煤磨热风管线旋风收尘器的改造

对5?000 t/d生产线煤磨热风管线收尘器进行改造，拆除原双旋风收尘器，利用原框架，缩小旋风筒直径与高度比例，提高旋风筒高度，缩小内筒直径尺寸，来提高收尘效率。改造后入窑煤粉灰分5?000 t/d线与2?000 t/d线差异减小到0.05%，相对降低了1.17%。     

One step method of structure engineering porous graphitic carbon nitride for efficient visible-light photocatalytic reduction of Cr(Ⅵ)

Porous g-C3N4 nanosheets (PCN) were prepared by the nickel-assisted one-step thermal polymerization method.Hydrogen (H2) which was produced by the reaction between nickel (Ni) foam and ammonia (NH3) defined the structure and properties of PCN.During the formation of PCN,the participation of H2 not only enhanced the spacing between layers but also boosted the specific surface area that more active sites were exposed.Additionally,H2 promoted pores formation in the nanosheets,which was beneficial to the transfer of photons through lamellar structure and improved the absorption efficiency of visible light.Remarkably,the obtained PCN possessed better Cr(Ⅵ) photocatalytic reduction efficiency than pure g-C3N4.The reaction rate constant (k) of PCN (0.013 min-1) was approximately twice that of bare g-C3N4 (0.007 min-1).Furthermore,the effects of original pH and concentration of Cr(Ⅵ)-containing solution on removal efficiency of Cr(Ⅵ) were explored.A possible photocatalytic mechanism was proposed based on the experiments of radical scavengers and photoelectrochemical characterizations.     

Electrochemical performance of in situ LiFePO4 modified by N-doped graphene for Li-ion batteries

LiFePO₄ modified by N-doped graphene (NG) with a three-dimensional conductive network structure was synthesized via a one-step in situ hydrothermal method. The effects of N amount of NG on the phase structure, morphology, and electrochemical properties of LiFePO₄ are investigated in this study. X-ray diffraction (XRD) results show that doping suitable N amounts in NG do not alter the crystal structure of LiFePO_4, and scanning electron microscopy (SEM) images show that NG can slightly reduce the particle size of LiFePO₄. The high-resolution transmission electron microscopy (HRTEM) results show that the LiFePO₄ particles are well covered and connected by NG. The electrochemical performance confirms that LiFePO₄ modified by 20% N-doped graphene (named LFP/NG-4) displays a perfect specific capacity of 166.6 mAh·g^?1 at a rate of 0.2C and can reach 125 mAh·g^?1 at a rate of 5 C. Electrochemical impedance spectroscopy (EIS) results illustrate that the charge transfer resistance value of the LFP/NG-4 composite is only 58.6 Ω, which is very low compared with LiFePO₄. Cyclic voltammetry (CV) tests indicate that the addition of 20% N-doped graphene can effectively reduce electrode polarization and improve reversibility. The LFP/NG-4 composite with a three-dimensional conductive network structure can be regarded as a promising cathode material for Li-ion batteries.     

Stable Radicals with Protective Umbrellas Integrated on the Surface of 2D Layered Materials

Radicals are closely related to human life and health and have been widely used in biology, chemistry, functional materials, etc. However, the high reactivity, disorder, and short half-lives limit their wide applications. Therefore, it remains a great challenge to prepare stable and ordered radicals. Herein, radicals are prepared with protective umbrellas (diethylmethyleneamine, DEMA) that are integrated on the surface of 2D layered materials to isolate water and oxygen and enhance the stability of radicals. Taking 2D black phosphorus (BP) as an example: triethylamine reacts with dichloromethane to form quaternary ammonium salts with further Hoffmann elimination to produce DEMA radicals that could react with one electron of a lone pair electrons in P on the surface of BP to produce P radicals, which shows a prolonged half-life of 21 days at room temperature. First-principle calculations and electron paramagnetic resonance fitting confirm that the steric hindrance constructed by dense DEMA passivation layer acts as a protective umbrella and the 2D coupling of P radicals and other P atoms in 2D BP plane to enhance the stability and strong superexchange interaction of P radicals. Furthermore, it is a general strategy to produce stable radicals integrated on the 2D plane.     

Nanocrystallization and optical properties of CsPbBr3−xIx perovskites in chalcogenide glasses

The confinement of CsPbX₃ (X = Cl, Br, and I) perovskite nanocrystals (NCs) in a stabilized inorganic glass matrix is a new strategy for improving their long-term stability and promoting their applications in the optoelectronic field. Here, in situ nanocrystallization strategy is developed to precipitate CsPbBr_3?xI_x NCs with arbitrary I/Br ratio among an elaborately designed GeS₂–Sb₂S₃-based chalcogenide glass matrix. Spherical CsPbBr_3?xI_x NCs are homogeneously distributed in the glass matrix after thermal treatment. The photoluminescence (PL) spectra show that the emission peaks of CsPbBr_3?xI_x NCs can be tuned from 570 nm to 722 nm with the replacement of Br by I. The fs transient absorption (TA) spectra reveal that there exists some structural defects in the NCs, leading to short PL decay life. This work would shed light on confining CsPbX₃ NCs into glassy matrices, facilitating their future applications in photoelectronic fields.     

Study on the Minimum Flow Pore Throat Radius and the Lower Limit of Petrophysical Properties of a Reservoir Under Three Seepage States

Chemistry and Technology of Fuels and Oils - Through the analysis of the reservoir seepage capacity and high-pressure mercury intrusion porosimetry, the minimum flow pore throat radius and the...     

Engineering 2D Arsenic-Phosphorus Theranostic Nanosheets

As an anticancer drugs, arsenic trioxide (ATO) has been certified to efficiently treat refractory acute promyelocytic leukemia (APL). Unfortunately it suffers from limited therapeutic potency for solid tumors due to its in vivo restricted administration dose and rapid renal clearance. Herein, distinct 2D arsenic-phosphorus (AsP) nanosheets are engineered by adopting an alloy strategy followed by exfoliation, which can confine toxic arsenic into AsP crystals, thus significantly improving the biosafety and biocompatibility of arsenic-based chemotherapeutic drugs. Of particular note, the high light absorption and strong photothermal-conversion efficiency (37.6%) in the second near infrared biowindow (NIR-II) of AsP nanosheets not only endow them with desirable contrast-enhanced photoacoustic imaging properties, but also achieve efficient local tumor hyperthermia, which further synergistically triggers the in-situ transformation from low toxic/nontoxic AsP crystals into highly toxic arsenic species, exerting a strong arsenic-mediated antineoplastic effect. Both in vitro and in vivo data verify the synergy between photonic therapy in NIR-II and enhanced chemotherapy as enabled by AsP nanosheets, paving the way for efficient nanomedicine-enabled arsenic-based chemotherapeutic tumor treatment.     

深竖井大吨位提升机高比压高摩擦因数衬垫的研制

针对深竖井、大吨位的提升条件下,摩擦衬垫需要高比压和高摩擦因数的难题,在工况分析和参数设计的基础上,研制了比压为2.5 MPa、摩擦因数为0.28的摩擦衬垫,并分别对衬垫的稳定性、抗比压能力、硬度特性、压力特性和磨损情况进行试验.委托第三方检测验证,衬垫的比压试验值达到9.8 MPa,摩擦因数试验值达到0.381,满足实验室的指标要求.