0．22、0．50倍;废稀酸经化学沉淀法深度处理后．砷及重金属元素达到GB8978--1996《污水综合排放标准》中相关指标的要求,将其回用后所得的磷酸产品中砷及重金属元素浓度不会升高。选择合适的工艺将净化工序产生的废稀酸处理达标后再回用于湿法磷酸生产系统,能够同时取得良好的经济效益和环保效益。