全文获取类型
收费全文 | 66625篇 |
免费 | 1917篇 |
国内免费 | 4374篇 |
专业分类
电工技术 | 3252篇 |
技术理论 | 1篇 |
综合类 | 1951篇 |
化学工业 | 7006篇 |
金属工艺 | 7261篇 |
机械仪表 | 3126篇 |
建筑科学 | 3292篇 |
矿业工程 | 7294篇 |
能源动力 | 1239篇 |
轻工业 | 7434篇 |
水利工程 | 3107篇 |
石油天然气 | 4460篇 |
武器工业 | 883篇 |
无线电 | 7652篇 |
一般工业技术 | 4156篇 |
冶金工业 | 3457篇 |
原子能技术 | 2013篇 |
自动化技术 | 5332篇 |
出版年
2022年 | 607篇 |
2021年 | 627篇 |
2020年 | 456篇 |
2019年 | 620篇 |
2018年 | 676篇 |
2016年 | 580篇 |
2015年 | 761篇 |
2014年 | 1669篇 |
2013年 | 1276篇 |
2012年 | 1276篇 |
2011年 | 1443篇 |
2010年 | 1305篇 |
2009年 | 1409篇 |
2008年 | 1494篇 |
2007年 | 1617篇 |
2006年 | 1749篇 |
2005年 | 2014篇 |
2004年 | 2098篇 |
2003年 | 1740篇 |
2002年 | 1916篇 |
2001年 | 2185篇 |
2000年 | 1594篇 |
1999年 | 1445篇 |
1998年 | 1189篇 |
1997年 | 1068篇 |
1996年 | 1265篇 |
1995年 | 1244篇 |
1994年 | 1147篇 |
1993年 | 1162篇 |
1992年 | 1464篇 |
1991年 | 1424篇 |
1990年 | 1806篇 |
1989年 | 1585篇 |
1988年 | 2277篇 |
1987年 | 2767篇 |
1986年 | 2280篇 |
1985年 | 2615篇 |
1984年 | 2352篇 |
1983年 | 2153篇 |
1982年 | 2378篇 |
1981年 | 2026篇 |
1980年 | 1584篇 |
1979年 | 940篇 |
1978年 | 592篇 |
1975年 | 436篇 |
1974年 | 433篇 |
1966年 | 439篇 |
1965年 | 641篇 |
1964年 | 633篇 |
1956年 | 508篇 |
排序方式: 共有10000条查询结果,搜索用时 275 毫秒
1.
传统网络性能预测技术存在网络状态获取不够全面及网络性能评估准确性欠佳等问题,利用图神经网络学习推理网络关系数据的特点,结合捕获的网络全局信息,提出了一种基于图神经网络的网络性能智能预测方法。通过网络系统抽象及网络性能建模,将复杂的网络信息转化为形式化的图数据进行描述,利用图空域卷积处理图网络节点的消息传递过程,实现网络信息之间的关系推理,研究了实现网络性能预测的图神经网络模型,提出了一种能处理流量矩阵、网络拓扑、路由策略、节点配置的图神经网络体系结构,最后通过实验论证了模型能更好地实现包括时延、抖动和丢包率的网络性能的准确预测。 相似文献
2.
At present, the development and implementation of digital transformation are the keys to promoting high-quality industry development. The new digital fabrication method of robotic 3D printing is a research area being studied by many to tackle the issue of the declining productivity of traditional construction methods. Although many studies have been done, most of the current 3D printing projects are facing limitations in terms of scale. In order to bridge the gap, this article proposed a mass customization 3D printing framework system for large-scale projects. This article discusses how mass customization is made possible through the joint operation of the FUROBOT software and 3D printing hardware. By taking the east gate of Nanjing Happy Valley Plaza as a case study, the article demonstrates and studies the feasibility of the large-scale mass customization 3D printing framework system. 相似文献
4.
岩堆是发育在山坡坡脚或平缓山坡上的松散堆积体,属于典型的不良地质现象,直接威胁着当地人民的生命财产安全。本文以澜沧江右岸某在建公路桥梁处岩堆体为例,从岩堆的几何形态、物质组成、形成条件等方面对岩堆的发育特征及成因机制进行了分析。研究结果表明该岩堆为一古岩堆,其成因机理为坡脚软岩遭受河流侵蚀冲刷、上覆硬岩拉裂崩塌所致。岩堆区上覆盖层主要由松散崩坡积物构成,具有分布范围广、厚度大、边界条件复杂的特点。本文的研究结果能够有力指导相关公路桥梁墩台设计,在实际工程建设中具有重要意义。 相似文献
5.
6.
压水堆核电厂启动过程中,次级中子源为堆外源量程探测器提供本底计数率,避免测量盲区,确保反应堆安全启动。但次级中子源的引入会为核电厂带来较大的经济和环境负担,同时也需承受次级中子源破损等带来的风险。为此,可使用受辐照燃料组件的自发裂变中子源进行替代,即无源启动方式。通过研究堆外源量程探测器计数率的理论计算方法,并基于运行电厂测量数据进行分析验证,为源量程探测器计数率的理论预估提供了较为完善的理论方法流程。本文结果可为无源启动源量程探测器计数率分析提供支持,同时也可用于次级中子源装载量或布置位置的优化分析等。 相似文献
7.
Mohamed A.El-Nemr Ibrahim M.A.Ismail Nabil M.Abdelmonem Ahmed El Nemr Safaa Ragab 《中国化学工程学报》2021,36(8):199-222
Watermelon peel residues were used to produce a new biochar by dehydration method. The new biochar has undergone two methods of chemical modification and the effect of this chemical modification on its ability to adsorb Cr(VI) ions from aqueous solution has been investigated. Three biochars, Melon-B, Melon-BO-NH_2 and Melon-BO-TETA, were made from watermelon peel via dehydration with 50% sulfuric acid to give Melon-B followed by oxidation with ozone and amination using ammonium hydroxide to give Melon-BO-NH_2 or Triethylenetetramine(TETA) to give Melon-BO-TETA. The prepared biochars were characterized by BET, BJH,SEM, FT-IR, TGA, DSC and EDAX analyses. The highest removal percentage of Cr(VI) ions was 69% for Melon-B,98% for Melon-BO-NH_2 and 99% for Melon-BO-TETA biochars of 100 mg·L~(-1) Cr(VI) ions initial concentration and 1.0 g·L~(-1) adsorbents dose. The unmodified biochar(Melon-B) and modified biochars(Melon-BO-NH_2 and Melon-BO-TETA) had maximum adsorption capacities(Qm) of 72.46, 123.46, and 333.33 mg·g~(-1), respectively.The amination of biochar reduced the pore size of modified biochar, whereas the surface area was enhanced.The obtained data of isotherm models were tested using different error function equations. The Freundlich,Tempkin and Langmuir isotherm models were best fitted to the experimental data of Melon-B, Melon-BO-NH_2 and Melon-BO-TETA, respectively. The adsorption rate was primarily controlled by pseudo-second–order rate model. Conclusively, the functional groups interactions are important for adsorption mechanisms and expected to control the adsorption process. The adsorption for the Melon-B, Melon-BO-NH_2 and Melon-BO-TETA could be explained for acid–base interaction and hydrogen bonding interaction. 相似文献
8.
9.
Daniel T. Payne Mandeep K. Chahal V clav B&rcaron ezina Whitney A. Webre Katsuhiko Ariga Francis D Souza Jan Labuta Jonathan P. Hill 《Frontiers of Chemical Science and Engineering》2020,14(1):28
Chiral 1,1’-binaphthyl-linked diporphyrin ‘tweezers’ (R)-1/(S)-1 and the corresponding zinc(II) complexes (R)-2/(S)-2 were prepared as chiral host molecules, and their utility for chiral analyses (especially enantiomeric excess (ee) determinations) were evaluated. Tris(1-n-dodecyl)porphyrins were used for the first time as the interacting units. Host capabilities of the diporphyrin tweezers were investigated by titrations with (R,R)- and (S,S)-cyclohexane-1,2-diamine (CHDA). The host molecules could be used as multichannel probes of ee by using UV-vis, circular dichroism (CD), fluorescence emission and 1H nuclear magnetic resonance (1H-NMR) methods. Chiral configurations could also be differentiated using CD or 1H-NMR spectroscopy. All three optical techniques give good resolution of ee with reasonable sensitivity considering the low concentrations used (ca. 10−6 mol·L−1). The ee determination of CHDA enantiomers using NMR spectroscopy is also possible because of the reasonably well separated resonances in the case of (R,R)- and (S,S)-CHDA. Non-metallated (R)-1/(S)-1 hosts could not be used to detect chiral information in a strongly acidic chiral guest. This work demonstrates the utility of 1,1’-binapthyl-linked chiral hosts for chiral analysis of ditopically interacting enantiomers. 相似文献
10.
Pablo Salcedo-Abraira Sergio M.F.Vilela Artem A.Babaryk Maria Cabrero-Antonino Pedro Gregorio Fabrice Salles Sergio Navalon Hermenegildo Garcia Patricia Horcajada 《Nano Research》2021,14(2):450-457
A novel microporous two-dimensional(2D)Ni-based phosphonate metal-organic framework(MOF;denoted as IEF-13)has been successfully synthesized by a simple and green hydrothermal method and fully characterized using a combination of experimental and computational techniques.Structure resolution by single-crystal X-ray diffraction reveals that IEF-13 crystallizes in the triclinic space group Pi having bi-octahedra nickel nodes and a photo/electroactive tritopic phosphonate ligand.Remarkably,this material exhibits coordinatively unsaturated nickel(II)sites,free-P03H2and-P03H acidic groups,a C02accessible microporosity,and an exceptional thermal and chemical stability.Further,its in-deep optoelectronic characterization evidences a photoresponse suitable for photocatalysis.In this sense,the photocatalytic activity for challenging H2generation and overall water splitting in absence of any co-catalyst using UV-Vis irradiation and simulated sunlight has been evaluated,constituting the first report for a phosphonate-MOF photocatalyst.IEF-13 is able to produce up to 2,200 fimol of H2per gram using methanol as sacrificial agent,exhibiting stability,maintaining its crystal structure and allowing its recycling.Even more,170μmol of H2per gram were produced using IEF-13 as photocatalyst in the absence of any co-catalyst for the overall water splitting,being this reaction limited by the 02reduction.The present work opens new avenues for further optimization of the photocatalytic activity in this type of multifunctional materials. 相似文献