Synthesis, structure and magnetic properties of β-MnO 2 nanorods

We present synthesis, structure and magnetic properties of structurally well-ordered single-crystalline β-MnO₂ nanorods of 50–100 nm diameter and several μm length. Thorough structural characterization shows that the basic β-MnO₂ material is covered by a thin surface layer (∼2.5 nm) of α-Mn₂O₃ phase with a reduced Mn valence that adds its own magnetic signal to the total magnetization of the β-MnO₂ nanorods. The relatively complicated temperature-dependent magnetism of the nanorods can be explained in terms of a superposition of bulk magnetic properties of spatially segregated β-MnO₂ and α-Mn₂O₃ constituent phases and the soft ferromagnetism of the thin interface layer between these two phases.     

A chamber for biomechanical,electrochemical and electrophysiological measurements in functional segments of peripheral nerves

The aim of the work was to develop the chamber to be used in biomechanical, electrochemical and electrophysiological measurements in functional segments of peripheral nerves, when electrical stimulating pulses are selectively applied to preselected locations along the nerve and neural responses are measured.     

The control of the diameter and length of α-MnO2 nanorods by regulation of reaction parameters and their thermogravimetric properties

α-MnO₂-type single-crystal nanorods were synthesized under hydrothermal conditions based on the redox reaction of KMnO₄ in an acidic environment. Several reaction parameters, like the reaction temperature, the reaction time and the concentration of KMnO₄ in the reaction mixture, were varied in order to determine their impact on the structure, the dimensions of the synthesized nanorods, and as well on their thermogravimetric properties. It was found that the reaction time has no significant influence on the diameter, although it has a strong influence on the length of the obtained nanorods. On the other hand, the concentration of KMnO₄ in the reaction mixture has a strong impact on both the diameter and the length. With an increasing concentration of KMnO₄ in the reaction mixture the average lengths and diameters of the isolated MnO₂ nanorods are reduced. The change in dimensions of the synthesized nanorods is reflected in their thermogravimetric properties.     

Psychological factors in psychosomatic diseases: an outline of research results

This article presents an outline of 13 research studies which were carried out in the 1980s at the Clinical Psychology Division of the Psychology Department at the Faculty of Arts in Ljubljana. The studies concentrated on various psychosomatic diseases and dysfunctions by applying 26 psychodiagnostic instruments. The problems, the usefulness of the instruments, and basic characteristics of diseases were analyzed, and a model for further research into psychological factors in psychosomatic diseases was proposed. We are of the opinion that the fundamental dimensions of personality--aggressiveness and ways of coping with stress within a specific life style and supported by information from life history--deserve special attention. Therefore, we suggest that a set of basic psychodiagnostic instruments be compiled. We also suggest that particularly general practitioners be acquainted with these factors involved in psychosomatic dysfunctions, because they most often confront problems of this kind. We believe that somatic therapy is doubtless necessary, but insufficient, because a patient is not treated as a whole, which is imperative in psychosomatics. This is a sphere where medicine and psychology will meet more regularly in the future.     

Robustness as a criterion for use of hollow clay masonry units in seismic zones: an attempt to propose the measure

In order to provide adequate seismic behavior of masonry walls, local brittle failure of masonry units in the most stressed zones of structural walls should be prevented. Although robust behavior is required by the code, no specifications are given regarding the criteria to fulfill this requirement. To propose such criteria, a series of 28 masonry walls, built with six different types of hollow clay masonry units, currently available on the market, have been tested by subjecting them to cyclic lateral load at two levels of constant precompression. Besides, the strength characteristics of the units, like compressive strength orthogonal and parallel to the bed joints and tensile and shear strength of the units have been determined by standardized and specifically designed testing procedures. By correlating the parameters of seismic resistance of the walls and strength characteristics of the units, no specific indicator for robustness could have been determined on the basis of the mechanical characteristics of the tested units. It has been found that in all cases the level of precompression, i.e. the ratio between the compressive stresses in the walls and the compressive strength of masonry, represents the governing parameter.     

Enhanced selenium content in buckwheat (<Emphasis Type="Italic">Fagopyrum esculentum</Emphasis> Moench) and pumpkin (<Emphasis Type="Italic">Cucurbita pepo</Emphasis> L.) seeds by foliar fertilisation

The fruit and thin-husked seeds of the pumpkin (Cucurbita pepo L.) and buckwheat grain (Fagopyrum esculentum Moench), both grown in Slovenia, were analysed for selenium (Se) content following foliar application of Se(VI) solution during the period of blooming. Samples were digested by a H₂SO₄-HNO₃-H₂O₂-V₂O₅ mixture and Se determined, based on hydride generation atomic fluorescence spectrometry. The whole procedure from weighing to measuring was carried out in the same Teflon vessel. The detection limit of the method was 0.14 ng g^–1 solution. Buckwheat seeds from untreated plants contained 47 ng g^–1 of Se and 394 ng g^–1 from plants after foliar fertilisation with Se. Pumpkin seeds from untreated plants contained 108 ng g^–1 of Se, and 381 ng g^–1 of Se from Se-treated plants, all per lyophilised sample. Se content in lyophilised pumpkin fruit was 15 ng g^–1 in untreated plants and 20 ng g^–1 in Se-treated pumpkin plants. It is thus feasible to enhance Se content in buckwheat and pumpkin seeds by foliar fertilisation, making them a rich source of dietary Se and useful as a raw material for enriched food products.     

Single‐Step Deposition of Au‐ and Pt‐Nanoparticle‐Functionalized Tungsten Oxide Nanoneedles Synthesized Via Aerosol‐Assisted CVD,and Used for Fabrication of Selective Gas Microsensor Arrays

Tungsten oxide nanostructures functionalized with gold or platinum NPs are synthesized and integrated, using a single‐step method via aerosol‐assisted chemical vapour deposition, onto micro‐electromechanical system (MEMS)‐based gas‐sensor platforms. This co‐deposition method is demonstrated to be an effective route to incorporate metal nanoparticles (NP) or combinations of metal NPs into nanostructured materials, resulting in an attractive way of tuning functionality in metal oxides (MOX). The results show variations in electronic and sensing properties of tungsten oxide according to the metal NPs introduced, which are used to discriminate effectively analytes (C₂H₅OH, H₂, and CO) that are present in proton‐exchange fuel cells. Improved sensing characteristics, in particular to H₂, are observed at 250 °C with Pt‐functionalized tungsten oxide films, whereas non‐functionalized tungsten oxide films show responses to low concentrations of CO at low temperatures. Differences in the sensing characteristics of these films are attributed to the different reactivities of metal NPs (Au and Pt), and to the degree of electronic interaction at the MOX/metal NP interface. The method presented in this work has advantages over other methods of integrating nanomaterials and devices, of having fewer processing steps, relatively low processing temperature, and no requirement for substrate pre‐treatment.     

Total body irradiation with translation method

METHOD: An extended coverage bladder (ECB) G-suit was evaluated on the DCIEM centrifuge against the current service G-suit (CSU-15/P) in two separate series of experiments. The ECB G-suit covered approximately 85% of the lower body measuring from the umbilicus and all five bladders completely encircled each leg and the lower trunk. The CSU-15/P G-suit covered approximately 30% of the lower body and its five bladders were located only over the frontal aspect of each leg and the lower trunk. The first series of experiments involved five subjects from the highly experienced DCIEM A-team. A standard gradual onset rate (GOR) run was used and suit testing order was counterbalanced across subjects. RESULTS: The test condition G-tolerances are listed as mean +/- SEM; relaxed uninflated tolerances were 4.0 +/- 0.14 for the CSU-15/P suit vs. 4.1 +/- 0.09 for the ECB suit (ns, single tailed, paired t-test) while relaxed inflated tolerances were 4.7 +/- 0.19 for the CSU-15/P suit and 5.5 +/- 0.37 for the ECB suit (p = 0.02, single tailed, paired t-test). The straining tolerances were 8.1 +/- 0.44 for the CSU-15/P suit and 9.0 +/- 0.56 for the ECB suit (p = 0.01, single tailed, paired t-test). The second series involved nine subjects for the following three G-suit conditions; CSU-15/P, ECB with inflation limiters, and ECB with inflation limiters and foot bladders. Relaxed uninflated tolerances were 4.0 +/- 0.13, 4.0 +/- 0.08, and 3.9 +/- 0.10 (ns) while straining inflated tolerances were 9.4 +/- 0.48, 10.1 +/- 0.38 and 10.6 +/- 0.42, respectively (p = 0.01 between all three straining conditions, ANOVA with Scheffé F-test). The ECB G-suit with inflation limiters eliminated abdominal pain and discomfort. CONCLUSION: The ECB G-suit provides improved G-tolerance for both inflated relaxed and straining exposures. Foot bladders eliminated high Gz foot pain and improved straining G-tolerance by about half a Gz. The efficacy of ECB G-suits should be evaluated when used in conjunction with positive pressure breathing. While the ultimate G-suit has yet to be conceived and will no doubt be part of an integrated life support system, ECB G-suits are a step in the right direction in the evolution of life support garmentry.