Evaluation of humic acid photocatalytic degradation by UV–vis and fluorescence spectroscopy

Photodegradation of humic substances causes drastic changes in the UV–vis absorption and fluorescence properties of humic acids. In this study it is intended to fulfill the lack of knowledge about the spectral changes of humic acids during photocatalytic oxidation processes and elucidate the effects observed on the molecular size distribution of humic acid focusing on their analysis by UV–vis and fluorescence spectroscopy.

As confirmed by the spectroscopic evaluation of the molecular size distribution data, photocatalytic degradation of humic acid leads to the formation of lower molecular size (small fractions) and higher UV absorbing compounds. For fractions less than 10 kDa, UV₂₅₄ absorbing moieties in treated humic acid samples become higher than that of raw humic acid designating the generation of new species during photocatalysis. UV–vis spectroscopic changes were also evaluated by the parameters relating to the concomitant removal of the total organic carbon as well as by the ratios using absorption values at discrete wavelengths. Moreover, the fluorescence spectra of treated humic acid samples show decreasing intensity profiles with increasing photocatalytic irradiation time.     

Repeated thermo-hydrolytic disintegration of medium density fibreboards (MDF) for the production of new MDF

European Journal of Wood and Wood Products - Medium density fibreboards (MDF) are currently not recycled after service life, but various publications report on recycling by the disintegration of...     

Thermodynamic analysis of the interaction between 3-aminophenylboronic acid and monosaccharides for development of biosensor

The special interaction between 3-aminophenylboronic acid and monosaccharides, particularly glucose, fructose and galactose, has been investigated and used for the development of electrochemical and surface plasmon resonance (SPR) based saccharide sensors. The binding constants and thermodynamic parameters of interaction such as free energy of binding (ΔG), enthalpy (ΔH) and entropy (ΔS) were determined for the first time using isothermal titration calorimetry revealed the enthalpic and entropic contributions to the free energies of binding. Effects of pH and buffer on the binding constants (k) between 3-aminophenylboronic acid and monosaccharides were also examined. The binding constant of fructose was found to be six times higher than glucose and four times higher than galactose at pH 11, leading the specific detection of fructose. SPR and potentiometric calibration for fructose were linear in the concentration range of 10–120 mM and 8–84 mM, respectively. Limit of detection of the SPR and potentiometric method were found to be as 8.9 mM and 1.4 mM, respectively.     

Statistical Modeling of β-galactosidase Inhibition During Lactose Hydrolysis

A statistical model approach called response surface methodology was used to describe the product and substrate inhibition effect on β-galactosidase enzyme during lactose hydrolysis. The effect of independent variables, namely the initial concentrations of lactose (73 - 146 mM), galactose (44 - 122 mM) and glucose (83 - 167 mM) on the reaction rate of β-galactosidase was evaluated. The enzymatic reaction rate was influenced by both combined and individual effects of all the substrate and products. Although, glucose acted as an activator at low lactose and low galactose concentrations, glucose caused the inhibition of β-galactosidase at higher concentrations of lactose and galactose. The effect of galactose concentration on β-galactosidase enzyme was in the direction of inhibition. At low lactose concentrations and high glucose concentrations, galactose concentration became more effective on the reaction rate.     

An investigation of free vibrations of a strain gradient Timoshenko beams with the method of initial values

Investigated herein is the free vibrations of beams based on the strain gradient Timoshenko beam theory with the method of initial values. For the vibration of strain-gradient Timoshenko beam (SGTB), the sixth-order ordinary differential equation and three boundary conditions at each end have been obtained by using the Hamilton principle. The effect of the characteristic length on the frequencies of free vibrations is shown. The frequencies of the SGTB are compared to the frequencies of the strain gradient Euler beam (SGEB), classical Timoshenko beam (CTB) and classical Euler beam (CEB). It has been observed that the high-frequency values of conventional and strain-gradient beams are very different. This result can be used to determine the value of the material characteristic length for a nanobeam for which lengthscale effects are believed to be dominant.

     

NaOH modified P(acrylamide) hydrogel matrices for in situ metal nanoparticles preparation and their use in H2 generation from hydrolysis of NaBH4

Crosslinked poly(acrylamide) (p(AAm)) as neutral hydrogel is synthesized via photo polymerization technique, and the amide groups within p(AAm) matrices are converted to strongly ionizable carboxylic acids groups via facile modification route by simple treatment of NaOH to obtained NaOH‐p(AAm) hydrogels. Because of the highly ionizable nature of carboxylate groups within mod‐p(AAm), the swelling and metal ion absorbing capacities are increased tremendously, almost 40 and 7.5 folds, respectively. The Co(II) and Ni(II) metal ions are loaded into NaOH‐p(AAm) hydrogels, and are treated with NaBH₄ to form corresponding metal nanoparticles in situ within mod‐p(AAm) matrices, and used in H₂ generation production from hydrolysis of NaBH₄. Various parameters such as functionality of polymeric matrices, the kinds and the amount of metal nanoparticles, and the temperature effecting the H₂ generation are investigated. Comparable low E_a with the similar researches in the literature, E_a = 20.07 ± 0.05 kJ mol^?1 is obtained in NaBH₄ hydrolysis catalyzed by NaOH‐p(AAM)‐Co composite system. © 2014 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2014 , 131, 41106.     

Scheduling image processing tasks in a multilayer system

Multilayer multiprocessor systems are generally employed in real-time applications such as robotics and computer vision. This paper introduces three heuristic algorithms for multiprocessor task scheduling in such systems. In our model, tasks with arbitrary processing times and arbitrary processor requirements are considered. The scheduling aims at minimising completion time of processes in a two-layer system. We employed an effective lower bound (LB) for the problem. Then, we analysed the average performance of the heuristic algorithms by computing the average percentage deviation of each heuristic solution from the LB on a set of randomly generated problems. We have also applied these algorithms for scheduling computer vision tasks running on prototype multilayer architecture. Our computational and empirical results showed that the proposed heuristic algorithms perform well.     

Hybrid Adaptive Large Neighborhood Search for the Optimal Statistic Median Problem

In this paper, the problem of maximizing the median of a convex combination of vectors having important applications in finance is considered. The objective function is a highly nonlinear, nondifferentiable function with many local minima and the problem was shown to be APX hard. We present two hybrid Large Neighborhood Search algorithms that are based on mixed-integer programs and include a time limit for their running times. We have tested the algorithms on three testbeds and showed their superiority compared to other state-of-the-art heuristics for the considered problem. Furthermore, we achieved a significant reduction in running time for large instances compared to solving it exactly while retaining high quality of the solutions returned.