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In this paper, a feasible scheme is reported for the detection and identification of trace alcohol congeners that have identical elemental composition using laser-induced breakdown spectroscopy (LIBS). In the scheme, an intensive pulsed laser is used to break down trace alcohol samples and the optical emission spectra of the induced plasma are collected for the detection and identifq ication of alcohol molecules. In order to prepare trace alcohol samples, pure ethanol or methanol is bubbled by argon carrier gas and then mixed into matrix gases. The key issue for the scheme is to constitute indices from the LIBS data of the alcohol samples. Two indices are found to be suitable for alcohol detection and identification. One is the emission intensity ratio (denoted as H/C) of the hydrogen line (653.3 nm) to the carbon line (247.9 nm) for identification and the other is the ratio of the carbon line (as C/Ar) or the hydrogen line (as H/Ar) to the argon lines (866.7 nm) for quantitative detection. The calibration experiment result shows that the index H/C is specific for alcohol congeners while almost being independent of alcohol concentration. In detail, the H/C keeps a specific constant of 34 and 23 respectively for ethanol and methanol. In the meanwhile, the C/Ar and H/Ar indices respond almost linearly to the alcohol concentration below 1300 ppm, and are therefore competent for concentration measurement. With the indices, trace alcohol concentration measurement achieves a limit of 140 ppm using a laser pulse energy of 300 mJ. 相似文献
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200kg以下的微小卫星的轨道维持、姿态控制、阻尼补偿、编队飞行等任务对微电推进技术及产品提出了明确的应用需求,不同类型的微电推进在不同功率范围内有着各自的优势。本文对中国微小卫星12U立方星LPPT-5脉冲等离子体电推进系统、150kg小卫星LPPT-25脉冲等离子体电推进系统、6U立方星LVAT-1真空弧电推进系统、引力波探测卫星LCT-10胶体电推进系统、低轨小卫星星座LHT-40霍尔电推进系统方案及研制进展进行了论述,最后对正在研制的LRIT-40射频离子电推进系统与LECR-50微波离子电推进系统研制情况及后续应用进行了展望。 相似文献
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The accurate knowledge of the thrust vector eccentricity and beam divergence characteristics of Hall thrusters are of significant engineering value for the beneficial integration and successful application of Hall thrusters on spacecraft. For the characteristics of the plume bipolar diffusion due to the annular discharge channel of the Hall thruster, a Gaussian-fitted method for thrust vector deviation angle and beam divergence of Hall thrusters based on dual Faraday probe array planes was propo... 相似文献
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