基于成果导向的混合式教学研究与实践

为适应新形势下人才培养"成果导向"的要求,结合金属学及热处理课程特点,开展了混合式教学。充分尊重学生个体的独立性,以学生为中心设计教学活动,在自主探究过程中建构知识体系,工程素养和创新能力在循序渐进的教学中得到提升。     

Diporphyrin tweezer for multichannel spectroscopic analysis of enantiomeric excess

Chiral 1,1’-binaphthyl-linked diporphyrin ‘tweezers’ (R)-1/(S)-1 and the corresponding zinc(II) complexes (R)-2/(S)-2 were prepared as chiral host molecules, and their utility for chiral analyses (especially enantiomeric excess (ee) determinations) were evaluated. Tris(1-n-dodecyl)porphyrins were used for the first time as the interacting units. Host capabilities of the diporphyrin tweezers were investigated by titrations with (R,R)- and (S,S)-cyclohexane-1,2-diamine (CHDA). The host molecules could be used as multichannel probes of ee by using UV-vis, circular dichroism (CD), fluorescence emission and ¹H nuclear magnetic resonance (¹H-NMR) methods. Chiral configurations could also be differentiated using CD or ¹H-NMR spectroscopy. All three optical techniques give good resolution of ee with reasonable sensitivity considering the low concentrations used (ca. 10⁻⁶ mol·L⁻¹). The ee determination of CHDA enantiomers using NMR spectroscopy is also possible because of the reasonably well separated resonances in the case of (R,R)- and (S,S)-CHDA. Non-metallated (R)-1/(S)-1 hosts could not be used to detect chiral information in a strongly acidic chiral guest. This work demonstrates the utility of 1,1’-binapthyl-linked chiral hosts for chiral analysis of ditopically interacting enantiomers.     

海上石油平台继电保护设备动态模型测试技术研究

海上石油平台电网独立于陆地电网,发电机组容量较小,属于典型的孤岛电网,对大负荷波动、故障扰动平抑能力较弱,要求继电保护设备在电网故障时能够准确、迅速动作,切除故障线路,保证电网迅速回归稳定,但传统测试设备无法输出含非周期分量的全电流,也无法搭建平台电网模型,测试复杂故障中继电保护设备的动作情况,不满足对其全面测试、研究要求.针对当前保护设备测试缺陷,提出构建基于DDRTS系统的继电保护设备动模测试系统,实现对保护设备的全面测试和运行状态评价.     

界面张力及乳化效果对提高采收率的贡献

以中国石油冀东油田原油为研究对象,筛选并评价了具有不同界面张力及乳化效果的4组驱油体系,研究了界面张力与乳化效果对提高原油采收率的贡献。实验结果表明,油水界面张力与原油乳化效果之间没有明显的一致性,当以0.1%(w)的Na_2CO_3或0.5%(w)Na_2CO_3+0.3%(w)JS-33复配体系为驱油剂时,界面张力均可达到超低,但乳化效果较差,析水率分别高达91.7%和83.3%,而原油采收率提高值只有8.9%和12.4%;当以0.5%(w)的Na_2CO_3或0.5%(w)Na_2CO_3+0.5%(w)JS-33复配体系为驱油剂时,界面张力分别为10~(-2)和10~(-3)数量级,乳化效果较好,析水率分别为1.7%和0,原油采收率提高值达27.5%和24.4%。乳化效果好的驱油体系原油采收率提高值要高于超低界面张力体系,乳化效果相比界面张力而言对提高采收率的贡献占主要部分。     

基于产教融合的增量式案例驱动教学模式

通过对目前应用型人才培养在实现过程中所面临的困境进行分析,针对软件开发类课程教学过程中存在的不足,提出将基于产教融合的增量式案例驱动教学法引入教学,给出上述教学模式在实际授课中的设计及实现方案,以软件开发类课程为载体探讨遇到的问题并提出建议。     

Strain rate dependency and fragmentation pattern of expanding warheads

For the characterization of the behaviors of a metal material in events like expanding warheads, it is necessary to know its strength and ductility at high strain rates, around 104e105/s. The flyer plate impact testing produces the uniform stress and strain rates but the testing is expensive. The Taylor test is relatively inexpensive but produces non-uniform stress and strain fields, and the results are not so easily inferred for material modeling. In the split-Hopkinson bar(SHB), which may be used in compression, tension and torsion testing, the strain rates never exceeds 103/s. In the present work, we use the expanding ring test where the strain rate is 104e105/s. A streak camera is used to examine the expanding ring velocity, and a water tank is used to collect the fragments. The experimental results are compared with the numerical simulations using the hydrocodes AUTODYN, IMPETUS Afea and a regularized smooth particle(RSPH) software. The number of fragments increases with the increase in the expansion velocity of the rings. The number of fragments is similar to the experimental results. The RSPH software shows much the same results as the AUTODYN where the Lagrangian solver is used for the ring. The IMPETUS Afea solver shows a somewhat different fragmentation characteristic due to the node splitting algorithm that induces pronounced tensile splitting.     

Performance of insulated FRP-strengthened concrete flexural members under fire conditions

This paper presents the results of fire resistance tests on carbon fiber-reinforced polymer (CFRP) strengthened concrete flexural members, i.e., T-beams and slabs. The strengthened members were protected with fire insulation and tested under the combined effects of thermal and structural loading. The variables considered in the tests include the applied load level, extent of strengthening, and thickness of the fire insulation applied to the beams and slabs. Furthermore, a previously developed numerical model was validated against the data generated from the fire tests; subsequently, it was utilized to undertake a case study. Results from fire tests and numerical studies indicate that owing to the protection provided by the fire insulation, the insulated CFRP-strengthened beams and slabs can withstand four and three hours of standard fire exposure, respectively, under service load conditions. The insulation layer impedes the temperature rise in the member; therefore, the CFRP–concrete composite action remains active for a longer duration and the steel reinforcement temperature remains below 400°C, which in turn enhances the capacity of the beams and slabs.     

非常规蛋白基木材胶黏剂研究现状及发展前景

介绍了动物和植物型非常规蛋白资源的种类及其制备蛋白基木材胶黏剂的研究现状和存在的问题,展望了非常规蛋白胶黏剂的发展前景。