Investigation on sulphonated zinc oxide nanorod incorporated sulphonated poly (1,4-phenylene ether ether sulfone) nanocomposite membranes for improved performance of microbial fuel cell

Hydrothermally prepared zinc oxide nanorods are sulphonated (S–ZnO NR) and incorporated into 15% Sulphonated Poly (1,4-Phenylene Ether Ether Sulfone) (SPEES) to improve the hydrophilicity, water uptake and ion transfer capacity. Water uptake and ion transfer capacity increased to 34.6 ± 0.6% and 2.0 ± 0.05 meq g^?1 from 29.8 ± 0.3% and 1.4 ± 0.04 meq g^?1 by adding 7.5 wt% S–ZnO NR to SPEES. Morphological studies show the prepared S–ZnO NR is well dispersed in the polymer matrix. SPEES +7.5 wt% S–ZnO NR membrane exhibits optimum performance after three-weeks of continual operation in a fabricated microbial fuel cell (MFC) to produce a maximum power density of 142 ± 1.2 mW m^?2 with a reduced biofilm compared to plain SPEES (59 ± 0.8 mW m^?2), unsulphonated filler incorporated SPEES (SPEES + 7.5 wt% ZnO, 68 ± 1.1 mW m^?2) and Nafion (130 ± 1.5 mW m^?2) thereby suggesting its suitability as a sustainable and improved cation exchange membrane (CEM) for MFCs.     

Biohydrogen Production from Organic Waste – A Review

Hydrogen fuel is a promising alternative to fossil fuels because of its energy content, clean nature, and fuel efficiency. However, it is not readily available. Most current producion processes are very energy intensive and emit carbon dioxide. Therefore, this article reviews technological options for hydrogen production that are eco-friendly and generate clean hydrogen fuel. Biological methods, such different fermentation processes and photolysis are discussed together with the required substrates and the process efficiency.     

Performance analysis of linear precoding based on field trials results of MIMO-OFDM system

We use field trial results obtained from a multiple-input multiple-output (MIMO) orthogonal frequency-division multiplexing (OFDM) wireless system with two transmitter and three receiver antennas (2/spl times/3), to first validate the properties of the transmit correlation matrix in a macro-cellular environment. We find that approximately 20% of the locations have well-defined transmit correlation matrices. Furthermore, the eigenvectors of the transmit correlation matrix vary slowly over distance with 60% of the locations having eigenvector variation of less than 1 dB over a distance of 20 m. Next, we quantify the performance of the optimal statistical linear precoding (OSLP) , and statistical one-dimensional (1-D) eigenbeamforming (SEB) based on transmit correlation matrices, and the 1-D eigenbeamforming (EB)-based on perfect channel knowledge at the transmitter. We find that the OSLP and SEB schemes obtain array gain over the Alamouti scheme at lower signal-to-noise ratio (SNR) with a median gain of 2.0 (1.5) dB at the 1.0-(3.5) km cell-radii. However, the SEB scheme (unlike the OSLP scheme) looses diversity order at higher SNR that leads to a performance loss. The EB scheme provides the best performance over the Alamouti scheme, at the expense of increased feedback requirements.     

Are Diamonds a MEMS' Best Friend?

Next-generation military and civilian communication systems will require technologies capable of handling data/ audio, and video simultaneously while supporting multiple RF systems operating in several different frequency bands from the MHz to the GHz range [1]. RF microelectromechani-cal/nanoelectromechanical (MEMS/NEMS) devices, such as resonators and switches, are attractive to industry as they offer a means by which performance can be greatly improved for wireless applications while at the same time potentially reducing overall size and weight as well as manufacturing costs.     

Ambient and high-temperature thermal conductivity of thermal sprayed coatings

Aside from its importance as a design parameter for thermal barrier coatings, measuring thermal conductivity of thermal sprayed coatings itself provides a unique method to critically characterize the nature, quantity, and anisotropy of the defect morphologies in these splat-based coatings. In this paper, the authors present a systematic assessment of thermal conductivity of wide range using the flash diffusivity technique. For the case of plasma sprayed yttria-stabilized zirconia (YSZ), coatings obtained from wide-ranging initial powder morphologies as well as those fabricated under different particle states were characterized. Both in-plane and through-thickness properties were obtained. Other material systems that were considered include: metallic alloys and semiconductors of interests. Issues such as reproducibility and reliability in measurements were also considered and assessed. Finally, work in collaboration with the Oak Ridge National Laboratory (ORNL) for alternate approaches to characterization of thermal conductivity as well as high-temperature measurements was performed. This article was originally published inBuilding on 100 Years of Success, Proceedings of the 2006 International Thermal Spray Conference (Seattle, WA), May 15–18, 2006, B.R. Marple, M.M. Hyland, Y.-Ch. Lau, R.S. Lima, and J. Voyer, Ed., ASM International, Materials Park, OH, 2006.     

An elementary theory of product-line variations

The primary aim of a software product-line is to maximise reuse of software components by managing the variability in component functionalities and product configurations. Feature oriented domain analysis (FODA) diagrams are a formalism for modelling the variability in a software product-line, and are used as a tool for managing a product-line and planning its evolution. This paper presents an elementary theory of variations in a product-line, leading up to a technique for extracting FODA diagrams from legacy product-lines. The theory is elementary in the sense that it is built using very simple mathematical structures, making minimal assumptions on the structure of product-lines. Examples drawn from the automotive domain are used to illustrate the theoretical developments.     

Computational Decision Support System for ADHD Identification

Machine Intelligence Research - Attention deficit/hyperactivity disorder (ADHD) is a common disorder among children. ADHD often prevails into adulthood, unless proper treatments are facilitated to...     

Comparison of TiAIN,AICrN, and AICrN/TiAIN coatings for cutting-tool applications

Monolayer and bilayer coatings of TiAlN, AlCrN, and AlCrN/TiAlN were deposited onto tungsten carbide inserts using the plasma enhanced physical vapor deposition process. The microstructures of the coatings were characterized using scanning electron microscopy （SEM） and atomic force microscopy （AFM）. The SEM micrographs revealed that the AlrN and AlCrN/TiAlN coatings were uniform and highly dense and contained only a limited number of microvoids. The TiAIN coating was non-uniform and highly porous and contained more micro droplets. The hardness and scratch resistance of the specimens were measured using a nanoindentation tester and scratch tester, respectively. Different phases formed in the coatings were analyzed by X-ray diffraction （XRD）. The AlCrN/TiAlN coating exhibited a higher hardness （32.75 GPa）, a higher Young＇s modulus （561.97 GPa）, and superior scratch resistance （LcN = 46 N） compared to conventional coatings such as TiAlN, A1CrN, and TiN.     

Structure/property relationships in sintered and thermally sprayed WC-Co

Thermally sprayed WC-Co is widely used as a wear-resistant coating for a variety of applications. Although it is well established that thermal spray processes significantly affect chemistry, microstructure, and the phase distribution of WC-Co coatings, little is known about how these changes influence wear resistance. In this study, the microstructure and wear behavior of sintered and thermally sprayed WC-Co materials are examined. Powders of WC-12 wt% Co and WC-17 wt% Co were pressed and sintered, as well as thermally sprayed by high-velocity oxy-fuel (HVOF), air plasma spray (APS), and vacuum plasma spray (VPS) techniques. Results indicated considerable differences in the resulting microstructures, mechanical properties, and wear resistance. The thermally sprayed coatings showed anisotropic fracture toughness, whereas the sintered materials did not. It was also shown that a combined mechanical property/microstructure parameter, based on considerations of indentation fracture mechanisms, can be used in most cases to describe abrasive and erosive wear resistance of thermally sprayed WC-Co materials as follows: Wear resistance a whereK _ic is the indentation fracture toughness,H is hardness, andV ^Co _f is the volume fraction of cobalt. This relationship provides a means for assessing wear resistance of WC-Co coatings intended for industrial applications requiring abrasion and/or erosion resistance.