Contact size-dependent switching instabilities in HfO2 RRAM

Journal of Materials Science: Materials in Electronics - A comprehensive understanding of the resistive switching mechanisms that activate REDOX-based random access memory devices is necessary to...     

Superradiant Emission from Coherent Excitons in van Der Waals Heterostructures

Recent advancements in isolation and stacking of layered van der Waals materials have created an unprecedented paradigm for demonstrating varieties of 2D quantum materials. Rationally designed van der Waals heterostructures composed of monolayer transition-metal dichalcogenides (TMDs) and few-layer hBN show several unique optoelectronic features driven by correlations. However, entangled superradiant excitonic species in such systems have not been observed before. In this report, it is demonstrated that strong suppression of phonon population at low temperature results in a formation of a coherent excitonic-dipoles ensemble in the heterostructure, and the collective oscillation of those dipoles stimulates a robust phase synchronized ultra-narrow band superradiant emission even at extremely low pumping intensity. Such emitters are in high demand for a multitude of applications, including fundamental research on many-body correlations and other state-of-the-art technologies. This timely demonstration paves the way for further exploration of ultralow-threshold quantum-emitting devices with unmatched design freedom and spectral tunability.     

Matrix Transformation in Boron Containing High-Temperature Co–Re–Cr Alloys

An addition of boron largely increases the ductility in polycrystalline high-temperature Co–Re alloys. Therefore, the effect of boron on the alloy structural characteristics is of high importance for the stability of the matrix at operational temperatures. Volume fractions of ε (hexagonal close-packed—hcp), γ (face-centered cubic—fcc) and σ (Cr₂Re₃ type) phases were measured at ambient and high temperatures (up to 1500 °C) for a boron-containing Co–17Re–23Cr alloy using neutron diffraction. The matrix phase undergoes an allotropic transformation from ε to γ structure at high temperatures, similar to pure cobalt and to the previously investigated, more complex Co–17Re–23Cr–1.2Ta–2.6C alloy. It was determined in this study that the transformation temperature depends on the boron content (0–1000 wt. ppm). Nevertheless, the transformation temperature did not change monotonically with the increase in the boron content but reached a minimum at approximately 200 ppm of boron. A probable reason is the interplay between the amount of boron in the matrix and the amount of σ phase, which binds hcp-stabilizing elements (Cr and Re). Moreover, borides were identified in alloys with high boron content.     

Synthesis of ZnS nanoparticles of required size by precipitation in aerosol microdroplets

Zinc sulphide (ZnS) nanoparticles were prepared by an aerosol method from zinc acetate and sodium sulphide (Na₂S) aqueous solutions. Aqueous solution of zinc acetate was dispersed into the form of microdroplets, which were introduced by airflow to vigorously stirred aqueous solution of Na₂S, which was in excess. Microdroplets served as microreactors, so the reaction took place only in limited volume. Particle size distribution was studied by transmission electron microscopy and by dynamic light scattering measurements. In this work, the equation that allows us to predict the final size distribution of ZnS nanoparticles using exact concentration of zinc acetate was derived and ZnS nanoparticles with predicted mean particle diameter around 50 and 70?nm were successfully synthetised.     

Quantitative Analysis of Carbide Phases in Medium-Carbon Steel After Low-Temperature Tempering

Metallurgist - Structural features of high-strength wear-resistant steel formed after tempering at different temperatures are investigated. Temperature dependences are determined for steel hardness...     

A comparative study of direct and indirect evaluation of piezoelectric properties of electrophoreticaly deposited (Ba,Ca) (Zr,Ti)O3 lead-free piezoceramics

The development and optimisation of piezoceramics are targeted usually to enhance their piezoelectric properties evaluated by both the direct or indirect measurement methods. The presented work aims to elaborate on the correlation of one direct (Berlincourt) and two indirect (convert and field-dependent) piezoelectric measurement methods on various material states. The role of the ceramic powder treatment by ball milling and electrophoretic deposition (EPD) technique on the determined electric properties as well as basic physical and mechanical properties of (Ba_0.85Ca_0.15) (Zr_0.1Ti_0.9)O₃ ceramics (BCZT) was investigated. It was found that the EPD technologically supported by milling allows obtaining thick and dense deposits (>2 mm). After sintering, the BCZT ceramics with a relative density of >95%, hardness in the range of 2.3–2.9 GPa and piezoelectric coefficients of d₃₃* = 940 pm/V, d_33(E=0) = 427 pm/V and d₃₃ = 364 pC/N can be achieved. Reported results also suggest that indirect (field-dependent) and direct (Berlincourt) measurements of the piezoelectric coefficients can be comparable at optimal poling conditions.     

Ordinary Gasoline Emissions Induce a Toxic Response in Bronchial Cells Grown at Air-Liquid Interface

Gasoline engine emissions have been classified as possibly carcinogenic to humans and represent a significant health risk. In this study, we used MucilAir™, a three-dimensional (3D) model of the human airway, and BEAS-2B, cells originating from the human bronchial epithelium, grown at the air-liquid interface to assess the toxicity of ordinary gasoline exhaust produced by a direct injection spark ignition engine. The transepithelial electrical resistance (TEER), production of mucin, and lactate dehydrogenase (LDH) and adenylate kinase (AK) activities were analyzed after one day and five days of exposure. The induction of double-stranded DNA breaks was measured by the detection of histone H2AX phosphorylation. Next-generation sequencing was used to analyze the modulation of expression of the relevant 370 genes. The exposure to gasoline emissions affected the integrity, as well as LDH and AK leakage in the 3D model, particularly after longer exposure periods. Mucin production was mostly decreased with the exception of longer BEAS-2B treatment, for which a significant increase was detected. DNA damage was detected after five days of exposure in the 3D model, but not in BEAS-2B cells. The expression of CYP1A1 and GSTA3 was modulated in MucilAir™ tissues after 5 days of treatment. In BEAS-2B cells, the expression of 39 mRNAs was affected after short exposure, most of them were upregulated. The five days of exposure modulated the expression of 11 genes in this cell line. In conclusion, the ordinary gasoline emissions induced a toxic response in MucilAir™. In BEAS-2B cells, the biological response was less pronounced, mostly limited to gene expression changes.     

Conversion kinetics of container glass batch melting

Understanding the batch-to-glass conversion process is fundamental to optimizing the performance of glass-melting furnaces and ensuring that furnace modeling can correctly predict the observed outcome when batch materials or furnace conditions change. To investigate the kinetics of silica dissolution, gas evolution, and primary foam formation and collapse, we performed X-ray diffraction, thermal gravimetry, feed expansion tests, and evolved gas analysis of batch samples heated at several constant heating rates. We found that gas evolving reactions, foaming, and silica dissolution depend on the thermal history of the batch in a similar manner: the kinetic parameters of each process were linear functions of the square root of the heating rate. This kinetic similarity reflects the stronger-than-expected interdependence of these processes. On the basis of our results, we suggest that changes in furnace operating conditions, such as firing or boosting, influence the melting rate less than what one would expect without consideration of batch conversion kinetics.     

Can video games change attitudes towards history? Results from a laboratory experiment measuring short- and long-term effects

This study investigates a video game's effects on implicit and explicit attitudes towards depicted historical events in the short- and long-term on a sample of 148 young adults. We used, as an intervention tool, a serious game Czechoslovakia 38–89: Borderlands that deals with the expulsion of the Sudeten Germans from the former Czechoslovakia after the WWII. Results showed more negative pretest-posttest explicit attitude changes towards the expulsion on a general level (d = −0.34) and a specific level (d = −0.53) compared to the control group. Over the long-term, group differences in attitude change remained significant for the specific level (d = −0.44), but not for general one (d = −0.16). Exploratory analysis on the item level indicated that especially attitudes towards the expulsion's (un)fairness were affected by the game. However, no significant changes were found in implicit attitudes in the experimental group. This study is the first of such scale to empirically investigate video games' effects on a society's historical awareness.     

Effects of hydrocarbon impurities,vibrational relaxation,and boundary-layer-induced pressure rise on the ignition of H2–O2‒Ar mixtures behind reflected shock waves

The results of an experimental and theoretical study of the ignition of H₂–O₂?Ar mixtures behind reflected shock waves are reported. The experiments are performed with mixtures containing from 0.15 to 8.0% H₂ and from 0.75 to 2.0% O₂ at temperatures of 980–1800 K and a total gas concentration of (1.0 ± 0.1) × 10^?5 mol/cm³. The progress of the process is monitored by recording the time evolution of the pressure behind the reflected shock wave and the intensity of the chemiluminescence of electronically excited OH1 radicals (λ = 308 ± 2.5 nm). A numerical model capable of predicting the effects of additional factors, such as hydrocarbon impurities, the vibrational relaxation of the test mixture, and boundary-layer-induced pressure rise, is developed and used to simulate our own and published experimental data on the ignition of H₂–O₂?Ar mixtures. It is demonstrated that the best agreement between experimental and theoretical results is achieved when all the additional factors are taken into account. A sensitivity analysis shows that the effects of the vibrational relaxation of the test mixture and the presence of hydrocarbon impurities are significant only for lean mixtures, whereas the influence of the boundary-layer-induced pressure rise is important across a wide range of stoichiometries at long ignition delay times. Additionally, an analytical model is developed, which takes into account the finite time of the chain?propagation reactions O + H₂ and OH + H₂. The predictions of the numerical and analytical models are demonstrated to be in close agreement for a wide range of mixture compositions and experimental conditions.