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排序方式: 共有1243条查询结果,搜索用时 31 毫秒
1.
《Intermetallics》2015
Fine-grained fully-lamellar (FL) microstructure is desired for TiAl components to serve as compressor/turbine blades and turbocharger turbine wheels. This study deals with the process and phase transformation to produce FL microstructure for Mo stabilized beta-gamma TiAl alloys without single α-phase field. Unlike the α + γ two-phased TiAl or beta-gamma TiAl with single α-phase field, the wrought multi-phase TiAl–4/6Nb–2Mo–B/Y alloys exhibit special annealing process to obtain FL microstructure. Short-term annealing at temperatures slightly above β-transus is recommended to produce the desired FL microstructure. The related mechanism is to guarantee the sufficient diffusion homogenization of β stabilizers during single β-phase annealing, and further avoid α decomposition by α → γ + β when cooling through α + β + γ phase field. The colony boundary β phase contributes to fine-grained nearly FL microstructure, by retarding the coarsening of the α phase grains. 相似文献
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H. L. Du S. R. Rose Z. D. Xiang P. K. Datta X. Y. Li 《Materialwissenschaft und Werkstofftechnik》2003,34(4):421-426
The oxidation/sulphidation behaviour of a Ti‐46.7Al‐1.9W‐0.5Si alloy with a TiAl3 diffusion coating was studied in an environment of H2/H2S/H2O at 850oC. The kinetic results demonstrate that the TiAl3 coating significantly increased the high temperature corrosion resistance of Ti‐46.7Al‐1.9W‐0.5Si. The SEM, EDX, XRD and TEM analysis reveals that the formation of an Al2O3 scale on the surface of the TiAl3‐coated sample was responsible for the enhancement of the corroison resistance. The Ti‐46.7Al‐1.9W‐0.5Si alloy was also modified by Nb ion implantation. The Nb ion implanted and as received sampels were subjected to cyclic oxidation in an open air at 800oC. The Nb ion implantation not only increased the oxidation resistance but also substantially improved the adhesion of scale to the substrate. 相似文献
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In the oxidation of TiAl alloys, the role of scale-growth stresses formed during oxidation has, thus far, been unknown. In the present paper the oxide-growth stresses were investigated by the deflection-test method in monofacial oxidation (DTMO) accompanied by acoustic-emission measurements. On unmodified surfaces the growth stresses are compressive and reach levels of around –100 MPa. At the same time, significant acoustic emission occurs indicating that even under isothermal conditions, stresses are relieved by a scale-cracking mechanism. For oxide scales on TiAl surfaces, which had been ion implanted with chlorine before oxidation, a very thin protective alumina layer is formed which, however, develops growth stresses in the range of several GPa, accompanied by intensive acoustic emission. In all stress–time curves, a dynamic situation is observed. This consists of phases of stress relief by scale microcracking and phases of stresses increase due to crack healing and further oxide growth. As a result, the level of stress as a function of oxidation time, is characterized by an oscillating course. 相似文献
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TiAl+Sb合金的热稳定性的研究 总被引:1,自引:0,他引:1
研究了退火处理对Ti-34wt.%Al-0.5wt.%Sb合金的室温抗弯性能,显微组织,相组成和断口形貌的影响。发现,低于1000℃退火处理,TiAl+Sb合金的显微组织没有变化,其力学性能仍然保持较高的值。此合金成分适应高温使用条件。 相似文献
8.
研究了在700℃盐和水蒸气协同作用下TiAlNb合金的腐蚀行为以及溅射涂层对TiAlNb合金的防护作用。结果表明,在盐和水蒸气协同作用下,溅射TiAlCrAg涂层对TiAlNb合金具有一定的保护作用。盐和水蒸气协同作用加速了合金以及涂层的腐蚀。挥发性气体氯化物对α2相的循环作用是TiALNb合金腐蚀的主要原因。涂层中较少的α2相以及Laves相中较高的Cr含量是腐蚀有所减缓的主要原因。 相似文献
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运用XD工艺制备了颗粒增强TiAl基复合材料。增强颗粒均匀分布于TiAl基体中并细化TiAl合金。通过在TiB_2/TiAl、TiC/TiAl复合材料中加入适量的Si,颗粒增强TiAl基复合材料的室温延性得到了改善。 相似文献
10.
Dong-Bok Lee 《Metals and Materials International》2005,11(4):313-317
An alloy of 51.23Ti−48.73Al−0.4Fe (at.%) was oxidized at 800, 900 and 1000°C in air to determine the effect of Fe on oxidation.
The scales formed consisted of an outer TiO2 layer, an intermediate Al2O3 layer, and an inner mixed (TiO2 Al2O3) layer, typical of conventional TiAl alloys. A small amount of dissolved Fe ions was weakly segregated in the outer TiO2 layer and also in the inner (TiO2−Al2O3) mixed layer. Ti2AIN and TiN were detected in the scale in some instances. A thin, oxygen-affected Ti3Al sublayer formed at the oxide-substrate interface. The overall oxidation kinetics and the scale morphology were not affected
by Fe-addition. 相似文献