Effect of gamma irradiation on the optical properties of CR-39 polymer

The UV-Visible absorption spectra of virgin and gamma irradiated (20–800 kGy) CR-39 polymer have been deduced by using Shimadzu Double beam Double Monochromator UV-Visible Spectrophotometer (UV-2550). The existence of the peaks, their shifting and broadening as a result of gamma irradiation has been discussed. Finally the indirect and direct band gap in virgin and gamma irradiated CR-39 has been determined. The values of indirect band gap have been found to be lower than the corresponding values of direct band gap.     

Geometry Dependence of Magnetization Reversal in Nanocomposite Alloys

The geometrical optimization of aligned hard-soft permanent-magnet nanocomposites is investigated by model calculations. Considered criteria are the shapes of the soft and c-axis-aligned hard phases, the packing fraction of the soft phase, and magnetostatic interactions. Taking into account that the energy product is enhanced via the volume fraction of the soft phase, subject to maintaining coercivity, we find that the best structures are soft-magnetic cubes as well as long rods with a square cross section. Comparing embedded soft cubes with embedded soft spheres of the same size, our nucleation-field analysis shows that the volume fraction of the soft phase is enhanced by 91%, with a coercivity reduction of only 25%. Magnetostatic interactions often but not always deteriorate the permanent-magnet performance, as exemplified by the example of MnBi:FeCo bilayers and multilayers.     

Selective transport of radio-cesium by supported liquid membranes containing calix[4]crown-6 ligands as the mobile carrier

Facilitated transport of Cs-137 across supported liquid membranes (SLM) containing a calix-crown ligand viz. caliz[4]arene-bis(crown-6) (CC), calix[4]arene-bis(o-benzocrown-6) (CBC) or calix[4]arene-bis(napthocrown-6) (CNC) was investigated. The feed consisted of dilute nitric acid solutions while the carrier solutions contained mainly CNC in several organic diluents inside the pores of polypropylene (PP) as well as PTFE flat sheet membranes. PTFE membranes containing CNC in a diluent mixture of 2-nitrophenyloctyl ether (NPOE) and n-dodecane were found to have high stability. Selectivity studies were carried out using simulated high level waste (SHLW) as well as fission products obtained from an irradiated natural uranium target.     

Energy efficient design and occupant well-being: Case studies in the UK and India

The purpose of this paper is to demonstrate the relationships between sustainable building design and occupant well-being. It starts with a definition of sustainable design and well-being, and focuses on the relationships between energy performance and occupant feedback. Methodologically it draws on detailed monitoring and surveys of 12 case study office buildings in the UK and India, and the paper uses the data to explore whether energy use and associated CO₂ emissions are correlated to occupant satisfaction and comfort. The results demonstrate that increased energy use in the case study buildings is associated with increased mechanisation (e.g. centralised air conditioning) and reduced occupant control. This reduced control in turn is shown to relate to reduced occupant comfort and satisfaction. Finally, the paper reveals that the reported health conditions of occupants correlates strongly with their levels of satisfaction. The overall conclusion is that energy use in typical office buildings is inversely correlated with the well-being of the occupants: more energy use does not improve well-being.     

Solid phase extraction of europium and uranium using Tulsion CH-90 resin

A procedure for the pre-concentration and separation of trace amounts of Eu and U by solid phase extraction using Tulsion CH-90 resin (with imino diacetate functional group) has been developed. The determinations of europium and uranium have been carried out by a radiotracer technique using ^152,154Eu and ²³³U radionuclides. The experiments were carried out using both batch and column techniques. Parameters such as equilibration rate, effect of pH, sorption and desorption of metal ions have been studied. The maximum sorption capacities for Eu and U were found to be 0.31 mmolg^–1 at pH 5.3 and 0.96 mmolg^–1 at pH 3.1 respectively.     

Sensory modulation of the medial preoptic area neuronal activity by dorsal penile nerve stimulation in rats

The study was aimed at finding out the influence exerted by the genital afferents on the medial preoptic area (mPOA), which plays a pivotal role in the regulation of male sex behavior. To fulfil this objective, the effects of stimulation of the dorsal penile nerve (DPN) on the activity of 82 mPOA neurons were studied. The base line firing rates of the mPOA neurons, studied by extracellular recording, ranged between 0.5 and 38.5 Hz (mean 7.18 +/- 7.91). The stimulation of the DPN (20 Hz, 0.4 msec. 70 microA) influenced 79.69% of the neurons studied. Though increased firing was the predominant influence produced (50%), decreased firing was also seen in a few (29.69%). The excited and inhibited neurons were randomly distributed within the mPOA. Neurons located in the lateral and posterior hypothalamus were not affected by the DPN stimulation. The stimulation parameters used in this study did not produce any change in the systemic arterial pressure and heart rate. The results provide electrophysiological evidence of afferent inputs from the male sex organ to the mPOA, which is an important area controlling male sex behavior.     

Yttrium oxide/silicon dioxide: a new dielectric structure forVLSI/ULSI circuits

Electrical characteristics of Al/yttrium oxide (~260 Å)/silicon dioxide (~40 Å)/Si and Al/yttrium oxide (~260 Å)/Si structures are described. The Al/Y₂O₃/SiO₂/Si (MYOS) and Al/Y₂ O₃/Si (MYS) capacitors show very well-behaved I-V characteristics with leakage current density <10^-10 A/cm² at 5 V. High-frequency C- V and quasistatic C-V characteristics show very little hysteresis for bias ramp rate ranging from 10 to 100 mV/s. The average interface charge density (Q_f+Q _it) is ~6×10¹¹/cm² and interface state density D_it is ~10¹¹ cm^-2-eV^-1 near the middle of the bandgap of silicon. The accumulation capacitance of this dielectric does not show an appreciable frequency dependence for frequencies varying from 10 kHz to 10 MHz. These electrical characteristics and dielectric constant of ~17-20 for yttrium oxide on SiO₂/Si make it a variable dielectric for DRAM storage capacitors and for decoupling capacitors for on-chip and off-chip applications     

Studies on fermentation-broth rheology of a penicillium strain with cellulose as substrate

The rheological behaviour of cellulose fermentation broths of Penicillium funiculosum culture has been investigated. The shear stress-shear rate behaviour is explained satisfactorily by a power law model, although there appear to be small yield stresses, particularly at high substrate concentrations.