Preparation and evaluation of linseed oil based alkyd paints

Alkyd resins are produced with reaction of oil or fatty oil, polyol and polyacid. Alkyd resins are commonly used in coating and paint industry due to ease of application in changing environmental conditions. Linseed oil based paints executed all requirements of technical properties, drying time, storage properties, simplicity in maintenance, appearance, economy, etc. In this study, linseed oil based alkyd resins having different oil contents were synthesized     

Hybrid dual-curable cyanate ester/boron phosphate composites via sequential thiol-ene photopolymerization and thermal polymerization

The aim of this study was to improve hybrid dual-curable cyanate ester/boron phosphate composites via sequential thiol-ene photopolymerization and thermal polymerization for high performance applications such as aerospace and electronic devices. A novel 2,2′-diallylbisphenol A dicyanate ester (DA-BADCy) which is the allyl group containing cyanate ester was synthesized and characterized. DA-BADCy, silicon containing monofunctional thiol compound, trifunctional thiol compound and boron phosphate were cured using both ultraviolet (UV) and thermal methods. Using thiol-ene system, cyanate ester formulations, which are normally prepared at high temperatures, were prepared at room temperature. This study maintains ease of application for cyanate esters. Thermal stability, flammability and thermal conductivity of the samples were evaluated by thermogravimetric analysis (TGA), differential scanning calorimetry (DSC), limiting oxygen index (LOI) and laser flash method, respectively. The samples were characterized with the following analysis; gel content, water absorption capacity and stress–strain test. Hydrophobicity of the samples was determined by the contact angle measurements. Moreover, the surface morphology of the samples was investigated by a scanning electron microscopy (SEM–EDS). The obtained results prove that the composites have good thermal and mechanical properties and with the help of easier preparation techniques, they can be used in many applications such as aerospace, electronic devices, materials engineering.     

Surface Characterization of Mild Steel During Atmospheric Corrosion After Being Treated by Sodium Dihydrogen Orthophosphate

Protection of Metals and Physical Chemistry of Surfaces - The objective of this study was to characterize the surfaces of the steel products produced locally during their exposure to the industrial...     

Preparation and thermal properties of polyethylene terephthalate/huntite–hydromagnesite composites

In this report, it was aimed to the improve thermal stability of polyethylene terephthalate (PET) by adding huntite/hydromagnesite minerale. PET/huntite/hydromagnesite composites were prepared by adding various proportions of huntite/hydromagnesite to PET. The chemical structures of the composites were characterized by Fourier transform infrared spectroscopy (FTIR) and X‐ray diffraction (XRD) analysis. Thermal properties of the composites were determined by thermogravimetric analysis (TGA) and differential scanning calorimetry (DSC). Glass‐transition temperatures and char yields increased with the increase of the huntite/hydromagnesite content in the composites. The surface morphologies of the composites were investigated by a scanning electron microscopy. The obtained results proved that the composite system is more thermally stable than the pure PET itself. POLYM. COMPOS., 37:3275–3279, 2016. © 2015 Society of Plastics Engineers     

Estimating the uniaxial compressive strength of pyroclastic rocks from the slake durability index

Because the preparation of standard samples may not always be possible for weak or soft rocks, the prediction of uniaxial compressive strength (UCS) from indirect methods is widely used for preliminary investigations. In this study, the possibility of predicting UCS from the slake durability index (SDI) was investigated for pyroclastic rocks. For this purpose, pyroclastic rocks were collected from 31 different locations in the Cappadocian Volcanic Province of Turkey. The UCS and SDI tests were carried out on the samples in the laboratory. The UCS values were correlated with the SDI values and a very strong exponential relation was found between the two parameters. Since some data were scattered over the UCS values of 20 MPa, the correlation plot was redrawn for above and below the UCS values of 20 MPa, respectively. Very strong linear correlations were developed for two cases. Our concluding remark is that the UCS of pyroclastic rocks can be estimated from the SDI.

     

The study of MIG weldability of heat-treated aluminum alloys

In this article, Metal Inert Gas (MIG) weldability of commercially received and aged samples of 6061-T₆ and 7075-T₆₅₁ aluminum alloys was investigated. The welding joints were prepared in ten different combinations. Microstructure, microhardness, EDX, energy-dispersive spectroscopy (EDS), and X-ray diffraction (XRD) analyses were used in order to evaluate the effect of aged heat treatment on the performance of welded joints. In addition, the mechanical properties of welding joints were characterized using the tensile and microhardness tests. In conclusion, it was shown that prewelding aging heat treatment improves the mechanical properties of welding joints.     

An integrated fuzzy AHP–ELECTRE methodology for environmental impact assessment

Environmental impact assessment (EIA) is the assessment of the possible impact that a proposed plan or project may have on the environment, together consisting of the natural, social and economic aspects. The aim of this paper is to propose an environmental impact assessment methodology based on an integrated fuzzy AHP–ELECTRE approach in the context of urban industrial planning. In the proposed methodology the criteria weights are generated by a fuzzy AHP procedure. The fuzzy set theory is a perfect means for modeling uncertainty or imprecision arising from human mental phenomena. The usage of fuzzy sets in describing uncertainties and vagueness in different environmental factors simplifies the complex structure of EIA. A fuzzy outranking methodology, fuzzy ELECTRE is used to assess the environmental impact generated by the six different industrial districts which were predicted to shape the future industrial structure of Istanbul metropolitan area. Finally, a fuzzy dominance relation (FDR) methodology is used to rank the alternatives from the most risky to the least. A sensitivity analysis is also provided.     

Modifications in the properties of gypsum construction element via addition of expanded macroporous silica granules

The present study is focused on the production of light weight silicate based macroporous filler for hardened gypsum and its effect on the product properties. Highly porous, durable foam like silica granules were produced from the relatively low cost material of silica gel desiccant. Swelling behaviour and mineralogical structure of the granules after swelling were examined. Different sample series were produced by replacing gypsum by expanded silica gel. Physical properties of the hardened gypsum were improved by the addition of expanded silica gel granules. Thermal conductivity of the gypsum decreased significantly when the expanded silica gel granules introduced into the gypsum. Expanded silica gel addition also improved the high temperature durability of gypsum. Much better integrity was observed after the testing of samples at 700 °C when compared to control series.