排序方式: 共有38条查询结果,搜索用时 176 毫秒
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Ca3Y2(Si3O9)2:Tb3+绿色荧光粉的光谱特性 总被引:1,自引:1,他引:0
采用高温固相法制备了Ca3Y2(Si3O9)2: Tb3+绿色荧光粉,研究了材料的光学性能。X 射线衍射(XRD)结果显示,掺杂少量的Tb3+,并未影响Ca3Y2(Si3O9)2材料 的晶相结构。Ca3Y2(Si3O9)2:Tb3+ 荧光粉的激发光谱由较强的4f75d1宽带吸收(200~300 nm )和较弱的4f-4f电子跃迁吸收 (300~500 nm)构成,主激发峰位于236nm。取波长分别为236、376和482nm的光 作为激发源时,发现样品的主发射峰均位于544 nm,对应Tb3+的5D 4→7F5跃迁发射。以236nm 紫外光作为激发源,监测544nm主发射峰,随Tb3+浓度 的增大,Ca3Y2(Si 3O9)2:Tb3+的荧光寿命逐渐减小,但在实验范围内并未出现浓度猝灭现象。 相似文献
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Er3+/Ce3+co-doped tellurite-based glasses with composition of TeO 2-Zn O-Na2O are prepared by high-temperature melt-quenching technique.Effects of Ce2O3 content on the 1.53μm band fluorescence spectra and fluorescence lifetime of Er3+are measured and investigated.It is found that the tellurite glass containing Ce2O3 with molar concentration of 0.25%exhibits an increment of 13%in 1.53μm fluorescence intensity and an increment of 15%in the 4I13/2 level lifetime.The results indicate that the prepared tellurite-based glass with a suitable Er3+/Ce3+codoping concentration is an excellent gain medium applied for broadband Er3+-doped fiber amplifier(EDFA)pumped with a980 nm laser diode. 相似文献
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采用高温固相法制备了(Ba/Sr/Ca)2.9Ce(PO4)3:0.1Eu2+系列荧光粉,研究了材料的发光特性。在400 nm光激发下,增大x值,Ba2.9-xSrxCe(PO4)3:0.1Eu2+的主发射峰由515 nm红移至540 nm,色坐标从(0.312,0.607)变到(0.376,0.580);随着y值的增大,Ba2.9-yCayCe(PO4)3:0.1Eu2+的主发射峰由515 nm红移到553 nm,色坐标从(0.312,0.607)变到(0.427,0.535),随z值的增大,Sr2.9-zCazCe(PO4)3:0.1Eu2+的主发射峰值由540 nm红移... 相似文献
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Eu2+在KNaCa2(PO4)2中的发光及晶体学格位 总被引:2,自引:0,他引:2
采用高温固相法制备了KNaCa2(PO4)2:Eu2+蓝色荧光粉,并研究了材料的发光特性.在400 nm近紫外光激发下,材料呈非对称的单峰发射,主峰位于470 nm.监测470 nm发射峰,对应的激发光谱覆盖200~450 nm,主峰位于400 nm,说明材料能够很好的吸收紫外?近紫外光,发射蓝色光.利用van Uitert公式计算了Eu2+取代KNaCa2(PO4)2中Ca2+时所占晶体学格位,得出461和502 nm发射分别归属于八配位和六配位的Eu2+发射.研究了Eu2+掺杂浓度对KNaCa2(PO4)2:Eu2+材料发射强度的影响,结果显示Eu2+的最佳掺杂浓度为1mol%,利用Dexter理论得出其浓度猝灭机理为电偶极?电偶极相互作用. 相似文献
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用于白光LED的Ca2BO3Cl:Eu2+发光特性研究 总被引:2,自引:2,他引:0
采用高温固相法,制备了适于紫外-近紫外及蓝光激发,主峰位于573nm的Ca2BO3Cl:Eu2+黄色荧光粉。研究了Ce3+以及CaCl2和H3BO3用量对材料发光特性等的影响。结果表明,添加Ce3+,明显增强了Ca2BO3Cl:Eu2+材料在紫外-近紫外区的吸收,有效地提高了材料的发射强度;添加过量的CaCl2或H3BO3,均能提高Ca2BO3Cl:Eu2+材料的发射强度,最佳的CaCl2和H3BO3用量分别为过量5mol%和15mol%。将Ca2BO3Cl:Eu2+材料与460nm InGaN芯片组合,获得了白光发射,色坐标为(0.339,0.351)。 相似文献
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Ba3Tb(BO3)3:Eu3+的制备与发光性质 总被引:2,自引:1,他引:1
采用高温固相法合成了Ba3Tb(BO3)3:Eu3+红色荧光粉,并研究了Ba3Tb(BO3)3:Eu3+的发光特性。Ba3Tb(BO3)3:Eu3+的激发光谱包含250nm~330nm和350nm~400nm的2个宽带,最大峰值位于383nm,可以被紫外-近紫外发光二极管(light-emitting diodes,LED)有效激发。Ba3Tb(BO3)3:Eu3+的发射谱显示出4组发射峰,其主发射峰位于620nm,对应Eu3+的5D0→7F2跃迁;Eu3+掺杂摩尔分数为2%时,Ba3Tb(BO3)3:Eu3+发光亮度最高。经分析发现Ba3Tb(BO3)3:Eu3+存在Tb3+→Eu3+的能量传递。 相似文献
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The Ba3Y2(BO3)4:Eu^3+ phosphor was synthesized using a high temperature solid-state reaction method and the luminescent characteristics were investigated. The emission spectrum exhibited one strong red emission at 613 nm, corresponding to the electric dipole 5D0-TF2 transition of Eu^3+, under 365 nm excitation. The excitation spectrum of 613 nm indicated that the Ba3Y2(BO3)n:Eu^3+ phosphor was effectively excited by ultraviolet (UV) (254, 365 and 400 nm) and blue (470 nm) light. The effect of Eu^3+ concentration on the 613 nm emission of the Ba3Y2(BO3)n:Eu^3+ phosphor was measured. The results showed that the emission intensity increased with increasing Eu^3+ concentration, and then decreased. The CIE color coordinates of Ba3Y2(BO3)4:Eu^3+ phosphor were x=0.641 and y=0.359 at 15 mol.% Eu^3+. 相似文献