Study of Pb-based and Pb-free perovskite solar cells using Cu-doped Ni1-xO thin films as hole transport material

SCAPS solar cell simulation program was applied to model an inverted structure of perovskite solar cells using Cu-doped Ni_1-xO thin films as hole transport layer. The Cu-doped Ni_1-xO film were made by co-sputtering deposition under different deposition conditions. By increasing the amount of the Cu-dopant, the film crystallinity enhanced whereas the bandgap energy decreased. The transmittance of the thin films decreased significantly by increasing the sputtering power of copper. High quality, uniform, compact, and pin-hole free films with low surface roughness were achieved. The structural, chemical, surface morphology, optical, electrical, and electronic properties of the Cu doped Ni_1-xO films were used as input parameters in the simulation of Pb-based (MAPbI_3-xCl_x) and Pb-free (MAGeI₃) perovskite solar cells. Simulation results showed that the performance of both Pb-based and Pb-free perovskite solar cell devices significantly enhanced with Cu-doped Ni_1-xO film. The highest power conversion efficiency (PCE) for the Pb-free perovskite solar cell is 8.9% which is lower than the highest PCE of 17.5% for the Pb-based perovskite solar cell.     

溢流型球磨机进料口密封装置的改进

分析了溢流型球磨机进料口矿浆泄漏的原因以及泄漏后给球磨机润滑系统和环境所带来的危害。通过对溢流型球磨机进料口密封装置的改进,减少和杜绝了矿浆泄漏,改善了球磨机运行环境,延长了润滑油使用周期、提高了球磨机有效作业率,降低了球磨机运行成本。     

Fabrication of 3D Ni nanosheet array on Crofer22APU interconnect and NiO-YSZ anode support to sinter with small-size Ag nanoparticles for low-temperature sealing SOFCs

A novel low-temperature sealing method was developed to seal solid oxide fuel cells. The 3D Ni nanosheet array was pre-fabricated on faying surfaces of Crofer22APU interconnect and NiO-YSZ anode-support. Then it was covered with Au film without changing its morphology. This special nanostructure improved sintering efficiency between Ag nanoparticles and substrates. A dense joint was obtained at the low-temperature between 250 °C–300 °C. This method effectively avoided the oxidation of interconnect during sealing. When joints were sealed at 300 °C, the shear strength reached 16 MPa. The fracture was mainly located in the central Ag layer, presenting a significant plastic deformation. Due to the effective protection of Ni layer, joints also possessed excellent oxidation resistance in oxidizing atmosphere at 800 °C for 400 h. After high-temperature oxidation, the shear strength was increased to 23 MPa, revealing an increasement of 43.8% compared with the as-sealed condition (16 MPa). This sealing method has great potential in sealing solid oxide fuel cells. It also can be extended to seal other energy-conversion devices.     

赵庄井田煤层气成藏条件研究

煤层气成藏条件研究是有效划分成藏类型或含气系统，煤层气富集高渗有利区预测、评价及优选的关键基础工作。基于赵庄井田煤层气地质条件及相关测试资料，借鉴前人研究成果，从煤生烃、煤层气储集和煤层气封盖保存条件等方面对赵庄井田煤层气成藏条件进行了研究。研究结果表明:煤中丰富的生烃物质在良好的生烃动力作用下，提高了生烃率和生烃量，为煤层气成藏提供了基础条件；煤变质程度高，促使煤中微小孔隙发育，煤层气储集能力增强和储集空间增大，有利于煤层气大量储存和富集；煤层埋深、围岩特性、构造及地下水径流等地质条件的有机匹配，为煤层气成藏提供了良好的封盖保存条件，是煤层气成藏的关键因素。     

油封唇口温度变化对密封性能的影响

基于流量因子统计学方法建立油封唇口的混合流体润滑模型,耦合油封的能量守恒方程及黏温方程,通过迭代求解获得油封唇口的温度分布、不同转速下油封唇口的最高温度及温差变化情况;对比分析考虑和不考虑温差情况下油封各项密封性能。结果表明:随着转速的增大,唇口最高温度线性递增,而唇口温差先增大后减小;油封工作时,唇口区域的温度先迅速升高后下降,越靠近唇尖的位置温度越高;与不考虑温度的情况比较,考虑温度变化的影响时密封区域的油膜厚度减小,油膜承载力下降,不利于密封。     

盐穴地下储气库密封性的测试与评价

对盐穴储气库系统密封性的测试与评价方法进行了详细介绍。测试方法选取原则、测试相关计算方法以及测试标准为储气库密封性测试的工程设计提供了详实的理论基础。     

不同类型断层控制油气垂向富集的差异——以渤海湾盆地歧口凹陷歧南斜坡区为例

渤海湾盆地历经多期构造变动，断层圈闭发育普遍。断层作为断层圈闭的边界条件，在油气成藏过程中起着至关重要的作用。以断层圈闭较发育的歧南斜坡区为例分析了同向断层和反向断层控制油气垂向富集的差异，基于三维地震资料，从断层形成过程和断层圈闭分布出发，剖析了断层遮挡圈闭的成因及分布规律。结合油水分布规律，基于油藏解剖并应用储层定量荧光技术明确了不同类型断层控藏的差异及其形成机理。研究表明：①断层分段生长作用和断层上盘与下盘的差异活动是同向断层控制下断层遮挡圈闭形成的主要原因，斜坡区反向断层控制形成的断层圈闭则是断块掀斜翘倾作用所致；②同向断层圈闭发育在断层上盘分段点位置，只有当同向断层进入"硬连接"阶段方可形成断层圈闭，反向断层圈闭形成在断层下盘，在反向断层活动初期便可形成；③同向断层既可以控制油气在多套含油气系统中聚集成藏，也可在一套含油气系统中富集，而反向断层往往控制油气在一套含油气系统中富集；④不同类型断层控制油气垂向聚集的差异与圈闭发育位置以及断-盖配置有关。采用泥岩涂抹系数对沙河街组一段中部盖层控制的含油气系统的垂向调整进行定量评价，泥岩涂抹系数低于3.5时油气保存，泥岩涂抹系数高于3.5时油气垂向渗漏。     

基于ABAQUS的变截面橡胶密封条热应力与密封性分析

研究用于发动机油气分离器的乙烯丙烯酸酯橡胶密封胶条在不同温度下的强度和密封性能。借助于大型有限元分析软件ABAQUS建立橡胶密封胶条与配合壳体的有限元模型,采用Mooney-Rivlin模型,对不同温度下的密封胶条进行热应力计算分析,得到橡胶密封胶条在不同温度下的Von Mises应力、压缩率、接触应力和接触宽度。结果表明:随着温度的升高,密封胶条的Von Mises应力和密封胶条与壳体连续接触面上的接触应力逐渐增加,接触宽度基本不变,密封条的压缩率逐渐减小;密封胶条的Von Mises应力远小于橡胶材料的拉伸强度,满足强度要求;密封胶条连续接触面上的接触应力始终大于油气分离器的工作压力且接触宽度符合要求,橡胶密封胶条满足密封条件。     

Corrosion and mechanical properties of plasma electrolytic oxidation‐coated AZ80 magnesium alloy

Plasma electrolytic oxidation (PEO) coatings were produced on AZ80 magnesium alloy in a solution containing silicates and phosphates and working at high current densities with short treatment times. The effect of a sealing treatment in boiling water on corrosion and mechanical properties of the coatings were investigated. Moreover, the corrosion mechanism of the samples with and without the sealing treatment was evaluated. The microstructure of the coatings was characterized with scanning electron microscope observation and X‐ray diffraction analysis. The mechanical properties were evaluated with nanoindentation tests and the corrosion resistance was studied by potentiodynamic polarization, electrochemical impedance spectroscopy, and scanning vibrating electrode technique. The results showed that the sealing did not influence the microstructure and the mechanical properties of the samples and instead produced a remarkable increase in the corrosion resistance. The crevice corrosion, present in the sample without the sealing, was avoided with the treatment in boiling water.     

软土地基的真空预压+水载法处理施工技术

结合横琴国际商务中心(二期)项目中的软土地基处理实践,介绍了真空预压+水载法施工技术。从真空预压加速固结、设置水泥土搅拌桩形成密封墙等方面出发,对关键工艺进行了阐述。真空预压+水载法施工技术实施后,项目取得了良好的社会效益和经济效益,可供相关工程参考。