湿法回收钒高氨氮废水处理工程实例

湿法提钒回收处理过程中的废水具有高硬度、高含盐、高氨氮等特征,采用预处理+负压亚沸碱析脱氨及微负压氨回收工艺,可使出水水质稳定氨氮达到15 mg/L以下,同时超级吸氨器以及两级氨水吸收罐可制得浓度为18％～25％的氨水作为产品,降低项目整体运行费用.     

In situ Raman spectroscopic study towards the growth and excellent HER catalysis of Ni/Ni(OH)2 heterostructure

The electrochemical water splitting to produce H₂ in high efficiency with earth-abundant-metal catalysts remains a challenge. Here, we describe a simple “cyclic voltammetry + ageing” protocol at room temperature to activate Ni electrode (AC-Ni/NF) for hydrogen evolution reaction (HER), by which Ni/Ni(OH)₂ heterostructure is formed at the surface. In situ Raman spectroscopy reveals the gradual growth of Ni/Ni(OH)₂ heterostructure during the first 30 min of the aging treatment and combined with polarization measurements, it suggests a positive relation between the Ni/Ni(OH)₂ amount and HER performance of the electrode. The obtained AC-Ni/NF catalyst, with plentiful Ni–Ni(OH)₂ interfaces, exhibits remarkable performance towards HER, with the low overpotential of only 30 mV at a H₂-evolving current density of 10 mA/cm² and 153 mV at 100 mA/cm², as well as a small Tafel slope of 46.8 mV/dec in 1 M KOH electrolyte at ambient temperature. The excellent HER performance of the AC-Ni/NF could be maintained for at least 24 h without obvious decay. Ex situ experiments and in situ electrochemical-Raman spectroscopy along with density functional theory (DFT) calculations reveal that Ni/Ni(OH)₂ heterostructure, although partially reduced, can still persist during HER catalysis and it is the Ni–Ni(OH)₂ interface reducing the energy barrier of H1 adsorption thus promoting the HER performance.     

全过程集成管理服务在西安地铁5号线二期工程的应用

近年来,我国不断推动房地产和市政工程建设实施全过程工程咨询管理,即全过程集成管理服务.西咸轨道投资建设公司成立时间短、人员少,却仅用了一年零三个月的时间,完成了西安地铁5号线二期车站设备系统的工程建设任务,这得益于全过程集成管理模式的应用.     

Evolution of Local Structural Ordering and Chemical Distribution upon Delithiation of a Rock Salt–Structured Li1.3Ta0.3Mn0.4O2 Cathode

Lithium‐rich disordered rock‐salt oxides have attracted great interest owing to their promising performance as Li‐ion battery cathodes. While experimental and theoretical efforts are critical in advancing this class of materials, a fundamental understanding of key property changes upon Li extraction is largely missing. In the present study, single‐crystal synthesis of a new disordered rock‐salt cathode material, Li_1.3Ta_0.3Mn_0.4O₂ (LTMO), and its use as a model compound to investigate Li concentration–driven evolution of local cationic ordering, charge compensation, and chemical distribution are reported. Through the combined use of 2D and 3D X‐ray nanotomography, it is shown that Li removal accompanied by oxygen oxidation is correlated with the development of morphological defects such as particle cracking. Chemical heterogeneity, quantified by subparticle level distribution of Mn valence state, is minimal during Mn redox, which drastically increases upon the formation of cracks during oxygen redox. Density functional theory and bond valence sum mismatch calculations reveal the presence of local short‐range ordering in the pristine oxide, which gradually disappears along with the extraction of Li. The study suggests that with cycling the transformation into true cation–disordered state can be expected, which likely impacts the voltage profile and obtainable energy density of the oxide cathodes.     

Hierarchical Attention for Part-Aware Face Detection

International Journal of Computer Vision - Expressive representations for characterizing face appearances are essential for accurate face detection. Due to different poses, scales, illumination,...     

沿空切顶成巷段巷道围岩变形规律研究

以宏景塔一矿回采工作面为研究对象,基于切顶卸压无煤柱自动成巷技术原理,采用数值模拟计算和现场实测的方法,对该矿成巷段巷道围岩支承压力分布及围岩变形规律进行分析。研究结果表明:随着工作面向前推进,巷道围岩支承压力呈先增大后减小最后趋于稳定的变化趋势,支承压力稳定值为13.5 MPa;受工作面回采动压的影响,距离工作面70 m以内,锚索受力急剧增大到恒阻值、巷道围岩变形明显;距离工作面70~150 m,锚索受力迅速减小、巷道围岩变形逐渐变缓;在距离工作面150 m之后,锚索受力仅有微量变化、巷道围岩变形趋于稳定。因此确定支护体回撤保守安全位置为工作面后方150 m。工程实践表明:所设支护体回撤距离能够应对巷道围岩变形,成巷效果良好。     

基于DoG检测图像特征点的快速二进制描述子

针对SIFT描述子实时性差和传统二进制描述子对尺度、旋转和视角变化鲁棒性差的问题,本文通过优化采样模式和添加灰度差分不变量比较测试进行改进,提出了一种鲁棒性更高的二进制描述子。首先,设计了一种尺度关联、编号标记的采样模式;然后,旋转采样模式中各采样点到特定位置,确保描述子尺度、旋转不变性;接着,分析了采样点点对模式对描述子的影响,选择使用机器学习训练后的128对采样点对;最后,选择灰度值比较测试及梯度绝对值和比较测试构建二进制描述子。实验中采用DoG检测图像关键点,结果表明:本文提出的描述子在描述子构建和描述子匹配上比SIFT描述子分别快84%和67%;在有视角变化的图像匹配上,准确率比传统的二进制描述子高3%~5%,召回率平均要高30%以上。本文提出的特征点描述方法适用于时间要求高的图像匹配领域。     

六盘水市煤炭行业竞争战略分析

我国是富煤贫油少气的国家，煤炭是我国最重要的一次能源。但从能源激烈的竞争市场环境而言，当前我国煤炭行业发展出现了困境。为了更好地发展六盘水地区的煤炭行业，结合竞争战略理论和六盘水市的煤炭行业发展状况，运用PEST分析法和波特五力模型对六盘水市煤炭行业进行分析，得出整合资源，结合自身优势大力吸引人才，最终达到产业转型的生态化煤炭发展战略模型。分析结果可为提高六盘水煤炭行业竞争力提供理论支持。