Description of the thermodynamic properties and fluid-phase behavior of aqueous solutions of linear,branched, and cyclic amines

The SAFT-γ Mie group-contribution equation of state is used to represent the fluid-phase behavior of aqueous solutions of a variety of linear, branched, and cyclic amines. New group interactions are developed in order to model the mixtures of interest, including the like and unlike interactions between alkyl primary, secondary, and tertiary amine groups (NH₂, NH, N), cyclic secondary and tertiary amine groups (cNH, cN), and cyclic methine-amine groups (cCHNH, cCHN) with water (H₂O). The group-interaction parameters are estimated from appropriate experimental thermodynamic data for pure amines and selected mixtures. By taking advantage of the group-contribution nature of the method, one can describe the fluid-phase behavior of mixtures of molecules comprising those groups over broad ranges of temperature, pressure, and composition. A number of aqueous solutions of amines are studied including linear, branched aliphatic, and cyclic amines. Liquid–liquid equilibria (LLE) bounded by lower critical solution temperatures (LCSTs) have been reported experimentally and are reproduced here with the SAFT-γ Mie approach. The main feature of the approach is the ability not only to represent accurately the experimental data employed in the parameter estimation, but also to predict the vapor–liquid, liquid–liquid, and vapor–liquid–liquid equilibria, and LCSTs with the same set of parameters. Pure compound and binary phase diagrams of diverse types of amines and their aqueous solutions are assessed in order to demonstrate the main features of the thermodynamic and fluid-phase behavior.     

Research on phase shift characteristics of electromagnetic wave in plasma

The phase shift characteristics reflect the state change of electromagnetic wave in plasma sheath and can be used to reveal deeply the action mechanism between electromagnetic wave and plasma sheath. In this paper, the phase shift characteristics of electromagnetic wave propagation in plasma were investigated. Firstly, the impact factors of phase shift including electron density,collision frequency and incident frequency were discussed. Then, the plasma with different electron density distribution profiles were employed to investigate the influence on the phase shift characteristics. In a real case, the plasma sheath around the hypersonic vehicle will affect and even break down the communication. Based on the hypersonic vehicle model, we studied the electromagnetic wave phase shift under different flight altitude, speed, and attack angle. The results indicate that the phase shift is inversely proportional to the flight altitude and positively proportional to the flight speed and attack angle. Our work provides a theoretical guidance for the further research of phase shift characteristics and parameters inversion in plasma.     

Exploring the influences of the counterpart materials on friction and wear behaviors of atmospheric plasma-sprayed YSZ coating

Sliding wear behaviors of atmospheric plasma-sprayed Yttria Stabilized Zirconia (YSZ) coating mated with four metallic or ceramic counterparts (Si₃N₄, Al₂O₃, GCr15 and ZrO₂) were investigated. It has been found that YSZ coatings in contact with Si₃N₄ and GCr15 show better tribological performances than the other cases, which is due to the formation of the tribolayer mainly consisting of Si₃N₄ and Fe₂O₃ respectively on the worn surfaces. In the case of YSZ coating-Al₂O₃ and YSZ coating-ZrO₂ tribopairs, the wear debris are more irregular and larger in size, resulting in severe abrasive wear and brittle fracture of debris particles. In particular, the specific wear rate of YSZ coating sliding against GCr15 is negative due to the significant material transfer of the tribo-oxide layer, while that of YSZ coating sliding against ZrO₂ is the highest. Amorphization of the wear particles appears in the four cases due to the repeated mechanical action. It has been demonstrated that the wear of YSZ coating deteriorates with the increased flash temperature between the contact surfaces during rubbing process.     

产教融合背景下高职特色专业群“平台+模块”课程体系建设研究

In view of the problems in the construction of characteristic professional groups in higher vocational colleges, the professional group of "intelligent manufacturing" is taken as the research object, and the "platform + module" suitable for the development of the industry will be constructed according to the content of the vocational ability planning courses of the post group. The curriculum system establishes the framework of professional groups, and explores and forms a strategic study to optimize and integrate professional group resources.     

Systematic convergence of nonlinear stochastic estimators on the Special Orthogonal Group SO(3)

This paper introduces two novel nonlinear stochastic attitude estimators developed on the Special Orthogonal Group with the tracking error of the normalized Euclidean distance meeting predefined transient and steady‐state characteristics. The tracking error is confined to initially start within a predetermined large set such that the transient performance is guaranteed to obey dynamically reducing boundaries and decrease smoothly and asymptotically to the origin in probability from almost any initial condition. The proposed estimators produce accurate attitude estimates with remarkable convergence properties using measurements obtained from low‐cost inertial measurement units. The estimators proposed in continuous form are complemented by their discrete versions for the implementation purposes. The simulation results illustrate the effectiveness and robustness of the proposed estimators against uncertain measurements and large initialization error, whether in continuous or discrete form.     

Analyzing dissipation effects on the non-classicality witnessing by a qubit via the entangled state representation

ABSTRACT

In this paper, we study detection of the state non-classicality for a quantum harmonic oscillator by a qubit in the presence of dissipation effects. We show that dissipation can enhance the effectiveness of the method in case of using the corrected form of the related nonclassicality witness. Such an improvement is attributed to the fact that dissipation leads to probing a surface, instead of a curve, of the complex plane for non-classicality condition on normally-ordered characteristic function.     

基于气动性能与刚度特性的风力机翼型优化设计

结合翼型泛函集成理论与叶片截面刚度矩阵数学计算模型,提出了风力机中等厚度翼型气动性能与结构刚度特性的一体化设计方法,实现了翼型气动性能与叶片截面刚度特性的同时提高。对考虑叶片截面铺层参数变化设计的WQ-B300翼型与DU97-W-300翼型进行了气动性能与结构刚度特性对比分析,结果表明:相比于DU97-W-300翼型,WQ-B300翼型的气动性能与叶片截面刚度性能均有显著提高,其挥舞刚度和摆振刚度分别提高了6.2%和8.4%,验证了该设计方法的可行性,给风力机中等厚度及大厚度翼型设计提供了一种思路。     

双光束激光焊匙孔动态特征分析

文中研究了高功率单光束激光焊与双光束激光焊过程中匙孔动态特征的差别. 结果表明，单光束激光焊及双光束激光焊接过程中匙孔均处于从产生到湮灭的剧烈波动的过程，不同于单光束激光焊匙孔的形成、长大、维持、缩小、湮灭过程，双光束激光焊的匙孔还存在分离长大及合并缩小的过程；在相同的焊接参数及焊缝具有相同熔深的条件下，双光束激光焊匙孔的波动频率约为单光束激光焊的2/3，单光束激光焊匙孔的开口面积均值约为双光束激光焊匙孔开口面积的1/2，开口面积的波动变异系数约为单光束激光的2倍，即双光束激光焊过程中匙孔较单光束激光焊的具有较高稳定性.     

The thermodynamic characteristics of a Stirling/pulse tube hybrid cryocooler

A Stirling/pulse tube hybrid cryocooler (SPC), comprised of a Stirling cryocooler as the first stage and a pulse tube cryocooler as the second stage, features the ability of shifting cooling capacity between stages by adjusting the movement of the displacer in the first stage. Such an ability allows an SPC to accommodate itself to time-varying heat loads at different temperatures, which makes it a competitive candidate in space applications. However, due to the gas coupling, there exists a significant mutual effect between stages which endows an SPC with special thermodynamic characteristics and has a significant effect on the SPC’s capability of shifting cooling capacity between stages. With the phasor analysis and the thermodynamic analysis, this paper establishes an idealized model of an SPC. The model is then used to study the effect of the second stage on the first stage and reveal the condition that an SPC is able to shift cooling capacity between stages. Also, the model is compared with a Sage numerical model and the two models are consistent on the overall trend. Though it is unable to reflect reality precisely, the idealized model can interpret the mechanism and highlight some of the essential nature of an SPC, which will eventually benefit the appropriate design of an SPC.