Nido-Hydroborate-Based Electrolytes for All-Solid-State Lithium Batteries

Hydroborate-based solid electrolytes have recently been successfully employed in high voltage, room temperature all-solid-state sodium batteries. The transfer to analogous lithium systems has failed up to now due to the lower conductivity of the corresponding lithium compounds and their high cost. Here LiB₁₁H₁₄ nido-hydroborate as a cost-effective building block and its high-purity synthesis is introduced. The crystal structures of anhydrous LiB₁₁H₁₄ as well as of LiB₁₁H₁₄-based mixed-anion solid electrolytes are solved and high ionic conductivities of 1.1 × 10⁻⁴ S cm⁻¹ for Li₂(B₁₁H₁₄)(CB₁₁H₁₂) and 1.1 × 10⁻³ S cm⁻¹ for Li₃(B₁₁H₁₄)(CB₉H₁₀)₂ are obtained, respectively. LiB₁₁H₁₄ exhibits an oxidative stability limit of 2.6 V versus Li⁺/Li and the proposed decomposition products are discussed based on density functional theory calculations. Strategies are discussed to improve the stability of these compounds by modifying the chemical structure of the nido-hydroborate cage. Galvanostatic cycling in symmetric cells with two lithium metal electrodes shows a small overpotential increase from 22.5 to 30 mV after 620 h (up to 0.5 mAh cm⁻²), demonstrating that the electrolyte is compatible with metallic anodes. Finally, the Li₂(B₁₁H₁₄)(CB₁₁H₁₂)  electrolyte is employed in a proof-of-concept half cell with a TiS₂ cathode with a capacity retention of 82% after 150 cycles at C/5.     

Inhomogeneity of CoCrW powder products manufactured by SLM technology

Journal of Mechanical Science and Technology - The article deals with selective laser melting process using CoCrW powder. Our aim was to identify the influence of product position on the building...     

Hybrid laser-arc welding of advanced high-strength steel

This study investigated the synergetic effect between laser beam and electrical arc during hybrid welding by using a spectral diagnostic technique. The synergetic effect increased the energy density in the keyhole and deepened the weld penetration, resulting in a lower plasma electron temperature. The metal transfer mode was a globular one at a small offset distance while a spray mode was achieved with an increase in the offset distance. The decrease in the arc voltage and arc current due to the synergetic effect caused this transition from spray to globular modes. Globular transfer mode destabilized the molten pool and keyhole with the large droplet impingement, leading to the formation of porosity in the corresponding weld bead. The presence of porosity was on-line detected by identifying serious fluctuations in the Fe I electron temperature signals based on the fact that the instability of the molten pool and keyhole is strongly related to the signals coming from the plasma.     

Interaction of hIAPP with Model Raft Membranes and Pancreatic β‐Cells: Cytotoxicity of hIAPP Oligomers

Type II diabetes mellitus (T2DM) is associated with β‐cell failure, which correlates with the formation of pancreatic islet amyloid deposits. The human islet amyloid polypeptide (hIAPP) is the major component of islet amyloid and undergoes structural changes followed by self‐association and pathological tissue deposition during aggregation in T2DM. There is clear evidence that the aggregation process is accelerated in the presence of particular lipid membranes. Whereas hIAPP aggregation has been extensively studied in homogeneous model membrane systems, especially negatively charged lipid bilayers, information on the interaction of hIAPP with heterogeneous model raft membranes has been missing until now. In the present study, we focus on the principles of aggregation and amyloid formation of hIAPP in the presence of model raft membranes. Time‐lapse tapping mode AFM and confocal fluorescence microscopy experiments followed membrane permeabilization and localization of hIAPP in the raft membrane. Together with the ThT and WST‐1 assay, the data revealed elevated cytotoxicity of hIAPP oligomers on INS‐1E cells.     

Influence of Soft Cocoa Butter Equivalents on Color and Other Physical Attributes of Chocolate

The physical characteristics and color of chocolate depend on the physical properties and crystallization behavior of the fat phase. In this study, the fat phase of chocolate samples contains cocoa butter from Ghana and soft cocoa butter equivalent (CBE). The laboratory-made chocolate samples were tempered at three different precrystallization temperatures (25, 27 and 29 °C), using three different concentrations of CBE (3, 5 and 7%), calculated as percentage of the chocolate. Physical characteristics of chocolate, namely thermoreographic parameters and solid fat content (SFC), were measured. The color of the chocolate was determined instrumentally, before and after thermo-cycle testing at 32/20 °C. It was found that CBE changed the melting properties of chocolate produced with cocoa butter from Ghana, which is of moderate hardness. It was determined that the optimum precrystallization temperature for chocolate mass with addition of CBE in the given conditions of measurement was 27 °C, the temperature that resulted in the best fat bloom resistance.     

Source–receptor relationships for heavy metals in the European atmosphere

Atmospheric concentrations of heavy metals (HMs), in particular As, Cd, Cu, Pb and Zn, were studied in an effort to contribute to the understanding of European source-receptor relationships. A comparison was made between the ambient concentrations measured at 11 background aerosol monitoring stations (in Denmark, the Czech Republic, Finland, Norway and Sweden) and the corresponding HM concentrations estimated by the Heavy Metals Eulerian Transport (HMET) meteorological dispersion model. The collected samples were analysed with Particle Induced X-ray Emission analysis (PIXE) except the Finnish samples which were analysed with Inductively Coupled Plasma – Mass Spectrometry (ICP-MS). The available data covers the period 1985–1994. The comparison showed that the European emissions of As, Cd and Pb seem to be fairly well estimated. On the other hand, the European Zn emissions are underestimated by a factor of 3 or more, while the Cu emissions appear to be slightly overestimated. The HMET dispersion model also made it possible to select occasions for which the sampling sites had a substantial contribution of HM from the highly polluted “Black Triangle” region (on the borders between the Czech Republic, Poland and Germany). The time evolution of the sources of HMs within this source region could be studied by applying various statistical receptor models on the extensive data set from two Danish stations, Keldsnor and Tange, covering the period 1985–1994. Four source types were clearly discerned throughout the 10 year time period. These sources were: soil dust; sea spray; general combustion and oil combustion. The strong time-dependence observed for the contribution from the Black Triangle region emphasizes the importance of keeping the emission inventories continuously updated if HMs deposition calculations and HMs emissions reduction protocols are to be based on dispersion modelling approaches.     

Parametric study on a coaxial multi-material powder flow in laser-based powder deposition process

The manner with which the composite powder particles injected into the laser formed molten pool decides the deposition quality in a typical laser-based powder deposition of composite material. Since, the morphology and physical properties of nickel (Ni) and tungsten carbide (WC) are different their powder flow characteristics such as the powder particles stream structure, maximum concentration at the converging spot, and the powder particles velocity are noticeably different. In the current study, a computational fluid dynamics (CFD) based powder flow model is established to characterize the coaxial powder flow behavior of Ni–WC composite powders. The key powder flow characteristics such as the stand-off distance, the diameter of the powder stream at the stand-off distance, and the velocity of the powder particles are measured using three different vision based techniques. Both the numerical and experimental results reveal the exact stand-off distance where the substrate needs to be placed, the diameter of the concentration spot of powder at the stand-off distance, and a combination of suitable nozzle angle, diameter, and carrier gas flow rate to obtain a maximum powder concentration at the stand-off distance with a stable composite powder flow.     

Two-pass laser welding of galvanized high-strength dual-phase steel for a zero-gap lap joint configuration

A welding procedure based on using two-pass laser scans is introduced for joining overlapped galvanized high-strength steel sheets. The first pass is based on a defocused laser spot that scans across the top of the overlapped sheets and heats the zinc coating at the faying surface to be melted and vaporized, while the second pass is executed with a focused laser spot in order to perform the welding. Completely defect-free welds were obtained by using this two-pass laser welding procedure. An on-line machine vision system and a spectrometer were applied to analyze the stability of the laser welding process. An energy-dispersive X-ray spectroscopy (EDS) was carried out to determine the atomic percent of zinc and iron of the DP980 coupons. Mechanical testing was conducted to evaluate the mechanical properties of the welds. The experimental results show that the weld joints obtained by the two-pass laser welding approach have a higher failure value than those obtained by a single pass laser welding of galvanized steel with mechanically removed zinc at the faying surface under the same welding speed and laser power.     

The design and production of Ti-6Al-4V ELI customized dental implants

This paper addresses the production of customized Ti-6Al-4V ELI dental implants via electron beam melting (EBM). The melting of Ti-6Al-4V ELI powder produces implants with great biocompatibility, fi ne mechanical performance, and a high bone ingrowth potential. The EBM technology is used to produce one-component dental implants that mimic the exact shape of the patient’s tooth, replacing the traditional, three-component, “screw-like” standardized dental implants currently used. The new generation of implants provides the possibility of simplifying pre-insertion procedures leading to faster healing time, and the potential of better and stronger osseointegration, specifi cally through incorporating lattice structure design.     

Distribution of the carbide phase in the viscoplastic layer during the rotational friction-welding of various steels

The paper presents the viscoplastic phenomena observed during the rotational friction-welding process of high-speed steel M2 (AISI SAE) with carbon steel 1060 (AISI SAE). The structure, phase composition and distribution of the carbide phase in the friction plane and adjoining zones are examined by using optical microscopy (OM) with a system for quantitative analysis, and scanning electron microscopy (SEM) in addition to EDS analysis. The experimentally-checked mathematical relationship is suggested for the calculation of the radial movements of the carbide phase, immediately next to the friction plane. On the basis of qualitative and quantitative evaluation of the microstructural and rheological appearances, a model of carbide phase distribution is also established in the viscoplastic and viscous layers in the area of the friction plane.