基于柠檬酸-铕纳米配位聚合物构建荧光探针快速检测汤煲中5’-肌苷酸含量

基于柠檬酸-铕金属有机纳米配体聚合物（citrate/europium lanthanide coordination polymer nanoparticles，Cit/Eu LCP NPs）构建快速检测肉品汤煲中5’-肌苷酸（inosine-5’-monophosphate，5’-IMP）的荧光探针。研究结果表明，5’-IMP对Cit/Eu?LCP?NPs有良好的荧光猝灭作用。在最佳条件下，该荧光探针在5’-IMP?2.5～200?μg/mL的质量浓度范围内呈现出良好的线性关系，检出限为0.17?μg/mL，且具备良好的抗干扰、稳定性和重复性。为了验证方法可行性，将该方法应用于实际鸡汤样品中的5’-IMP检测，测得加标回收率为97.85%～103.95%，可为快速检测肉品汤煲中5’-IMP提供新的思路和方法。     

One-step preparation of the superhydrophobic Al alloy surface with enhanced corrosion and wear resistance

Corrosion and wear failures are bottlenecks for restricting applications and developments of Al-based functional materials. As a new lubrication technology, superhydrophobic preparation provides an effective way to settle Al alloy corrosion. The preparation methods of superhydrophobic Al alloys are mainly multistep strategies. In this study, superhydrophobic Al alloy, has been prepared by an efficient one-step electrochemical etching process. Meanwhile, its micromorphology has been observed by a scanning electron microscope. The wettability has been measured by video optical contact angle meter. The corrosion behavior has been tested by electrochemical workstation, and wear performance has been characterized by friction tester. The results show that the micro-nanoterraced concave–convex structure has been fabricated and an as-prepared surface exhibits excellent superhydrophobic behavior. Further electrochemical and tribological tests show that corrosion resistance and wear resistance have also been significantly improved. This study provides a new method to prepare wear-resistant and corrosion-resistant Al alloy for widening applications of multifunctional Al-based engineering materials.     

基于电能质量约束的智能配电网分布式电源消纳能力研究

针对智能配电网分布式电源消纳引起的电能质量问题，分析了以电能质量综合指标为控制目标的分布式电源消纳能力评价方法，并依此为约束，采用参数辨识的方法开展智能配电网分布式电源消纳能力研究。IEEE 33节点算例结果表明，文章提出的思路和方法可行，该方法可方便应用到实际工程的决策中。     

2.25Cr-1Mo与2.25Cr-1Mo-0.25V钢冷却转变对比分析

采用相变仪、光学显微镜及扫描电镜研究了2.25Cr-1Mo和2.25Cr-1Mo-0.25V钢冷却转变过程,并分析了钒对其冷却转变的影响。结果表明,与2.25Cr-1Mo钢的CCT曲线相比,2.25Cr-1Mo-0.25V钢铁素体转变区及贝氏体转变区均向右移,并且在现有试验条件下已无法观察到珠光体转变区;钒添加到2.25Cr-1Mo钢中,能够提高钢的淬透性,2.25Cr-1Mo-0.25V钢在48 000 ℃/h冷速下能生成部分马氏体;钒能够细化钢板显微组织,与2.25Cr-1Mo钢相比,2.25Cr-1Mo-0.25V钢在800 ℃/h冷速下组织更为细小。     

仿生群体智能算法的演示教学

近年来,蚁群算法、蟑螂算法、微粒群算法、鱼群算法、蜂群算法等仿生算法层出不穷,由于这些群体智能算法具有良好的全局搜索能力,故在复杂的化工优化问题中得以广泛应用。因此,数值计算、优化方法等相关课程中应用演示教学法,将各种仿生算法的计算过程、算法参数对计算过程、计算性能的影响通过计算演示充分展示给学生看,可使枯燥、抽象的算法教学变得具体、形象、生动,显著提高学生的学习兴趣和教学质量。     

Ultraviolet‐crosslinked hydrogel sustained‐release hydrophobic antibiotics with long‐term antibacterial activity and limited cytotoxicity

To prolong erythromycin (EM) release and prevent the side effects of EM, a Pluronic F‐127 diacrylate macromer (PF127) was synthesized and then self‐assembled into micelles with their hydrophobic cores loaded with EM. The EM‐loaded micelles were mixed with a photoinitiator to form the EM/PF127 hydrogels rapidly under a low‐intensity UV light. Afterward, the hydrogel properties, antibacterial performance, and cytotoxicity of this novel hybrid hydrogel were investigated. The results show that the EM/PF127 hydrogel had a rapid gelation time. The sustained release of EM reduced its side effects. With controlled antibacterial activity, the use of EM would be safer and more efficient. What is more, the EM/PF127 hydrogel showed a slight cytotoxicity, and this suggests great potential application as antibacterial hydrogels in the prevention of postoperative infection. © 2014 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2014 , 131, 40438.     

天然橡胶中蛋白质的研究进展

天然橡胶中含有很大数量的蛋白质,文章从蛋白质在天然胶乳中的生理作用,蛋白质对天然橡胶性能的影响及蛋白质脱除技术三个方面简述了天然橡胶中蛋白质的研究现状。     

甲醇制烯烃催化剂积炭的形成机理

采用二氯甲烷超声波萃取,提取甲醇制烯烃(MTO)待生催化剂和不完全再生催化剂外表面可溶性积炭,采用氢氟酸溶解及碳酸钠溶液中和后再用二氯甲烷超声波萃取,提取待生催化剂和不完全再生催化剂孔道内可溶性积炭,结合气相色谱-质谱(GC-MS)分析了其组成,并对MTO催化剂积炭形成的机理和再生烧炭的机理进行了分析探讨。结果表明:MTO待生催化剂外表面可溶性积炭主要是饱和烃和芳烃,其中饱和烃以C23~C31的正构烷烃为主,芳烃以一环和二环芳烃为主;孔道内可溶性积炭均为芳烃,以三环和四环芳烃为主,从质谱峰强度计算约占总量的80%,菲和芘约占总量的50%。MTO不完全再生催化剂外表面可溶性积炭主要是沸点较高的C23~C31正构烷烃;孔道内可溶性积炭主要是几个高含量组分如芘和菲等的残留。在催化剂外表面的饱和烃可能是由小分子烯烃类化合物经过一系列聚合而成,而催化剂外表面的一环和二环芳烃应该是从分子筛孔道内形成并溢出,在分子筛孔道口吸附。分子筛催化剂孔道内的多环芳烃,是由小分子烃类化合物经过一系列低聚、氢转移、环化和脱氢等反应生成。     

离子膜电解装置氯气泄漏微正压操作处置总结

总结了在系统不停车的情况下采用微正压操作控制、处置离子膜电解装置氯气泄漏的经验.