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本文评述了TiO_2半导体陶瓷在氧敏、湿敏、pH敏以及其他传感材料中的应用,结合作者近期的研究结果,对其有关敏感机理作了分析,并对TiO_2传感材料的多功能开发作了一定探讨。 相似文献
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IR and EXAFS spectra of two binaryBi_2O_3-GeO_2 and Bi_2O_3-B_2O_3 glasses aremeasured,the effect of Bi~(3+) on B-O,Ge-Onetwork structure is analysed,and thelocal structure of Bi~(3+) in oxide glasseshas been discussed.The results show:Bi_2O_3 can introduce some non-bridgingoxygens to Bismuth Germanate glasses todepolymerize the Ge-O tetrahedronnetwork and give part of its oxygens toBismuth Borate glasses to form four-coordinated sites.Asymmetric [BiO_6]octahedra are distorted in oxide glasses.The highly polarizable Bi~(3+) ions partici-pate in the structure of oxide glasses byforming [BiO_3] groups. 相似文献
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通过气氛模拟实验,研究了TiO_2气敏元件的空燃比(A/F)敏感特性;借助气体边界层模型分析了临界值(A/F)_c的偏移现象。测定了气孔率、催化剂等对气敏速度的影响。采用EPMA技术,分析了元件表面污染状态对其使用寿命的影响。并初步探讨了掺杂对TiO_2电性能的影响以及TiO_2的自身催化氧化过程。 相似文献
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Room temperature EXAFS spectra of a series ofgallium phosphate glasses have been obtained in alaboratory EXAFS facility.Fourier transform isemployed for EXAFS data analysis.Low-cristobalitetype GaPO_4 crystal is used as a standard specimento extract the local structure parameters of Gaatoms in Ga_2O3-P_2O_5 glasses.The Ga-O average bondlength is 1.75-1.86 and Ga atoms can form both[GaO_4] tetrahedra and [GaO_6] octahedra in some ofthese glasses.The coordination number of Ga atomschanges from six to four with the increase of Ga_2O_3content,and this change becomes more significantwhen the Ga_2O_3 content exceeds 30mol%.The anomalouschange of the refractive index at 30mol% Ga_2O_3 iscaused by the change of the local structure of Gafrom [GaO_6] octahedra to [GaO_4] tetrahedra.A simpleformula to estimate the concentration of six foldcoordinated Ga atoms in glasses is derived based onaverage bond length measured from the EXAFS. 相似文献
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本文采用混合溶剂法对硅酸盐玻璃进行三甲基硅烷化,通过气相色谱-质谱联用分析,以测定硅酸盐玻璃中硅酸根的聚合度及其分布。 相似文献
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本文测定了铋锗酸盐、铋硼酸盐玻璃的IR光谱和EXAFS谱,分析了Bi~(3+)对B-O、Ge-O网络结构的影响,讨论了Bi~(3+)在氧化物玻璃中的结构形态。结果表明:Bi_2O_3能够给锗酸盐玻璃提供非桥氧,使[GeO_4]四面体构成的结构网络解聚;Bi_2O_3能够提供游离氧给硼酸盐玻璃,使[BO_3]三角体转变成[BO_4]四面体。晶体中不规则的[BiO_6]八面体在玻璃中产生了更为严重的畸变,使极化率很大的Bi~(3+)离子在氧化物玻璃中可能以低配位的[BiO_3]基团形式存在。 相似文献
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本文通过正电子湮没寿命谱分析了ZrO_2材料电导率σ与稳定剂含量的关系,研究表明材料中的“有效空位量”是决定σ的关键因素,解释了σ随稳定剂含量的变化规律 相似文献
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