Effect of apple cider vinegar agent on the microstructure,phase evolution,and magnetic properties of CoFe2O4 magnetic nanoparticles

In the present study, spinel structure CoFe₂O₄ nanoparticles were successfully synthesized by the sol-gel auto-combustion technique. The effect of apple cider vinegar (ACV) addition as an organic biocompatible agent on the size, morphology, and magnetic properties of CoFe₂O₄ nanoparticles was investigated in detail. The phase evolution, particle size, and lattice parameter changes of the synthesized phase have been estimated by using Rietveld structure refinement analysis of X-ray powder diffraction data. Also, Fourier transform infrared spectra (FT-IR) of the samples verified the presence of two expected bands correspond to tetrahedral and octahedral metal-oxygen complexes within the spinel structure. Furthermore, microstructural observations revealed that ultrafine particles have a semi-spherical morphology. It was shown that the particles size decreased from ~45 to ~17 nm with an increase in the amount of ACV. Magnetic properties were carried out by vibrating sample magnetometer (VSM) at room temperature. Both the saturation magnetization (M_s) and coercivity (H_c) were found to be significantly dependent on the crystallite size and the amount of ACV.     

Type II robotic assembly line balancing problem: An evolution strategies algorithm for a multi-objective model

In this paper a different type II robotic assembly line balancing problem (RALB-II) is considered. One of the two main differences with the existing literature is objective function which is a multi-objective one. The aim is to minimize the cycle time, robot setup costs and robot costs. The second difference is on the procedure proposed to solve the problem. In addition, a new mixed-integer linear programming model is developed. Since the problem is NP-hard, three versions of multi-objective evolution strategies (MOES) are employed. Numerical results show that the proposed hybrid MOES is more efficient.     

Use of FIB to Study ZDDP Tribofilms

Focussed ion beam milling (FIB) followed by TEM has been used to study ZDDP tribofilms on rubbed steel surfaces. It has been found that the impact of high energy platinum and gallium ions during FIB causes significant morphological and structural changes to the uppermost 30–50 nm of a ZDDP tribofilm. This can be prevented by the low energy deposition of a quite thick gold layer prior to installation of the sample in the FIB facility. This problem, and its solution, have been quite widely reported in the non-tribology literature but have not previously been highlighted in the application of FIB to study tribological surfaces. It has also been found, using this gold pre-deposition method, that the bulk of the ZDDP tribofilm studied has a polycrystalline structure.     

Morphological aspects of competitive grain growth during directional solidification of a nickel-base superalloy, CMSX4

Quenched directional solidification of specially oriented bi-crystals of the Ni-base superalloy CMSX4, was carried out in an attempt to understand the role of the dendritic morphology in the process of competitive grain growth. For the range of misorientations considered (primary 001 misoriented by up to 7° from the uniaxial thermal gradient), there was no evidence of overgrowth of the primary misoriented dendrite by the secondary arms on the leading aligned primary. In fact, it was observed that for this range of misorientations, the tip of the retarded primary suppresses the growth of secondaries on its leading neighbour. This subsequently simply restricts the growth of the mis-aligned crystal to its original boundary, rather than reducing its size and is suggested as a possible reason for the range of stable axial orientations encountered during directional solidification of CMSX4.     

A more accurate one-dimensional analysis and design of irregular LDPC codes

We introduce a new one-dimensional (1-D) analysis of low-density parity-check (LDPC) codes on additive white Gaussian noise channels which is significantly more accurate than similar 1-D methods. Our method assumes a Gaussian distribution in message-passing decoding only for messages from variable nodes to check nodes. Compared to existing work, which makes a Gaussian assumption both for messages from check nodes and from variable nodes, our method offers a significantly more accurate estimate of convergence behavior and threshold of convergence. Similar to previous work, the problem of designing irregular LDPC codes reduces to a linear programming problem. However, our method allows irregular code design in a wider range of rates without any limit on the maximum variable-node degree. We use our method to design irregular LDPC codes with rates greater than 1/4 that perform within a few hundredths of a decibel from the Shannon limit. The designed codes perform almost as well as codes designed by density evolution.     

A novel approach for optimal chiller loading using particle swarm optimization

This study employs two new methods to solve optimal chiller loading (OCL) problem. These methods are continuous genetic algorithm (GA) and particle swarm optimization (PSO). Because of continuous nature of variables in OCL problem, continuous GA and PSO easily overcome deficiencies in other conventional optimization methods. Partial load ratio (PLR) of the chiller is chosen as the variable to be optimized and consumption power of the chiller is considered as fitness function. Both of these methods find the optimal solution while the equality constraint is exactly satisfied. Some of the major advantages of proposed approaches over other conventional methods can be mentioned as fast convergence, escaping from getting into local optima, simple implementation as well as independency of the solution from the problem. Abilities of proposed methods are examined with reference to an example system. To demonstrate these abilities, results are compared with binary genetic algorithm method. The proposed approaches can be perfectly applied to air-conditioning systems.     

Synthesis and photocatalytic activity of WO(3) nanoparticles prepared by the arc discharge method in deionized water

In this paper, we discuss the synthesis and characterization of tungsten trioxide nanoparticles prepared by the arc discharge method in deionized (DI) water. The size and morphology of WO(3) nanoparticles prepared using different arc currents (25, 35 and 45?A) were studied. Dynamic light scattering (DLS) and scanning electron microscopy (SEM) results indicate that at an arc current of 25?A, the size of the particles is about 30?nm, and this increases to 64?nm by increasing the arc current. This size increase caused a decrease of optical band gap from 2.9 to 2.6?eV. X-ray diffraction (XRD) and x-ray photoelectron spectroscopy (XPS) spectra demonstrate the formation of the WO(3) phase. Photodegradation of Rhodamine B shows that samples prepared at the lowest current have more photocatalytic activity due to having the smallest particle size and highest surface area. The results demonstrate the ability of the arc discharge method for direct formation of WO(3) nanoparticles in DI?water medium.     

Corrosion Behavior and Microhardness of Ni-P-SiO<Subscript>2</Subscript>-Al<Subscript>2</Subscript>O<Subscript>3</Subscript> Nano-composite Coatings on Magnesium Alloy

In the present work, nano-composites of Ni-P-SiO₂-Al₂O₃ were coated on AZ91HP magnesium alloy. The surface morphology of the nano-composite coating was studied by field emission scanning electron microscopy (FESEM). The amount of SiO₂ in the coating was determined by energy-dispersive analysis of x-ray (EDX), and the crystalline structure of the coating was examined by x-ray diffractometer (XRD). All the experiments concerning the corrosion behavior of the coating carried out in 3.5 wt.% NaCl solution and evaluated by electrochemical impedance spectroscopy (EIS) and polarization technique. The results showed that an incorporation of SiO₂ and Al₂O₃ in Ni-P coating at the SiO₂ concentration of 10 g/Land 14 g/LAl₂O₃ led to the lowest corrosion rate (i _corr = 1.3 µA/cm²), the most positive E _corr and maximum microhardness (496 VH). Furthermore, Ni-P-SiO₂-Al₂O₃ nano-composite coating possesses less porosity than that in Ni-P coating, resulting in improving corrosion resistance.     

Detecting sybil attacks in vehicular ad hoc networks using fuzzy logic and arithmetic optimization algorithm

The Journal of Supercomputing - In vehicular ad hoc networks (VANETs), Sybil attacks are serious security problems that can seriously affect the operations of the VANETs by producing fake...     

Ball-and-finger system: modeling and optimal trajectories

A rigid-body model of a finger interacting with a trackball is considered. The proposed system is a suitable candidate for studying trajectory generation when interaction plays an important role, such as in assembly and manipulation tasks. The mathematical model consists of a ball with a spherical joint constraint, a finger with three degrees of freedom, and the Coulomb friction model. From first principles, we derive a hybrid, high-index differential-algebraic equation for modeling the system dynamics, which is used for both simulation and finding optimal trajectories. For this problem, task planning, path planning, and trajectory generation are strongly interrelated, which makes using an integrated approach to trajectory generation inevitable. Moreover, the trajectory generation algorithm has to handle a number of important features, e.g., unilateral and non-holonomic constraints.