Editorial: the March 2022 cover paper

Journal of Materials Science -     

Efficiency of removal of whey protein from sweet whey using polymeric microfiltration membranes

Our objective was to measure whey protein removal percentage from separated sweet whey using spiral-wound (SW) polymeric microfiltration (MF) membranes using a 3-stage, 3× process at 50°C and to compare the performance of polymeric membranes with ceramic membranes. Pasteurized, separated Cheddar cheese whey (1,080 kg) was microfiltered using a polymeric 0.3-μm polyvinylidene (PVDF) fluoride SW membrane and a 3×, 3-stage MF process. Cheese making and whey processing were replicated 3 times. There was no detectable level of lactoferrin and no intact α- or β-casein detected in the MF permeate from the 0.3-μm SW PVDF membranes used in this study. We found BSA and IgG in both the retentate and permeate. The β-lactoglobulin (β-LG) and α-lactalbumin (α-LA) partitioned between retentate and permeate, but β-LG passage through the membrane was retarded more than α-LA because the ratio of β-LG to α-LA was higher in the MF retentate than either in the sweet whey feed or the MF permeate. About 69% of the crude protein present in the pasteurized separated sweet whey was removed using a 3×, 3-stage, 0.3-μm SW PVDF MF process at 50°C compared with 0.1-μm ceramic graded permeability MF that removed about 85% of crude protein from sweet whey. The polymeric SW membranes used in this study achieve approximately 20% lower yield of whey protein isolate (WPI) and a 50% higher yield of whey protein phospholipid concentrate (WPPC) under the same MF processing conditions as ceramic MF membranes used in the comparison study. Total gross revenue from the sale of WPI plus WPPC produced with polymeric versus ceramic membranes is influenced by both the absolute market price for each product and the ratio of market price of these 2 products. The combination of the market price of WPPC versus WPI and the influence of difference in yield of WPPC and WPI produced with polymeric versus ceramic membranes yielded a price ratio of WPPC versus WPI of 0.556 as the cross over point that determined which membrane type achieves higher total gross revenue return from production of these 2 products from separated sweet whey. A complete economic engineering study comparison of the WPI and WPPC manufacturing costs for polymeric versus ceramic MF membranes is needed to determine the effect of membrane material selection on long-term processing costs, which will affect net revenue and profit when the same quantity of sweet whey is processed under various market price conditions.     

Laboratory evaluation of interfacial mechanical properties in geogrid-reinforced bituminous layers

In this study, the mechanical properties of composite bituminous structures with geogrid products, used as an interlayer between different types of bituminous mixtures, at a constant temperature, were examined. A twofold experimental program based on new approaches was selected. A new configuration of the 3-Point Bending Test (3-PBT) was adopted to capture the J-integral and crack resistance property defined by crack resistance index (CRI) at the interface against bottom-up crack propagation. The bonding quality at the interface was also defined through a new index named coefficient of interface bonding (CIB), which was measured via a modified version of the slant shear device. The results derived from this research revealed that reinforcement of the interface, with varying degree of surface texture, by geogrid products significantly enhances the fracture toughness of the whole system in terms of the J-integral, which could be properly connected to the combined functions of bonding quality and crack resistance indices defined at the interface.     

Innovation in urban systems: The interrelationships between urban and national economic development

The theoretical basis for analysing the role of innovation in economic development is assessed, as is the application of such theories to urbanisation processes. It is concluded that innovation lies at the heart of economic development and that urban development has important feedback effects on national economic development. Analysing these feedbacks requires a sophisticated data set allowing the analysis of input-output relationships in urban systems over time. In the absence of such data, industry employment classifications are used as a proxy for economic structure in an analysis of United States and Australian cities. Particular kinds of cities in the urban hierarchy can be analysed in terms of their economic structure and this can then be related to national economic development trends. The contributions of categories of city (particularly by size class) to economic development can then be explored. Obviously, results will vary with the era of economic development covered by the data. However, in all eras, certain kinds of cities will emerge as leaders in the process of urban economic development and will also play a crucial role in national economic development.     

Toxicity bioassay of heavy metals in water using Tetrahymena pyriformis

The toxicities of five heavy metal compounds on the survival of the ciliated protozoan Tetrahymena pyriformis were determined. Three-day old cultured cells were exposed to five concentrations of each test compound in one or more of three water series; distilled, soft, and hard water. A culture of each sample was placed in a plastic petri dish and covered with mineral oil to prevent evaporation. The cells were counted initially, then again at 0·5 h, 1 h, 2 h, 1 day, 2 days, 3 days, and on the fourth day. Lethal threshold concentrations and tolerance limit medians were determined by graphic methods. On a weight bases cadmium was most toxic, followed in decreasing toxicity by mercury, cobalt, zinc, and lead. Compared to similar fish data, all heavy metals were more toxic to T. pyriformis except lead. The toxicity of lead in soft versus hard water exemplified an antagonistic effect with greater than seven times the amount of lead necessary in hard water to produce comparable mortality as lead in soft water. On the other hand, the toxicity of mercury is about twice as great in hard water as in soft water (a synergistic effect). T. pyriformis appears to be a more sensitive indicator than fish of heavy metal contamination of water. T. pyriformis bioassay should prove a good means of determining the existence of many water pollutants.     

Oriented polymer grid reinforcement

Tensar high strength oriented polymer grids were developed in the UK in the late 1970s. Extensive research has been conducted in Europe and North America to investigate the various civil engineering applications for these materials. The availability of these high strength, durable reinforcing grids has led to many innovative and economical developments in geotechnical and highway engineering. This paper describes the major application areas: reinforced soil walls and slopes, reinstatement of slope failures; embankment foundations over soft soil; reinforcement of road bases for paved roads; and asphalt reinforcement.     

Unpacking Cohort Social Ties: The Appropriateness of Perceived Social Capital to Graduate Early Career Performance in Construction Project Teams

Construction project teams require social capital. When present in appropriate forms, it creates the social cohesion through which individuals accept project goals as their own. It lets team members share knowledge when present and reveal when it is missing. In education, social learning helps students appreciate the need for social capital appropriate to team performance. In practice, social capital enables the project team learning that overcomes project-specific challenges. Despite this importance, little is known about how students perceive social capital or the compatibility of that understanding with construction project needs.

To characterise this aspect of ‘graduateness,’ collective understanding of social capital was elicited from construction students in a Scottish university by free recall. Analysis was structured around four dimensions of social capital: cohesion, legitimacy & authenticity, sharing, and safety. Notions of friendship were found to dominate student understanding of their social capital even though this understanding derived from settings where the need for capital to support team performance is emphasized. The potential for misalignment between the capital that graduating students bring into practice with that required by project teams was apparent. The case for further investigation of this influence on early career development was established.     

Evaluation of surface/interface quality,microstructure and mechanical properties of hybrid additive-subtractive aluminium parts

A disadvantage of selective laser melting (SLM) processes for the manufacture of large parts is their slow build time per unit volume. A hybrid route is to generate core simple shapes traditionally, for example by machining, followed by adding final features by SLM. Here the mechanical integrity of such hybrid parts is studied, choosing the building of AlSi10Mg by SLM on a machined AA6082 base, in the shape of a tensile test piece, as a simple example. These materials are chosen for their relevance to lightweight parts. As-built parts fail at the SLM/machined interface but standard heat treatments transfer failures to the machined material. Optimised SLM processing conditions and microstructures of the SLM and interfacial regions are reported.