Challenges and considerations for planning toward sustainable biodiesel development in developing countries: Lessons from the Greater Mekong Subregion

Biodiesel has the potential to economically, socially, and environmentally benefit communities as well as countries, and to contribute toward their sustainable development. Nonetheless, the complex nature of biodiesel development makes it susceptible to exogenous problems that could hinder sustainable development. To ensure that biodiesel development actually leads to a sustainable path, all possible issues and challenges need to be identified and analyzed up front, so that they can be prepared for and handled in the planning and management stages. Building upon lessons learned from biodiesel developments in the Greater Mekong Subregion, this work examines biodiesel development in developing countries in the aspects of policy, governance, management, infrastructure, technology, feedstock, impacts on the rural poor and local livelihood, climate change, and the environment. Issues within each aspect are also analyzed in the context of developing countries. As a result, this review can serve as a guideline for ensuring that biodiesel development contributes toward sustainable development in developing countries.     

A comparative study of KOH/Al2O3 and KOH/NaY catalysts for biodiesel production via transesterification from palm oil

The transesterification of palm oil to methyl esters (biodiesel) was studied using KOH loaded on Al₂O₃ and NaY zeolite supports as heterogeneous catalysts. Reaction parameters such as reaction time, wt% KOH loading, molar ratio of oil to methanol, and amount of catalyst were optimized for the production of biodiesel. The 25 wt% KOH/Al₂O₃ and 10 wt% KOH/NaY catalysts are suggested here to be the best formula due to their biodiesel yield of 91.07% at temperatures below 70 °C within 2–3 h at a 1:15 molar ratio of palm oil to methanol and a catalyst amount of 3–6 wt%. The leaching of potassium species in both spent catalysts was observed. The amount of leached potassium species of the KOH/Al₂O₃ was somewhat higher compared to that of the KOH/NaY catalyst. The prepared catalysts were characterized by using several techniques such as XRD, BET, TPD, and XRF.     

Utilization of palm oil alkyl esters as an additive in ethanol-diesel and butanol-diesel blends

This research focuses on the use of biodiesel as an additive in diesohol preparation. Three types of biodiesel—methyl, ethyl, and butyl esters—were prepared from palm oil through transesterification using a conventional base catalyst. Ethanol is generally used to blend in diesohol; however, butanol is another alcohol which has higher solubility in diesel than ethanol and it can improve the fuel properties of the blends. Therefore, a comparative study of phase stability, the dependence of solubility on temperature (10, 20, and 30 °C), and an evaluation of some basic fuel properties according to the ASTM of diesel-biodiesel-ethanol and diesel-biodiesel-butanol three-component systems at different component concentrations was done. We found that the use of butanol in diesohol could solve the problem of fuel instability at low temperatures because of its higher solubility in diesel fuel. In addition, the fuel properties results indicated that blends containing butanol have properties closer to diesel than those of blends containing ethanol.