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排序方式: 共有3645条查询结果,搜索用时 265 毫秒
1.
Liting Yang Xiao Li Ke Pei Wenbin You Xianhu Liu Hui Xia Yonggang Wang Renchao Che 《Advanced functional materials》2021,31(35):2103971
Large interfacial resistance plays a dominant role in the performance of all-solid-state lithium-ion batteries. However, the mechanism of interfacial resistance has been under debate. Here, the Li+ transport at the interfacial region is investigated to reveal the origin of the high Li+ transfer impedance in a LiCoO2(LCO)/LiPON/Pt all-solid-state battery. Both an unexpected nanocrystalline layer and a structurally disordered transition layer are discovered to be inherent to the LCO/LiPON interface. Under electrochemical conditions, the nanocrystalline layer with insufficient electrochemical stability leads to the introduction of voids during electrochemical cycles, which is the origin of the high Li+ transfer impedance at solid electrolyte-electrode interfaces. In addition, at relatively low temperatures, the oxygen vacancies migration in the transition layer results in the formation of Co3O4 nanocrystalline layer with nanovoids, which contributes to the high Li+ transfer impedance. This work sheds light on the mechanism for the high interfacial resistance and promotes overcoming the interfacial issues in all-solid-state batteries. 相似文献
2.
Applied Intelligence - With the development of sensor and communication technology, industrial systems have accumulated a large amount of data. This data has provided new perspectives and methods... 相似文献
3.
擦拭样品微粒分析技术是核保障环境样品分析的一种主要手段,从大量灰尘颗粒中识别并定位含高浓铀(HEU)或含Pu微粒是微粒分析首先需要解决的问题。本文以HEU和Pu微粒为研究对象,建立了用于微粒α径迹测量的样品制备方法,采用CR-39固体径迹探测器为α径迹探测器,测量了不同蚀刻时间2种微粒产生的α径迹星的径迹参数。结果表明:可通过测量径迹短轴与曲率直径并作图来分辨HEU和Pu微粒,该方法对于蚀刻时间大于10 h的微粒径迹星,均能明显分辨,对于径迹非常密集的径迹星,也能准确分辨。 相似文献
4.
Chengyong Yang Bolong Huang Shuxing Bai Yonggang Feng Qi Shao Xiaoqing Huang 《Advanced materials (Deerfield Beach, Fla.)》2020,32(24):2001267
Electrocatalytic nitrogen reduction reaction (NRR) is a promising process relative to energy-intensive Haber–Bosch process. While conventional electrocatalysts underperform with sluggish paths, achieving dissociation of N2 brings the key challenge for enhancing NRR. This study proposes an effective surface chalcogenation strategy to improve the NRR performance of pristine metal nanocrystals (NCs). Surprisingly, the NH3 yield and Faraday efficiency (FE) (175.6 ± 23.6 mg h–1 g–1Rh and 13.3 ± 0.4%) of Rh-Se NCs is significantly enhanced by 16 and 15 times, respectively. Detailed investigations show that the superior activity and high FE are attributed to the effect of surface chalcogenation, which not only can decrease the apparent activation energy, but also inhibit the occurrence of the hydrogen evolution reaction (HER) process. Theoretical calculations reveal that the strong interface strain effect within core@shell system induces a critical redox inversion, resulting in a rather low valence state of Rh and Se surface sites. Such strong correlation indicates an efficient electron-transfer minimizing NRR barrier. Significantly, the surface chalcogenation strategy is general, which can extend to create other NRR metal electrocatalysts with enhanced performance. This strategy open a new avenue for future NH3 production for breakthrough in the bottleneck of NRR. 相似文献
5.
通过有限元仿真软件Autoform分析了热冲压过程中工艺参数的变化对22MnB5马氏体钢B柱起皱、回弹、减薄、马氏体量以及强度的影响。结果表明:22MnB5马氏体钢B柱热冲压最优化工艺参数为加热温度930 ℃,冷却速率80 ℃/s。该工艺参数下,热冲压过程各处均完成马氏体转变,硬度分布均匀,材料减薄率较低,热冲压成形效果好,尺寸精度高,冲压件强度均大于1400 MPa。 相似文献
6.
为研究铝合金三角形波纹夹芯板对平头弹体的抗冲击性能及损伤特性,利用有限元软件ABAQUS/Explicit建立弹体冲击靶板的数值模拟模型,并结合实验验证了模型及其参数的有效性。基于数值计算结果,分析了三角形波纹夹芯板几何结构对其防护性能、失效模式和能量吸收的影响规律及机理,并与等面密度单层板进行对比分析,研究结果表明,靶体几何结构对其抗冲击性能存在影响,三角形波纹夹芯板抗冲击性能低于单层板抗冲击性能。此外,增加芯体拓扑结构夹角能显著提高三角形波纹夹芯板的抗冲击性能,并且靶板几何形状会对其失效模式及耗能特性存在影响。 相似文献
7.
Chenxu Liu Shuguang Zhang Ruonan Ji Peng Wang Jin Zhang Yu Tian Yonggang Meng Yedong He 《Ceramics International》2019,45(4):4747-4755
Semiconductor particles doped Al2O3 coatings were prepared by cathode plasma electrolytic deposition in Al(NO3)3 electrolyte dispersed with SiC micro- and nano-particles (average particle sizes of 0.5–1.7?µm and 40?nm respectively). The effects of the concentrations and particle sizes of the SiC on the microstructures and tribological performances of the composite coatings were studied. In comparison with the case of dispersing with SiC microparticles, the dispersion of SiC nanoparticles in the coatings was more uniform. When the concentration of SiC nanoparticles was 5?g/L, the surface roughness of the composite coating was reduced by 63%, compared with that of the unmodified coating. Friction results demonstrated that the addition of 5?g/L SiC nanoparticles reduced the friction coefficient from 0.60 to 0.38 and decreased the wear volume under dry friction. The current density and bath voltage were measured to analyze the effects of SiC particles on the deposition process. The results showed that the SiC particles could alter the electrical behavior of the coatings during the deposition process, weaken the bombardment of the plasma, and improve the structures of the coatings. 相似文献
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10.
实验构建了人工湿地-微生物电解池耦合系统(CW-MEC),并考察了CW-MEC在阴极有无曝气及不同水力停留时间(HRT)的条件下对生活污水的处理效果。实验结果显示,降低HRT会让CW-MEC阴极、阳极的COD去除率由91.11%±7.76%、86.58%±9.54%降低为77.81%±14.84%、81.44%±11.11%,氨氮去除率由58.54%±5.80%、58.22%±5.03%降低为48.04%±12.94%、48.27%±13.40%;阴极增加曝气会让CW-MEC阴极、阳极的COD去除率分别提高到89.51%±3.92%、82.40%±1.63%,阴极氨氮去除率提高到71.51%±16.44%,而阳极氨氮去除率不受影响;增加阴极曝气条件后,系统阴、阳极开始有硝酸盐氮积累,而CW-MEC阴极的硝酸盐氮含量明显低于对照组(CW-MFC);通过电化学性能分析,相对于CW-MFC系统,CW-MEC具有更低的内阻;通过微生物多样性分析,CW-MEC系统具有更丰富的微生物多样性。 相似文献