独立学院《环境监测实验》课程教学改革

从独立学院"应用型专业人才"的培养目标出发,结合我院近年来开展《环境监测实验》课程积累的经验,对本实验课程的教学内容、教学方法和课程评价体系等进行了改革。强调理论与实验内容有机结合,通过激发学生的学习兴趣,提高学生的实践应用能力,以满足社会对环境科学与工程专业应用型专业人才的需求。     

Highly active sites of low spin FeⅡN4species:The identification and the ORR performance

Over recent years,catalytic materials of Fe-N-C species have been recognized being active for oxygen reduction reaction(ORR).However,the identification of active site remains challenging as it generally involves a pyrolysis process and mixed components being obtained.Herein Fe₃C/C and Fe₂N/C samples were synthesized by temperature programmed reduction of Fe precursors in 15%CH₄/H₂and pure NH₃,respectively.By acid leaching of Fe₂N/C sample,only single sites of FeN₄species were presented,providing an ideal model for identification of catalytic functions of the single sites of FeN₄in ORR.A correlation was conducted between the concentration of Fe^ⅡN₄in low spin state by Mossbauer spectra and the kinetic current density at 0.8 V in alkaline media,and such a structure-performance correlation assures the catalytic roles of low spin Fe^ⅡN₄ species as highly active sites for the ORR.     

基于统计软件R的安全壳泄漏率试验数据有效性分析

安全壳泄漏率计算过程中，最重要的环节是以不同时刻测量数据对时间进行线性回归分析。对回归的显著性检验以及方差分析是评价试验结果有效性的重要手段。本文基于统计软件R对某电厂调试阶段安全壳泄漏率试验的数据进行分析，通过对线性回归模型的独立性、正态性和异方差性检验以及极端样本点的剔除等方式，探讨泄漏率计算前的回归诊断对计算结果可靠性的影响。通过回归诊断的实例分析发现，在安全壳泄漏率计算的数据样本中，可能存在自相关、非正态和异方差性等问题影响回归结果，进而影响泄漏率的最终结果。因此，在计算泄漏率结果时，须通过回归诊断方法评价数据的有效性，对不能通过检验的样本应通过适当方法对最终结果进行修正。      

The formation of fibrous structure of polyamide 6 induced by the three-step forming process and its prominent reinforcement in nitrile rubber

Nitrile rubber (NBR) blends with excellent performance have always been a hot research topic in petroleum field. Due to the excellent performance and compatibility of polyamide 6 (PA6), it provides an opportunity for the preparation of high-performance NBR/PA6 blends. In this article, NBR/PA6 blends were prepared by the three-step molding process. Experimentally, it was found that PA6 has a prominent reinforcement effect in NBR matrix. The variation of this mechanical property was investigated from different aspects of the crystal structure, crystallinities, phase morphology, and so on. It can be cleared that the formation of fibrous structure of PA6 phase is the main factor for reinforcement of the polymer blends. Meanwhile, the formation mechanism of the special phase structure induced by the three-step process is deeply expounded and its structural evolution schematic is established. © 2019 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2019 , 136, 47472.     

井工转露天采区顶板厚度不足诱发滑坡问题研究

井工转露天开采是安全生产遇到的新问题。以紫金山金铜矿为背景，利用数值模拟法系 统研究了井 工转露天开采工况下顶板厚度从 68 m 逐渐减小至 44 m 时顶板的安全性，界定出顶板最小安 全厚度为 45 m。同时 系统研究了顶板厚度变化对上部边坡应力场的影响特点，得出随着顶板变薄坡脚处塑性破坏区 增大，导致边坡稳 定性变小的规律，并通过边坡稳定性分析计算验证其正确性。因此在井工转露天开采过程中， 为了确保安全生产 需要确保顶板有足够的厚度，避免作业设备和工作人员坠入老井采区及滑坡灾害发生。     

Effects of B2O3 on Crystallization,Structure, and Heat Transfer of CaO-Al2O3-Based Mold Fluxes

Metallurgical and Materials Transactions B - The reaction between traditional CaO-SiO2-based mold fluxes and high-Al steel inevitably changes flux composition, and, consequently, flux properties....     

Evaluation of bismuth doped La2-xBixNiO4+δ (x = 0, 0.02 and 0.04) as cathode materials for solid oxide fuel cells

Bismuth doped La_2-xBi_xNiO_4+δ (x = 0, 0.02 and 0.04) oxides are investigated as SOFC cathodes. The effects of Bi doping on the phase structure, thermal expansion, electrical conduction behavior as well as electrochemical performance are studied. All the samples exist as a tetragonal Ruddlesden-Popper structure. Bi-doped LBNO-0.02 and LBNO-0.04 have good chemical and thermal compatibility with LSGM electrolyte. The average TEC over 20–900°С was 13.4 × 10^?6 and 14.2 × 10^?6 K^?1 for LBNO-0.02 and LBNO-0.04, respectively. The electrical conductivity was decreasing with the rise of Bi doping content. EIS measurement indicates Bi doping can decrease the ASR values. At 750 °C, the obtained ASR for LBNO-0.04 is 0.18 Ωcm², which is 56% lower than that of the sample without Bi doping, suggesting Bi doping is beneficial to the electrochemical catalytic activity of LBNO cathodes.     

Cyclic thermal shock resistance of h-BN composite ceramics with La2O3–Al2O3–SiO2 addition

The effects of La₂O₃–Al₂O₃–SiO₂ addition on the thermal conductivity, coefficient of thermal expansion (CTE), Young's modulus and cyclic thermal shock resistance of hot-pressed h-BN composite ceramics were investigated. The samples were heated to 1000 °C and then quenched to room temperature with 1–50 cycles, and the residual flexural strength was used to evaluate cyclic thermal shock resistance. h-BN composite ceramics containing 10 vol% La₂O₃–Al₂O₃ and 20 vol% SiO₂ addition exhibited the highest flexural strength, thermal conductivity and relatively low CTE, which were beneficial to the excellent thermal shock resistance. In addition, the viscous amorphous phase of ternary La₂O₃–Al₂O₃–SiO₂ system could accommodate and relax thermal stress contributing to the high thermal shock resistance. Therefore, the residual flexural strength still maintained the value of 234.3 MPa (86.9% of initial strength) after 50 cycles of thermal shock.